Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence     

《China Geology》2020,3(4):602-610

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.  相似文献   

湖北地区地震震源参数研究     

申学林  魏贵春  丁文秀  戴苗 《中国地震》2018,34(4):781-787

为了研究湖北地区地震震源参数特征,本文基于湖北数字地震台网记录到的S波观测振幅谱,通过遗传算法获得湖北地区的介质品质因子和台站场地响应,并在此基础上计算了湖北地区地震震源参数。结果显示,湖北地区介质品质因子Q值随频率f变化的关系式为Q(f)=501.8·f~(0.309);对于大部分台站获得了与其岩石基底相符的场地响应,没有出现明显放大效应;地震震级与地震矩对数间呈线性关系,即lg M_0=10.06+1.093M_L;震源半径与应力降间呈双对数线性关系,即lgΔσ=10.52-2.01lgr;地震矩与拐角频率间整体上呈反相关;地震矩与应力降间关系不显著。  相似文献   

相山铀矿田西部地区深部多金属矿化成矿年代与成矿流体演化:Rb-Sr同位素体系的制约   总被引：1，自引：1，他引：0  

刘军港  李子颖  聂江涛  张万良  王勇剑  田明明 《岩石学报》2019,35(9):2787-2800

江西相山铀矿田科学深钻3号孔在深部-700 m发现大量铅锌多金属矿化脉,垂向上呈"上铀下多金属"的分布特征。本文选取深部多金属矿脉主成矿阶段(S3)自形闪锌矿样品6件和不同阶段的毒砂、黄铁矿、方铅矿、方解石等样品12件,以及围岩全岩样品17件,进行了Rb、Sr同位素组成研究。结果表明:(1)由闪锌矿Rb-Sr等时线法确定的相山铀矿田深部多金属矿化形成于121. 0±3. 5Ma,与围岩火山岩存在较大时差,可能与晚于围岩的深部次火山有关。根据穿插关系,多金属矿化略晚于碱性交代铀矿化,但明显早于酸性交代铀矿化;(2)多金属矿化脉体中金属矿物的Rb和Sr含量分别介于0. 041×10~(-6)～1. 38×10-6和2. 35×10-6～23. 11×10-6之间,Sr同位素初始比值(87Sr/86Sr)i变化较大,介于0. 706114～0. 718814之间,平均值为0. 713579,暗示相山铀矿田深部多金属矿化的成矿物质主要来源于地壳。初始流体Sr同位素值(0. 718665)明显高于成矿时赋矿围岩(流纹英安岩为0. 714581,碎斑流纹岩为0. 714417)的Sr同位素组成,表明多金属成矿流体和物质并非来自围岩火山岩;(3)由早到晚阶段的(87Sr/86Sr)i呈明显降低的演化趋势,表明成矿流体演化过程中受到大气降水的不断稀释作用。相山矿田的铀矿和深部多金属矿化同形成于华南中生代板内伸展构造背景。  相似文献   

N油田A油组钙质隔夹层地质特征及成因分析     

廖明光  黄志强  廖纪佳  梁文锋  张航  潘柯宇 《沉积与特提斯地质》2020,40(1):26-34

在油田开发过程中,隔夹层控制油气水运动规律,对于寻找剩余油具有重要控制作用。本文以N油田TF组2段A油组为研究对象,通过薄片、岩心测试、测井、碳氧同位素等资料综合分析,研究其钙质隔夹层的分布特征、岩石学特征、物性特征、测井识别特征,并从沉积环境、物质来源、成岩作用相结合的角度分析钙质隔夹层的成因。研究表明,A油组纵向上发育的三套钙质隔夹层主要发育在前滨滩坝沉积微相,顶钙与底钙的岩性以砂质生屑质灰岩为主,中钙为钙质砂岩;三套钙质隔夹层中生物碎屑主要以腕足、腹足、有孔虫为主,含少量棘皮、瓣鳃、红藻、介形虫、苔藓虫等;成岩作用主要为胶结作用,胶结物类型包含早期方解石胶结物、中期铁方解石胶结物、晚期铁白云石胶结物;碳氧同位素分析表明,隔夹层中碳主要来自于沉积过程中的海水,同时有少量来自于大气淡水和有机酸,Ca~(2+)主要来源于生物碎屑,其次为钙长石溶解、铝硅酸盐矿物的水化作用。  相似文献   

