小太平山油砂油地球化学及生物降解特征     

郝国丽  单玄龙  仝立华  李锋  刘轶松  王书琴  吴文丽 《世界地质》2017,36(3):913-923

采用小太平山同一层位不同深度且连续的油砂样品,对油砂油的地球化学及生物降解特征进行分析。小太平山油砂油在生物降解作用下产生了丰富的25-降霍烷,常规藿烷和甾烷也发生了一系列变化。由于分子结构和稳定性不同,抗降解能力不同,C_(21)/C_(23)三环萜烷、伽马蜡烷/C_(30)藿烷、Ts/Tm、C_(30)重排藿烷/C_(30)藿烷值、αααC_(27)R/αααC_(29)R、C_(28)αααR/C_(29)αααR、C_(29)ααα20R/αββ20S、C_(29)ααα20R/αββ20R、C_(27)重排甾烷/(规则甾烷+重排甾烷)、常规藿烷异构体降解为25-降霍烷的比例,均反映出油砂油的生物降解程度随深度的增加而增大。小太平山油砂油随含水饱和度的增加降解程度增大,证实地层水有利于细菌类微生物的迁移、营养物质的传递,促进原油的生物降解及25-降霍烷的产生。  相似文献   

Tectonic evolution of the West Kunlun Orogenic Belt along the northern margin of the Tibetan Plateau:Implications for the assembly of the Tarim terrane to Gondwana   总被引：2，自引：0，他引：2  

Chuan-Lin Zhang  Hai-Bo Zou  Xian-Tao Ye  Xiang-Yan Chen 《地学前缘(英文版)》2019,10(3):973-988

The West Kunlun orogenic belt(WKOB) along the northern margin of the Tibetan Plateau is important for understanding the evolution of the Proto-and Paleo-Tethys oceans. Previous investigations have focused on the igneous rocks and ophiolites distributed mostly along the Xinjiang-Tibet road and the China-Pakistan road, and have constructed a preliminary tectonic model for this orogenic belt. However, few studies have focused on the so-called Precambrian basement in this area. As a result, the tectonic affinity of the individual terranes of the WKOB and their detailed evolution process are uncertain. Here we report new field observations, zircon and monazite U-Pb ages of the "Precambrian basement" of the South Kunlun terrane(SKT) and the Tianshuihai terrane(TSHT), two major terranes in the WKOB. Based on new zircon U-Pb age data, the amphibolite-facies metamorphosed volcanosedimentary sequence within SKT was deposited during the late Neoproterozoic to Cambrian(600-500 Ma), and the flysch-affinity Tianshuihai Group, as the basement of the TSHT, was deposited during the late Neoproterozoic rather than Mesoproterozoic. The rock association of the volcano-sedimentary sequence within SKT suggests a large early Paleozoic accretionary wedge formed by the long-term lowangle southward subduction of the Proto-Tethys Ocean between Tarim and TSHT. The amphibolitefacies metamorphism in SKT occurred at ca. 440 Ma. This ca. 440 Ma metamorphism is genetically related to the closure of the Proto-Tethys Ocean between Tarim and the Tianshuihai terrane, which led to the assembly of Tarim to Eastern Gondwana and the final formation of the Gondwana. Since the late Paleozoic to early Mesozoic, the northward subduction of the Paleo-Tethys Ocean along the HongshihuQiaoertianshan belt produced the voluminous early Mesozoic arc-signature granites along the southern part of NKT-TSHT. The Paleo-Tethys ocean between TSHT and Karakorum closed at ca. 200 Ma, as demonstrated by the monazite age of the paragneiss in the Kangxiwa Group. Our study does not favor the existence of a Precambrian basement in SKT.  相似文献   

