Kinetic simulation of hydrocarbon generation from lacustrine type I kerogen from the Songliao Basin: Model comparison and geological application     

Wang Min  Lu Shuang-fangXue Hai-tao 《Marine and Petroleum Geology》2011,28(9):1714-1726

Eight lacustrine Type I kerogen samples from the Songliao Basin were pyrolyzed using the Rock-Eval equipment, and parallel first-order reaction models including the model with a single frequency factor and a discrete distribution of activation energies (SFF model) and the model with multiple frequency factors and a discrete distribution of activation energies (MFF model) were adopted to analyze kinetic characteristics of hydrocarbon generation of the Type I kerogen samples. The results show that the MFF and SFF models can satisfactory simulate hydrocarbon generation under laboratory conditions and the Type I kerogen shows relatively concentrated activation energy distributions (activation energies of MFF model range from 190 kJ/mol to 250 kJ/mol, activation energies of SFF model range from 220 kJ/mol to 240 kJ/mol), which indicates a homogeneous chemical bond structure of the Type I kerogen. The hydrocarbon generated curves from Type I kerogen were calculated by using the two models with a linear heating rate (3.3 K/Ma). It indicates that the hydrocarbon generation potentials (reaction fractions) are underestimated by using the SFF model during the kerogen thermal degradation for the components with chemical bond of lower and higher activation energies, while this problem can be avoided by using the MFF model. The calculated temperatures for 50% transformation ratio (TR) of all samples differ by as much as 20 °C. For the SFF model, the hydrocarbon generation curve obtained by using the weighted averaged kinetic parameters and the SFF model almost includes every curve calculated by using its own kinetic parameters. While the curve obtained by using the weighted averaged kinetic parameters and the MFF model cannot include every curve for all samples, it lies at the position of the averaged curve of all samples. The application of the MFF model in Songliao Basin shows that if TR 10% is taken as the onset of hydrocarbon generation, the threshold depth of hydrocarbon generation is about 1700 m, which is consistent with other geochemical parameters, such as S₁/TOC, S₁/(S₁ + S₂) and HC/TOC.  相似文献   

DSQ水管仪和SSQ-2I水平摆效能对比研究   总被引：1，自引：1，他引：0  

朱石军  樊志勇  武晓东  王志惠  胡毅涛 《地震地磁观测与研究》2011,32(6):122-126

SSQ-2I型水平摆仪器和DSQ水管仪同属倾斜类前兆仪器,两者观测原理不同,但观测物理量一致.相对于水管仪而言,SSQ-2I型水平摆属于新型仪器,有关其运行效能的评价很少.延庆地震台从2007年开始两种仪器同场地观测,通过年变幅度、滤波残差、周期分析、Venedikov调和分析、相关性分析、抗干扰能力等角度,对两种仪器...  相似文献   

Optimization and Characterization of Tl(I) Adsorption onto Modified Ulmus carpinifolia Tree Leaves     

Javad Zolgharnein  Neda Asanjarani  S. Norollah Mousavi 《洁净——土壤、空气、水》2011,39(3):250-258

Ulmus carpinifolia tree leaves were successfully used to remove Tl(I) from aqueous solution in a batch system. In order to improve the uptake capacity of sorbent, it was modified by various chemical agents such as NaOH, HNO₃, NH₃, NaCl, NaHCO₃, and CaCl₂. Among the modifiers, NaCl was the best. Equilibrium behavior of sorbent with Tl(I) was examined by the several isotherms. Considering modified U. carpinifolia equilibrium data fitted well to the Langmuir model with maximum capacity of 54.6 mg/g. The other isotherms such as: Freundlich and Dubinin‐Redushkevich (D‐R) models were also examined. The central composite design (CCD) was successfully employed for optimization of biosorption process. An empirical model was given through using response surface methodology. Also its validation was recognized by using relevant statistical tests such as ANOVA. The optimum conditions of biosorption: pH, m (amount of sorbent) and C (initial concentration) were found to be 7.9, 11.4 g/L, and 8.8 mg/L, respectively. On the other hand thermodynamic parameters: ΔG, ΔH, and ΔS were evaluated: the obtained results show that biosorption process was spontaneous and exothermic. Eventually, FT‐IR analysis confirmed that the main functional groups of sorbent have been involved through the biosorption process.  相似文献   

