气袋采样法对还原硫化物测定的影响因素分析及机理研究     

孟洁  翟增秀  刘英会  张君  韩萌 《岩矿测试》2019,38(2):179-185

还原硫化物是一Z类典型的恶臭物质,其特点是活性高、不易储存,因此适宜的储存条件对还原硫化物的准确测定具有重要意义。本文使用气相色谱-质谱联用技术,从气袋材质、还原硫化物初始浓度、还原硫化物性质和储存时间四个因素探究袋采样法储存还原硫化物过程的损失情况。以Tedlar~? PVF和Teflon~? FEP为目标采样袋,使用5个初始浓度(0. 001、0. 010、0. 100、1. 000和10. 000μg/m L)的混合还原硫化物,选择0、2、6、12、24、48以及72h的储存时间,以响应因子和相对回收率作为评价因子,并使用配对t检验法和吸附动力学,研究影响储存效果的主要因素、物质损失机理以及两种采样袋的储存能力。结果表明,储存时间越长、物质初始浓度越高,物质活性越强,损失情况越严重;在环境温度达到60℃时,Tedlar~? PVF的基质背景较Teflon~? FEP更复杂;相同条件下,还原硫化物在Teflon~? FEP储存过程中损失更严重。依据研究结果建议:(1)样品采集后避光保存;(2)低浓度含硫样品的测定在采样后8h内完成,高浓度含硫样品的测定在2h内完成;(3)若待测样品气体温度较高,优先选择Teflon~? FEP采样袋,气体温度较低条件下选择Tedlar~? PVF采样袋,可最大限度保持样品的原始状态。本研究成果有利于确保还原硫化物样品的储存稳定性,最大限度还原恶臭污染现场情况,为恶臭污染的分析测试以及后续的恶臭污染控制与治理提供技术支持。  相似文献   

南海北部琼东南海域活动冷泉特征及形成模式   总被引：3，自引：0，他引：3       下载免费PDF全文

杨力  刘斌  徐梦婕  刘胜旋  关永贤  顾元 《地球物理学报》2018,61(7):2905-2914

近年来，活动冷泉的研究越来越受到关注.本文利用多波束数据、多道地震数据以及底质取样结果研究琼东南海域活动冷泉系统，分析活动冷泉的羽状流特征、海底地貌与底质特征以及流体活动构造特征.多波束水体数据上，观测到多个延伸高度超过750 m的气泡羽状流，海底流体活动非常强烈；多道地震上识别出麻坑、流体运移通道、气烟囱等流体渗漏相关的构造，与其他海域观测到的反射特征不同，羽状流的下方流体运移通道呈强振幅"串珠"反射；重力活塞取样在两个站位上获得浅表层块状天然气水合物.其中一个站位位于活动冷泉附近，天然气水合物赋存于海底以下8 m左右.基于以上三方面的数据，笔者提出了一个用于描述活动冷泉系统的形成模式，游离气通过气烟囱向上运移到达浅层，一部分在天然气水合物稳定带内形成天然气水合物，另一部分穿透天然气水合物稳定带到达海底，形成活动冷泉的羽状流.  相似文献   

Evaluation of clayed silt properties on the behavior of hydrate production in South China Sea     

《China Geology》2020,3(3):362-368

Gas hydrate is one kind of potential energy resources that is buried under deep seafloor or frozen areas. The first trial offshore production from the silty reservoir was conducted in the South China Sea by the China Geological Survey (CGS). During this test, there were many unique characteristics different from the sand reservoir, which was believed to be related to the clayed silt physical properties. In this paper, simulation experiments, facilities analysis, and theoretical calculation were used to confirm the hydrate structure, reservoir thermo-physical property, and bond water movement rule. And the behavior of how they affected production efficiency was analyzed. The results showed that: It was reasonable to use the structure I rather than structure II methane hydrate phase equilibrium data to make the production plan; the dissociation heat absorbed by hydrate was large enough to cause hydrate self-protection or reformation depend on the reservoir thermal transfer and gas supply; clayed silt got better thermal conductivity compared to coarse grain, but poor thermal convection especially with hydrate; clayed silt sediment was easy to bond water, but the irreducible water can be exchanged to free water under high production pressure, and the most obvious pressure range of water increment was 1.9–4.9 MPa.  相似文献   