泡沫镍基P-25薄膜光催化降解水中喹啉   总被引：1，自引：0，他引：1  

朱遂一  霍明昕  杨霞  董龙  王健  金生威  刘秀 《吉林大学学报(地球科学版)》2011,41(5):1554-1561

为了提高TiO2薄膜的光催化效率和使用稳定性,采用浸渍涂布法将粉体P-25TiO2负载在泡沫镍基片上,制备泡沫镍基负载P-25薄膜光催化材料,利用XPS和FE-SEM分析了薄膜的晶相和形貌,并考察了不同条件下P-25薄膜对水中喹啉的降解效能。研究发现:P-25薄膜均匀覆盖泡沫镍基片表面,薄膜呈混晶结构,表面呈现微裂痕。实验表明:增大光照强度和曝气量能够明显提高水中喹啉的光催化降解率;低pH有利于水中喹啉的去除;初始浓度和温度不是光催化反应的主控因子;曝气产生的吹脱、扰动和水力紊流效应对光催化反应的影响不明显。结果显示:不改变水溶液温度和pH条件下,P-25薄膜对水中喹啉有良好的去除效果,并可多次重复使用。  相似文献   

Swashed away? Storm impacts on sandy beach macrofaunal communities     

Linda Harris  Ronel Nel  David Schoeman 《Estuarine, Coastal and Shelf Science》2011,94(3):210-221

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Short-term residence and movement patterns of the annular seabream Diplodus annularis in a temperate marine reserve     

David March  Josep Als  Amlia Grau  Miquel Palmer 《Estuarine, Coastal and Shelf Science》2011,92(4):251-587

The short-term movements of a small temperate fish, the annular seabream Diplodus annularis (Linnaeus 1758), were examined using standard tag-recapture and passive acoustic telemetry in Palma Bay (NW Mediterranean), a marine protected area (MPA). The study aimed to provide valuable information for assessing the recreational fishery and its results suggest that MPAs can be used to protect the adult stock of D. annularis. All the fish tagged with standard tags were recaptured near the release locations, with a maximum distance of ∼300 m. The maximum time between release and recapture was 185 d. Two different arrays of acoustic receivers were deployed, one in 2008 and another in 2009, within the MPA. Twenty adults were surgically tagged with acoustic transmitters. Fish monitored in 2008 (n = 12) were translocated from the point of capture to analyse the movement behaviour after artificial displacement. Upon release at displaced locations, 67% of the fish moved towards the original capture location using a time of return that ranged from 0.75 to 15.25 h. Fish monitored in 2009 (n = 8) were released at the point of capture. They showed high site fidelity with a maximum period of 27 d between the first time and the last time they were detected.  相似文献   

珠江三角洲城市群对夏季降雨影响的初步研究   总被引：5，自引：4，他引：1  

任慧军  徐海明 《气象科学》2011,31(4):391-397

利用TRMM 2A25卫星降水数据和CMORPH同化数据对珠三角洲地区的降水分布特征进行了探讨,观测表明：珠三角城市群区域总体处于降水的低值中心,且对流降雨的低值中心尤为明显;同时近10 a珠三角核心城市区域降雨有减少的趋势,这种降水减少的趋势可能与珠三角城市化效应有关。本文进一步利用WRF模式模拟分析了珠三角城市群发展对夏季降雨的影响,结果表明珠三角城市化使得该区域降雨减少,其原因为城市化使得地表的蒸发减弱及其大气中的水分供应减少,同时也抬升了珠三角区域边界层高度相应增强了低层大气水汽垂直混合。  相似文献   

4种再分析资料在中国区域的适用性研究进展   总被引：4，自引：0，他引：4       下载免费PDF全文

谢潇  何金海  祁莉 《气象与环境学报》2011,27(5):58-65

根据NCEP/NCAR、NCEP/DOE、ERA-40和JRA-25共4种比较常用的再分析资料在中国区域的适用性研究作了概述。结果表明：4种资料既呈现出一定的共性,又在不同区域、不同时间尺度上差异显著;再分析资料的可信度普遍表现为在东部地区好于西部地区,低纬地区好于高纬地区,这可能与中国地面气象站点＂东密西疏＂有关;1...  相似文献   

