First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

2007-2017年中国沙尘气溶胶的三维分布特征及输送过程     

贾瑞  刘玉芝  吴楚樵  祝清哲  汪兵 《中国沙漠》2019,39(6):108-117

利用最新发布的CALIPSO产品，构建了2007-2017年中国沙尘气溶胶的三维分布，并结合HYSPLIT-4模式和再分析数据，探讨了沙尘的三维输送过程。结果表明：中国的沙尘排放源区主要是塔克拉玛干沙漠和巴丹吉林沙漠，沙尘气溶胶出现频率分别为60%和35%。塔克拉玛干沙漠排放的沙尘主要（50%~70%）停留在源地0~6 000 m高度，少部分向东输送至甘肃和内蒙古；巴丹吉林沙漠排放的沙尘则主要向东输送。中国沙尘排放量在春季最大，向东输送最强；夏季，东亚夏季风限制了沙尘向东输送；秋季，沙尘排放减弱，输送强度和夏季相当；沙尘排放量在冬季最小，输送最弱。夏季，沙尘在输送过程中可被抬升至高度5 000 m以上，春季次之，秋、冬季的沙尘主要在低层大气输送。沙尘在向东输送的过程中被抬升并和当地人为污染物混合变为污染性沙尘，华北地区污染性沙尘出现频率高达30%；输送到海洋的沙尘也会与洋面上（0~3 000 m高度）的海盐气溶胶混合，出现频率约为10%。  相似文献   

Spatial and Temporal Distribution of Dust‐Bound Trace Metal Elements around Kuhdasht Watershed Area in Iran     

Hamid Alipour  Ahmad Jalalian  Naser Honarjoo  Norair Tommanian  Fereidoon Sarmadian 《洁净——土壤、空气、水》2019,47(10)

Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km²), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg^?1), Pb (46.352.9 mg kg^?1), and Cd (2.443.30 mg kg^?1) are obtained in winter, of Ni (98110 mg kg^?1) and Cu in autumn (16.053.5 mg kg^?1), and of Mn in summer (385505 mg kg^?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   

An Amended Chemical Mass Balance Model for Source Apportionment of PM2.5 in Typical Chinese Eastern Coastal Cities     

Qiaoli Wang  Nana Cheng  Sujing Li  Minli Dong  Xiangqian Wang  Linlin Ge  Tianjiao Guo  Wei Li  Xiang Gao 《洁净——土壤、空气、水》2019,47(2)

  相似文献   

车辆碾压作用下戈壁地表起尘浓度   总被引：1，自引：1，他引：0  

孟小楠  严平  王振亭  董苗  王勇 《中国沙漠》2019,39(1):80-87

通过野外观测车辆碾压作用下戈壁地表PM₁₀释放浓度，探讨其主要影响因素。针对戈壁区砾石、砂砾、砂质和砂土4种路面类型，应用TSI粉尘仪多次重复观测车辆碾压产生的PM₁₀浓度，进而阐明碾压次数、车速和地表水分等因素对起尘浓度的影响。结果表明：4种路面的平均起尘浓度依次为5.339、9.089、16.944、50.251 mg·m^-3，是自然状态下的5~50倍；起尘浓度随碾压次数增多而增大，其中砂土路情况下的增长最显著；随土层厚度的增大呈现出幂函数的增长趋势；降雨后路面起尘浓度显著减小，且降雨量会影响降雨后起尘浓度的变化趋势。最后提出了针对性的建议和措施以减弱车辆碾压导致的戈壁地表起尘。  相似文献   

新疆库尔勒市道路积尘重金属污染及健康风险评价     

阿地拉&#;艾来提  麦麦提吐尔逊&#;艾则孜  靳万贵  姑力巴努&#;艾尼  艾尼瓦尔&#;买买提  阿里木江&#;卡斯木 《中国地质》2020,47(6):1915-1925

为探究绿洲城市道路积尘重金属污染风险，在新疆库尔勒市采集54个代表性道路积尘样品，分析其中Hg、Cd、As、Pb、Cr和Cu等6种元素含量，基于GIS技术与地学统计法，采用污染负荷指数法和US EPA健康风险评价模型，对道路积尘中重金属污染及潜在健康风险进行评价。结果表明：库尔勒市道路积尘中Hg、Cd、As、Pb和Cu等元素含量的平均值均小于土壤环境质量—建设用地土壤污染风险管控标准（GB 36600—2018）中的筛选值，但Cr元素含量平均值为相应筛选值的9.90倍。污染评价结果表明，研究区道路积尘中Cr呈现重度污染，Hg、Cd、As、Pb和Cu呈无污染。道路积尘中重金属元素的污染负荷指数介于0.0142~0.0522，平均值为0.0266，处于无污染水平。从道路积尘重金属污染空间分布格局来看，库尔勒市东北部和北部区域出现污染高值区。健康风险评估结果表明，经手-口摄入途径是库尔勒市道路积尘重金属日均暴露量及健康风险的主要途径，儿童受到的健康风险高于成人。库尔勒市道路积尘中Hg、Cd、As、Pb、Cr与Cu等元素的非致癌风险及致癌风险处于安全范围内，As对非致癌风险的贡献最大，Cr对致癌风险的贡献最大。  相似文献   