Low-cost high performance distributed data storage for multi-channel observations     

《New Astronomy》2015

The New Vacuum Solar Telescope (NVST) is a 1-m solar telescope that aims to observe the fine structures in both the photosphere and the chromosphere of the Sun. The observational data acquired simultaneously from one channel for the chromosphere and two channels for the photosphere bring great challenges to the data storage of NVST. The multi-channel instruments of NVST, including scientific cameras and multi-band spectrometers, generate at least 3 terabytes data per day and require high access performance while storing massive short-exposure images. It is worth studying and implementing a storage system for NVST which would balance the data availability, access performance and the cost of development. In this paper, we build a distributed data storage system (DDSS) for NVST and then deeply evaluate the availability of real-time data storage on a distributed computing environment. The experimental results show that two factors, i.e., the number of concurrent read/write and the file size, are critically important for improving the performance of data access on a distributed environment. Referring to these two factors, three strategies for storing FITS files are presented and implemented to ensure the access performance of the DDSS under conditions of multi-host write and read simultaneously. The real applications of the DDSS proves that the system is capable of meeting the requirements of NVST real-time high performance observational data storage. Our study on the DDSS is the first attempt for modern astronomical telescope systems to store real-time observational data on a low-cost distributed system. The research results and corresponding techniques of the DDSS provide a new option for designing real-time massive astronomical data storage system and will be a reference for future astronomical data storage.  相似文献   

2005—2018年北京市外来人口迁移特征与影响因素分析     

赵迪  陈鹏  李海成  苗红斌 《地球信息科学学报》2022,24(4):698-710

外来人口是大型或超大型城市人口结构的重要组成部分,研究特定城市外来人口的迁移特征及其影响因素不仅有助于从迁入地视角发现以特定城市为目标的人口迁移规律,对新城镇化背景下的城市化建设与发展也具有重要的现实意义。本文以北京市为例,通过收集2005—2018年的公安机关外来人口登记数据,对外来人口在不同年份的市级迁出地空间分布格局进行了研究,并利用空间回归模型对人口迁移的影响因素进行了分析,得到如下发现：① 北京市外来人口的迁出地在市级尺度下表现出明显的空间聚集效应,且聚集效应逐年增强;外来人口迁出地空间分布基本稳定,热点迁出地分布主要集中在河北-天津和河南省南部-湖北省北部2个主要聚集簇中;② 影响人口向北京迁移的主要变量为各迁出地的人口规模、交通时间、人均收入、高等教育水平、人口密度等,其中人口规模和人均收入对人口迁移的影响较为稳定,而高等教育水平和人口密度的影响分别从2010年和2014年后才开始显现,交通时间对人口迁移的障碍性作用虽然有所下降,但对人口迁移的影响变化不大;③ 空间误差项持续显著,表明迁出地的人口迁出量可能受相邻地市的社会文化等其他变量的影响。  相似文献   

I(L)值完全诱导空间     

方进明  岳跃利  刘刚 《中国海洋大学学报(自然科学版)》2001,31(6):960-964

作者引入 I(L)值完全下半连续映射 ,研究其性质。利用 I(L)值完全下半连续映射定义I(L)值完全诱导空间 ,给出 I(L)值完全诱导空间的拓扑基的表达形式 ,证得两个 I(L)值完全诱导空间的映射是连续映射的充分必要条件 ,并建立了乘积空间的 I(L)值完全诱导空间与 I(L)值完全诱导空间的乘积空间的联系  相似文献   