济阳拗陷特殊生物降解油的初步研究   总被引：1，自引：1，他引：0  

卢鸿  彭平安  徐兴友  张林晔 《沉积学报》2004,22(4):694-699

济阳拗陷草古100平19井奥陶系储层原油,饱和烃馏分均已损失殆尽,仅残余藿烷系列化合物;同时,芳烃馏分化合物也已损失殆尽,仅残余三芳甾烷系列化合物。上述芳烃化合物俱已损失殆尽的蚀变特征,在相关文献中的报道较为少见。原油中不受水洗作用影响的正构烷烃和不受生物降解作用影响的有机硫化合物(苯并噻吩和二苯并噻吩)均已损失殆尽,显然暗示了原油蚀变是遭受水洗作用和生物降解作用共同作用的结果。原油芳烃馏分的“UCM”鼓包幅度明显大于饱和烃馏分的“UCM”鼓包,暗示了芳烃化合物的降解速率平行甚至超过饱和烃的降解速率。原油中低分子量芳烃化合物的快速降解,暗示了油藏可能是在氧化条件下而非在还原条件下发生蚀变的。  相似文献   

Do paleoclimate proxies agree? A test comparing 19 late Holocene climate and sea‐ice reconstructions from Icelandic marine and lake sediments     

Yarrow Axford  Camilla S. Andresen  John T. Andrews  Simon T. Belt  Áslaug Geirsdóttir  Guillaume Massé  Gifford H. Miller  Sædís Ólafsdóttir  Lindsay L. Vare 《第四纪科学杂志》2011,26(6):645-656

Geochemical, mineralogical and biological indicators preserved in sediments are widely used to reconstruct past climate change, but proxies differ in the degree to which their utility as climate indicators has been validated via laboratory experiments, modern spatial calibrations, or down‐core comparisons with instrumental climate data. Multi‐proxy studies provide another means of evaluating interpretations of proxies. This paper presents a multi‐proxy assessment comparing 19 sub‐centennially resolved late Holocene proxy records, covering the period 300–1900 AD, from seven Icelandic marine and lacustrine core sites. We employ simple statistical comparisons between proxy reconstructions to evaluate their correlations over time and, ultimately, their utility as proxies for regional climate. Proxies examined include oxygen isotopic composition of benthic and planktonic foraminifera, abundance of the sea‐ice biomarker IP₂₅, allochthonous quartz in marine sediments (a proxy for drift ice around Iceland), marine carbonate abundance, total organic carbon concentration, chironomid assemblages, lacustrine biogenic silica and carbon/nitrogen ratios in lake sediments. Most of the examined proxy records, including temperature and sea‐ice proxies, correlate strongly with each other over multi‐centennial timescales, and thus do appear to record changes in regional climate. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

The blue supergiant Sher 25 and its intriguing hourglass nebula     

M. A. Hendry  S. J. Smartt  E. D. Skillman  C. J. Evans  C. Trundle  D. J. Lennon  P. A. Crowther  I. Hunter 《Monthly notices of the Royal Astronomical Society》2008,388(3):1127-1142

The blue supergiant Sher 25 is surrounded by an asymmetric, hourglass-shaped circumstellar nebula. Its structure and dynamics have been studied previously through high-resolution imaging and spectroscopy, and it appears dynamically similar to the ring structure around SN 1987A. Here, we present long-slit spectroscopy of the circumstellar nebula around Sher 25, and of the background nebula of the host cluster NGC 3603. We perform a detailed nebular abundance analysis to measure the gas-phase abundances of oxygen, nitrogen, sulphur, neon and argon. The oxygen abundance in the circumstellar nebula  (12 + log O/H = 8.61 ± 0.13 dex)  is similar to that in the background nebula (8.56 ± 0.07), suggesting that the composition of the host cluster is around solar. However, we confirm that the circumstellar nebula is very rich in nitrogen, with an abundance of 8.91 ± 0.15, compared to the background value of 7.47 ± 0.18. A new analysis of the stellar spectrum with the fastwind model atmosphere code suggests that the photospheric nitrogen and oxygen abundances in Sher 25 are consistent with the nebular results. While the nitrogen abundances are high, when compared to stellar evolutionary models, they do not unambiguously confirm that the star has undergone convective dredge-up during a previous red supergiant phase. We suggest that the more likely scenario is that the nebula was ejected from the star while it was in the blue supergiant phase. The star's initial mass was around  50 M_⊙  , which is rather too high for it to have had a convective envelope stage as a red supergiant. Rotating stellar models that lead to mixing of core-processed material to the stellar surface during core H-burning can quantitatively match the stellar results with the nebula abundances.  相似文献