南秦岭早古生代玄武岩的岩浆源区及演化过程   总被引：1，自引：1，他引：0  

张方毅  赖绍聪  秦江锋  朱韧之  赵少伟  杨航  朱毓  张泽中 《岩石学报》2020,36(7):2149-2162

南秦岭地区早古生代玄武岩中发育的大量单斜辉石斑晶为研究火山岩的深部演化过程及源区属性提供了重要的载体。本文通过对早古生代玄武岩及其中的单斜辉石斑晶进行矿物学、岩石学及地球化学分析,讨论火山岩的演化历程及源区属性。电子探针分析结果表明玄武岩中单斜辉石斑晶属于透辉石,其成分与全岩成分并不平衡,暗示岩石经历了单斜辉石的堆晶作用。通过质量平衡计算得到了与单斜辉石斑晶平衡的熔体并计算了单斜辉石结晶的温压条件,结果显示单斜辉石斑晶结晶压力为7.6～14.0kbar,温度为1201～1268℃。高压下的分离结晶作用导致了单斜辉石成为主要的结晶相。重建后的玄武岩具有高镁、高钙、富钛,富集高场强元素Nb、Ta,亏损Rb、K、Sr和P,Dy/Yb比值高的地球化学特征,指示其源区为含单斜辉石、磷灰石及石榴石的交代岩石圈地幔。同地区发现的玄武质角砾也具高镁及高钙的特征,其富集Ba、Nb、Ta、Ti及低Dy/Yb比值表明源区为含单斜辉石、角闪石及尖晶石的交代岩石圈地幔。  相似文献   

京西北地区地应变观测与小震震源机制解一致性研究     

茅远哲  曹筠  高晨  冯向东  王晓山 《中国地震》2019,35(4):709-717

以京西北地区作为研究区域，采用应变参数方法解算定点地应变观测数据，将所得应变参数时间序列作为研究对象，利用该结果与研究区内同期小震震源机制解进行一致性分析，研究得出呈拉张性质的定点观测最大主应变方位与震源机制解最大拉张变形方向（T轴）水平投影具有良好的对应性，整体以NNW—NE向为主，且自西向东排布的测点最大主应变方位与震源机制解最大拉张变形方向均表现为逐渐东向偏移的趋势，与华北平原块体北部发生顺时针旋转活动的特征相吻合，结果进一步检验了地应变观测反映区域应变场信息的能力。  相似文献   

Groundwater contaminant source identification based on iterative local update ensemble smoother          下载免费PDF全文

YANG Ai-lin  JIANG Si-min  LIU Jin-bing  JIANG Qian-yun  ZHOU Ting  ZHANG Wen 《地下水科学与工程》2020,8(1):1-9

Identification of the location and intensity of groundwater pollution source contributes to the effect of pollution remediation, and is called groundwater contaminant source identifcation. This is a kind of typical groundwater inverse problem, and the solution is usually ill-posed. Especially considering the spatial variability of hydraulic conductivity field, the identification process is more challenging. In this paper, the solution framework of groundwater contaminant source identification is composed with groundwater pollutant transport model (MT3DMS) and a data assimilation method (Iterative local update ensemble smoother, ILUES). In addition, Karhunen-Loève expansion technique is adopted as a PCA method to realize dimension reduction. In practical problems, the geostatistical method is usually used to characterize the hydraulic conductivity feld, and only the contaminant source information is inversely calculated in the identifcation process. In this study, the identification of contaminant source information under Kriging K-field is compared with simultaneous identification of source information and K-field. The results indicate that it is necessary to carry out simultaneous identification under heterogeneous site, and ILUES has good performance in solving high-dimensional parameter inversion problems.  相似文献   