中国工业烟粉尘排放时空演化及其影响因素     

郭政  姚士谋  吴常艳 《地理科学》2020,40(12):1949-1957

采用空间分析和空间杜宾模型等方法，研究1999—2017年中国工业烟粉尘排放时空演化特征及其影响因素。结果表明：① 中国工业烟粉尘排放空间分布差异明显，其排放的基尼系数和污染物分布指数均呈现下降态势，空间集中程度有所缓和。② 中国工业烟粉尘排放空间分布呈东北?西南走向，其排放中心不断由东南向西北方向迁移。③ 中国工业烟粉尘排放存在空间相关性和空间溢出效应，其冷热点区空间分布发生显著变化。④ 能源消耗、第二产业比重、人口密度和经济发展水平的提升将会增加工业烟粉尘排放，而外资水平、治理技术水平和环境规制力度的提升则有利于减少工业烟粉尘排放。  相似文献   

西太平洋海域现场培养实验中挥发性卤代烃浓度的变化及其影响因素     

韩钰  何真  刘珊珊  高旭旭  杨桂朋 《海洋学报》2020,42(2):1-9

CH₃I、CHCl₃、C₂HCl₃和CH₂Br₂是挥发性卤代烃4种重要成分，对大气化学产生重要影响。于2018年10月在西太平洋进行船基现场培养实验，研究微量元素Fe (50 nmol/L)、酸化(pH=7.9)、酸化(pH=7.9)和微量元素Fe (50 nmol/L)耦合作用、微量元素Fe (50 nmol/L)和N/P (16∶1)耦合作用及沙尘(4 mg/L)对浮游植物释放CH₃I、CHCl₃、C₂HCl₃和CH₂Br₂含量的影响。结果表明，与对照组相比，实验组CH₃I、C₂HCl₃和CH₂Br₂的释放均被不同程度抑制；CHCl₃的释放除添加沙尘时表现抑制作用外，其他条件下均为促进作用；实验组培养周期内叶绿素a浓度较高，而营养盐浓度变化规律不明显。总的来说，酸化和微量元素Fe可能是影响浮游植物释放挥发性卤代烃的重要限制因素，沙尘对促进浮游植物生长繁殖的影响更为显著。  相似文献   

High-latitude dust deposition in snow on the glaciers of James Ross Island,Antarctica     

Jan Kavan  Daniel Nývlt  Kamil Láska  Zbyněk Engel  Michaela Kňažková 《地球表面变化过程与地形》2020,45(7):1569-1578

High-latitude dust (HLD) depositions on four glaciers of James Ross Island (the Ulu Peninsula) were analysed. The deposition rate on the selected glaciers varies from 11.8 to 64.0 g m⁻², which is one order of magnitude higher compared to the glaciers in Antarctica or elsewhere in the world. A strong negative relationship between the sediment amount and altitude of a sampling site was found. This is most likely caused by the higher availability of aeolian material in the atmospheric boundary layer. General southerly and south-westerly wind directions over the Ulu Peninsula – with exceptions based on local terrain configuration – help to explain the significantly lower level of sediment deposition on San Jose Glacier and the high level on Triangular Glacier. X-ray fluorescence (XRF) spectrophotometry was used to estimate the relative proportions of the main and trace (lithophile) elements in the sediment samples. Both the sediment amount and the XRF results are analysed in a depth profile at each locality and compared among the glaciers, suggesting long-range transport of fine mineral material from outside James Ross Island. The distribution of aeolian sediment among the glaciers corresponds well with the prevailing wind direction on the Ulu Peninsula. © 2020 John Wiley & Sons, Ltd.  相似文献   

塔克拉玛干荒漠-绿洲过渡带尘卷风活动特征——以肖塘为例     

马明杰  杨兴华  何清  买买提艾力&#  买买提依明  周成龙  霍文 《中国沙漠》2019,39(2):115-121

利用1992-2011年塔克拉玛干沙漠北缘荒漠-绿洲过渡带肖塘气象站的观测资料，分析了该地区尘卷风的年、月变化规律及其与气象因子的关系。结果表明：（1）1992-2011年尘卷风发生日数总体呈波动递减趋势；尘卷风主要发生在3-9月，占全年总日数的90.9%，其中4-7月占全年总日数的70%左右。（2）尘卷风月发生日数随月平均地表与1.5 m高处温差的增大而线性增加（r=0.875，P<0.01）。（3）尘卷风月发生日数随着月平均风速的增大而幂函数增加（r=0.89，P<0.01）。（4）尘卷风月发生日数随月平均相对湿度的增大而线性减少（r=-0.869，P<0.01）。  相似文献