A sand-production control system for gas production from clayey silt hydrate reservoirs     

《China Geology》2019,2(2):121-132

Sand production is a crucial problem during the process of extracting natural gas from hydrate reservoirs. To deal with sand-production problems systematically, a sand-production control system (SCS) is first proposed in this paper, specialized for pore-distributed clayey silt hydrate reservoirs. Secondly, a nodal system analysis method (NSAM) is applied to analyze the sand migration process during hydrate exploitation. The SCS is divided into three sub-systems, according to different sand migration mechanisms, and three key scientific problems and advances in SCS research in China Geological Survey are reviewed and analyzed. The maximum formation sanding rate, proper sand-control gravel size, and borehole blockage risk position were provided for clayey hydrate exploitation wells based on the SCS analysis. The SCS sub-systems are closely connected via bilateral coupling, and coordination of the subsystems is the basis of maintaining formation stability and prolonging the gas production cycle. Therefore, contradictory mitigation measures between sand production and operational systems should be considered preferentially. Some novel and efficient hydrate exploitation methods are needed to completely solve the contradictions caused by sand production.© 2019 China Geology Editorial Office.  相似文献   

New high-resolution 2D seismic imaging of fluid escape structures in the Makran subduction zone,Arabian Sea     

《China Geology》2020,3(2):269-282

Seabed fluid escape is active in the Makran subduction zone, Arabian Sea. Based on the new high-resolution 2D seismic data, acoustic blanking zones and seafloor mounds are identified. Acoustic blanking zones include three kinds of geometries: Bell-shaped, vertically columnar and tilted zones. The bell-shaped blanking zone is characterized by weak and discontinuous reflections in the interior and up-bending reflections on the top, interpreted as gas chimneys. Vertically columnar blanking zone is interpreted as side-imaged gas chimneys associated with focused fluid flow and topped by a seafloor anomaly expressed as a localized reflection discontinuity, which may together serve as a vent structure. Tilted acoustic blanking zone could be induced by accretionary thrust activity and rapid sedimentation surrounding slope. Seafloor mounds occur at the sites of bell-shaped acoustic blanking zone and may be associated with the material intrusion. Bottom simulating refectors (BSRs) are widely distributed and exhibit a series of characteristics including diminished amplitude, low continuity as well as local shoaling overlapping with these acoustic blanking zones. The large amount of gases dissociated from the gas hydrates migrated upwards and then arrived at the near-seafloor sediments, followed by the formation of the gas hydrates and hence the seafloor mound.  相似文献   

南海北部神狐海域天然气水合物成藏模式研究   总被引：4，自引：0，他引：4  

苏正  曹运诚  杨睿  吴能友  陈多福  杨胜雄  王宏斌 《地球物理学报》2014,57(5):1664-1674

南海北部陆坡神狐海域是我国海洋天然气水合物勘探开发研究的重点靶区，独特的水合物成藏特征，难以利用当前观测到的沉积速率和流体流动条件对其成藏机理进行解释和量化说明，对其形成演化模式和控制因素尚不明确.本文构建了海洋天然气水合物形成演化过程的动力学模型，模型的主控参量为海底沉积速率和水流速率，以此计算了神狐海域天然气水合物聚集演化过程，并与饱和度的盐度测试值进行对比.最后，在研究神狐海域地质构造活动和水合物成藏动力学基础上建立了神狐天然气水合物形成演化模式.认为神狐海域当前的天然气水合物是在上新世末—更新世早期断裂体系水合物基础上继承演化而来的，神狐海域天然气水合物形成演化具有典型的二元模式.第一阶段水合物形成发生在距今1.5 Ma之前构造活动形成的断裂体系中，高达50 m/ka的孔隙水流动携带了大量的甲烷进入水合物稳定带，导致了水合物的快速生成，在4万年内形成了饱和度达20%的甲烷水合物；第二阶段发生在1.5 Ma以来，泥质粉砂沉积使沉积体渗透率骤减，0.7 m/ka的低速率水流使甲烷供给不足，在海底浅层新沉积体中无法生成水合物，仅在水合物稳定带底部有缓慢的水合物继承增长，并因此形成了神狐海域当前观测到的水合物产出特征，而且水合物资源量仍在减少.  相似文献   