面向目标的起伏地表组合震源延时参数计算方法          下载免费PDF全文

秦龙  尹成  崔永福  刘正文  张振  方兵  陶正武 《地球物理学报》2019,62(4):1492-1501

组合震源技术通过调节延迟激发时间和震源埋藏深度能够实现地震波场的定向传播,提高地震波的照明能量和地震数据信噪比.然而,目前国内外对基于特定目标的组合震源最佳聚焦方向的选取以及起伏地表组合震源定向理论的研究相对较少.在聚焦方向选取方面,目前基本是利用多种不同延时参数的组合震源分别进行试验,从而确定较好的组合震源延时参数.本文则利用爆炸反射面原理,在目的层界面上均匀布置震源同时激发地震波,能够产生垂直于地层界面传播的平面波,当初至波传播至地表时进行地表方向统计.根据互易性原理,以初至波传播方向的反方向为聚焦方向,激发产生的地震波主波束方向将垂直入射到目的层界面上,从而精确的计算出组合震源的最佳聚焦方向.在组合震源定向方面,目前主要是利用组合震源方向因子公式进行计算,但该方法要求震源布置在同一条直线上,并不能满足起伏地表的应用要求.本文以惠更斯-菲涅尔原理为理论基础,提出通过炮点向量在聚焦方向上的投影来确定组合震源传播至虚拟波前的走时,从而确定任意起伏地表组合震源的延迟激发时间.该方法不仅能够计算出沿给定地质模型的目的层界面垂直入射的组合震源聚焦方向,也能够确定任意起伏地表情况下形成沿该聚焦方向定向传播地震波场的组合震源延迟激发时间.因此,本文提出的面向目标的起伏地表组合震源延时参数计算方法对组合震源数据采集具有理论与实践意义.  相似文献   

Distribution and source of heavy metals in the surface sediments from the near-shore area,north Jiangsu Province,China   总被引：1，自引：0，他引：1  

Gang Xu  Jian Liu  Shaofeng Pei  Xianghuai Kong  Gang Hu 《Marine pollution bulletin》2014

Samples of surface sediment and vibrocore were collected in the near-shore area of north Jiangsu Province for grain size, elements, ²¹⁰Pb_excess and ¹³⁷Cs analyses. In our study area, the diversity of metal concentration was controlled not by the grain size, but by the source. The element content of the old Yellow River Delta was used as baseline for our study area. Geoaccumulation indexes indicate that no station was polluted by Cu, Pb, Zn and As, but the I_geo values of As were close to zero in some stations. Slight pollution caused by Cd was observed in some stations. Correlation and enrichment factors suggest that Cu, Pb and Zn are lithogenic in origin, while As and Cd are mixed in origin. Especially, in some polluted stations Cd was obviously anthropogenic in origin.  相似文献   

Heavy metals in particulate and colloidal matter from atmospheric deposition of urban Guangzhou,South China     

Wen Huang  Dandan Duan  Yulong Zhang  Hefa Cheng  Yong Ran 《Marine pollution bulletin》2014

Suspended particulate matter (SPM) and colloidal matter (COM) in annual dry and wet deposition samples in urban Guangzhou were for the first time collected, and their trace metals were investigated by using inductively coupled plasma mass spectrometry (ICP-MS). The deposition flux of SPM and of metal elements varied largely among the investigated seasons, and reached the maximum in spring. The correlation analysis indicated that significant correlations existed among some of the metal elements in the deposition samples. The enrichment factors (EF) of metals in COM in the deposition ranging from 79.66 to 130,000 were much higher than those of SPM ranging from 1.65 to 286.48, indicating the important role of COM. The factor analysis showed that emissions from street dust, non-ferrous metal production, and heavy fuel oil were major sources of the trace metals. Positive matrix factorization (PMF) model was used to quantitatively estimate anthropogenic source.  相似文献