肝素酶Ⅰ对合成的肝素五糖的酶解作用及对其抗Xa因子活性的影响     

于广利  管华诗  Jawed Fareed 《中国海洋大学学报(自然科学版)》2001,31(4):529-535

研究肝素酶Ⅰ(来源于Flavobacterumheparinase，EC4.2.2.7)对人工合成的且含有与抗凝血酶Ⅲ特定结合位点的肝素五糖(SHP)的酶解作用，并对酶解作用的动力学进行研究。利用强阴离子高效液相色谱(SAX-HPLC)对酶解混合物进行分离，利用质谱(ESIMS)和核磁共振波谱(1H-NMR)技术对得到的二糖和三糖的结构进行确证。研究结果表明，这种被作为肝素反向试剂的肝素酶Ⅰ可水解人工所合成的肝素五糖，从而使之丧失抗Xa因子活性。  相似文献   

Optimum Sample Size to Detect Perturbation Effects: The Importance of Statistical Power Analysis – A Critique     

Marco Ortiz 《Marine Ecology》2002,23(1):1-9

Abstract. The current article describes statistical power analysis as an efficient strategy for the estimation of the optimum sample size. The principle aim is constructively to criticise and enrich the results presented by Mouillot et al. (1999) , who estimate the optimum sample size for evaluating possible perturbations. The authors did not make any reference to statistical power analysis, even though their objective clearly went beyond a simple stock evaluation to assess management strategies in a particular marine ecosystem. Surprisingly, they proposed (a priori) an ANOVA design to test a hypothesis considering both space and temporal scales. However, the authors did not cover important topics related with power analysis and the precautionary principle, both used into environment impact assessment programmes for marine ecosystems. Based on their results and on statistical power analysis, it is demonstrated that the variability (dispersion statistics), a key factor they used to estimate the sample size, is less relevant than the magnitude of perturbation (effect size). Therefore, a greater effort must be devoted to estimate the effect size of a particular phenomenon rather than a desired variability.  相似文献   

Methodical series tests for fuller ship hull forms     

B. Della Loggia  L. Doria 《Ocean Engineering》1980,7(6):659-706

In recent years many fuller ship hull forms have been designed and constructed in various shipbuilding countries, but the data available for the development of the fuller forms are inadequate from the point of view of preliminary ship design. In this paper the authors describe how they have systematically tested vessel forms of block coefficients ranging from 0.80 to 0.90. The analysis and presentation of the test results have been made in such a manner that designers can produce hull forms like those of tankers and other bulk carriers quickly and reliably.  相似文献   

冬季和春季长江口及其近海水域浮游病毒丰度的分析   总被引：7，自引：2，他引：7       下载免费PDF全文

白晓歌  汪岷  马晶晶  孙军  梁彦韬  乔倩 《海洋与湖沼》2007,38(4):367-372

采用荧光显微技术,对2006年长江口及近海水域20个站点的表层及10m层或潜水体冬、春两季的浮游病毒丰度进行了检测,对浮游病毒丰度在季节（冬、春两季）、水平分布和垂直分布上的变化进行了探讨.调查区浮游病毒丰度在冬、春季节上并无明显差异,但在水平分布上存在很大差异,河口区浮游病毒直接检测量（Virus Direct Count, VDC）达到10^7个/ml,近海水域VDC为10^6个/ml,河口区的浮游病毒丰度都明显高于近海水域病毒丰度 （P＜0.01）.在垂直分布上,冬、春两季长江口水域水深小于10m的站位,表层浮游病毒丰度与底层病毒丰度无明显差别,水深大于10m的站位,表层水样的浮游病毒丰度都高于10m水层病毒丰度,说明长江口浮游病毒的垂直分布与站位总水深有关.还通过比较各站点VDC与叶绿素a含量的数据,分析了二者之间的相关性：冬季浮游病毒丰度与叶绿素a含量成正相关性;春季浮游病毒丰度与叶绿素a含量成负相关性,但病毒丰度受叶绿素a含量的影响仅为10%-11%.  相似文献