Gas/Substrate Fluxes and Microbial Community in Phenol Biodegradation Using an O2‐Based Membrane Biofilm Reactor          下载免费PDF全文

Özge Hanay  Ergin Taşkan  Burçin Yıldız  Halil Hasar  Eoin Casey 《洁净——土壤、空气、水》2014,42(1):36-42

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阳城煤矿瓦斯地质规律研究     

孟彦如  王薇  刘海燕 《山东地质》2011,(6):14-17

运用沉积学、构造地质学、煤地质学、数学分析等相关学科和方法,综合分析瓦斯涌出量的地质构造、顶底板岩性、上覆基岩厚度等地质因素,对阳城地区瓦斯含量、涌出量进行量化预测,并作出其全井田瓦斯含量、涌出量的等值线图。研究表明,阳城井田属低瓦斯矿井,瓦斯含量的变化主要与煤层埋深有关,随着煤层上覆基岩厚度以及煤层埋深的增高,瓦斯含量与涌出量在区内由北向南有增高趋势。  相似文献   

鄂西渝东区志留系流体封存箱的演化与天然气成藏   总被引：1，自引：0，他引：1  

胡晓凤  丁青 《海相油气地质》2011,16(3):38-44

因鄂西渝东区志留系勘探程度甚低,长期以来志留系一直被视为烃源层或盖层.随着建深1井在志留系钻获高压工业气流,曾经的"思维定式"发生了改变.通过对志留系油气成藏条件及碳、氧、锶稳定同位素追踪流体行为轨迹的分析认为,该区志留系具有自源供烃的特点以及流体相对封闭的独特性,这是形成志留系下统龙马溪组、小河坝组以及志留系中统韩家...  相似文献   

Occurrence and exploration of gas hydrate in the marginal seas and continental margin of the Asia and Oceania region   总被引：5，自引：0，他引：5  

Ryo Matsumoto  Byong-Jae Ryu  Sung-Rock Lee  Saulwood Lin  Shiguo Wu  Kalachand Sain  Ingo Pecher  Michael Riedel 《Marine and Petroleum Geology》2011,28(10):1751-1767

Supplies of conventional natural gas and oil are declining fast worldwide, and therefore new, unconventional forms of energy resources are needed to meet the ever-increasing demand. Amongst the many different unconventional natural resources are gas hydrates, a solid, ice-like crystalline compound of methane and water formed under specific low temperature and high pressure conditions. Gas hydrates are believed to exist in large quantities worldwide in oceanic regions of continental margins, as well as associated with permafrost regions in the Arctic. Some studies to estimate the global abundance of gas hydrate suggest that the total volume of natural gas locked up in form of gas hydrates may exceed all known conventional natural gas reserves, although large uncertainties exist in these assessments. Gas hydrates have been intensively studied in the last two decades also due to connections between climate forcing (natural and/or anthropogenic) and the potential large volumes of methane trapped in gas hydrate accumulations. The presence of gas hydrate within unconsolidated sediments of the upper few hundred meters below seafloor may also pose a geo-hazard to conventional oil and gas production. Additionally, climate variability and associated changes in pressure-temperature regimes and thus shifts in the gas hydrate stability zone may cause the occurrence of submarine slope failures.Several large-scale national gas hydrate programs exist especially in countries such as Japan, Korea, Taiwan, China, India, and New Zealand, where large demands of energy cannot be met by domestic supplies from natural resources. The past five years have seen several dedicated deep drilling expeditions and other scientific studies conducted throughout Asia and Oceania to understand gas hydrates off India, China, and Korea. This thematic set of publications is dedicated to summarize the most recent findings and results of geo-scientific studies of gas hydrates in the marginal seas and continental margin of the Asia, and Oceania region.  相似文献