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The direct H2Oliquid–H2Ovapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ2H and δ18O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ2H and δ18O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ2H and 0.98‰ for δ18O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ2H and δ18O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ2H and 0.73‰ for δ18O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS. 相似文献
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何瑞霞 金会军 蒋观利 张泽 陈雪梅 Raul David SERBAN Mihaela SERBAN Jef VANDENBERGHE Valentin V.SPEKTOR Hugh M.FRENCH 《冰川冻土》2021,43(1):263-273
冰缘遗迹（特别是冷生楔形构造及融冻褶皱）是重建古气候及第四纪晚期多年冻土环境的重要证据。内蒙古鄂尔多斯高原是我国北方地区冰缘现象最为发育的地区之一。为准确了解鄂尔多斯高原冰缘遗迹类型及其分布特征、区域冻土演化历史等,中国科学院西北生态环境资源研究院和荷兰自由大学共同组成科研小组,于2018年5—6月组织了“鄂尔多斯高原冰缘遗迹科学考察”。考察区域涉及靖边—城川—乌审旗—鄂尔多斯东胜区一带约12 000 km2的范围。考察内容主要包括鄂尔多斯高原冰缘遗迹类型及特征、分布区域、各类型冰缘遗迹所指示的气候条件的初步推断等。结果表明：冻融褶皱和冷生楔体构造是鄂尔多斯高原主要存在的两大类冰缘遗迹。基于本次考察中关于冰缘遗迹的分布与特征等新发现,并综合前人研究成果,初步推断：在气温极低、多年冻土非常发育的时段,有利于形成各类冷生楔状构造,如冰楔假形和大型原生砂楔等;在气候转暖、多年冻土退化,但还没有全部融化完阶段,可能形成融冻褶皱;区域性大面积分布和成群出现的融冻褶皱一般反映较暖气候环境下,多年冻土层上部已退化到一定程度。基于光释光（OSL）年代测试结果,结合冰缘遗迹的特征及其所指示的古气候环境,初步重建了鄂尔多斯5万年以来的冻土环境变化序列。区内多年冻土在多年冻土最大期（LPM,25~19 ka BP）时最发育,以大面积连续多年冻土为主;之后,随气温转暖,总趋势呈退化状态,多年冻土分布逐渐变为片状→岛状→零星斑状,直至现今全部融完变为深季节冻土区。 相似文献
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液氮冻结条件下岩石孔隙结构损伤试验研究 总被引：2，自引：0，他引：2
液氮温度极低,约在-195.56-180.44℃之间,当与岩石接触时会对岩石孔隙结构产生损伤。根据这一特点,低温液氮有望作为压裂流体对储层进行压裂改造。为了研究液氮冻结对岩石孔隙结构损伤的影响,选取两种不同砂岩岩样,分别在不同初始含水饱和度条件下进行液氮冻结处理。对冻结前、后的岩样进行孔隙度以及核磁共振测试,得到岩样在冻结前、后的孔隙度、横向弛豫时间T2分布以及T2谱面积变化情况。试验结果表明:液氮冻结会对岩石的孔隙结构产生损伤,损伤程度受到岩性、孔隙度和岩石含水饱和度等因素影响;岩石含水饱和度越大,损伤就越严重,当岩石含水饱和度达到100%时,岩石表面产生了明显裂纹;岩石在液氮冻结下损伤形式主要是微孔隙的发育和扩展,微孔隙的增加会使岩石孔隙结构的连通性增强,甚至会产生新的大尺寸孔隙,从而对孔隙结构造成严重损伤。 相似文献
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Cryogenic structure (patterns made by ice inclusions) in seasonally frozen and permafrost-af-fected soils result from ice formation during freezing. Analysis of cryogenic structures in soils is essential to our understanding of the cryogenic processes in soils and to formulating land use management interpretations. When soils freeze, the freezing front moves downward and attracts water moving upward resulting in mainly horizontal lenticular ice formation. Platy and lenticular soil structures form between ice lenses in upper active layer. The reticular soil structure usually forms above the permafrost table caused by freeze-back of the permafrost. The upward freeze-back resulted in platy soil structure and the volume changes following the annual freeze-thaw cycle resulted in vertical cracks. The combined result is an ice-net formation with mineral soils embedded in the ice net. The upper permafrost layer that used to be a part of the active layer has an ice content exceeding 50% due to repeated freeze-thaw cycles over time. The mineral soils appear in blocks embedded in an ice matrix. The permafrost layer that never experienced the freeze-thaw cycle often consists of alternate layers of thin ice lens and frozen soils with extreme hard consistence and has relatively lower ice content than the ice-rich layer of the upper permafrost. Ice contents and thaw settling potentials associated with each cryogenic structure should be considered in engineering and land use interpretations. 相似文献
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Igor E. Guryanov 《冰川冻土》2004,26(Z1):70-75
The paper discusses the distinctive features of grain size distribution of permafrost soils formed under conditions of continental lithogenesis and cryogenic weathering of rocks. As a functional consequence of surface erosion of mineral particles, the log-normal distribution of the density function of grain size is derived confirmed for any conditions and sediment types. 相似文献
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广东2008年低温雨雪冰冻灾害及气象应急响应 总被引：16，自引：4，他引：12
2008年初我国南方遭受了百年一遇低温雨雪冰冻灾害,广东的受灾程度属80年一遇,造成了重大经济损失和严重社会影响.分析发现:灾害过程在近年来最严重的一次"拉尼娜"事件背景下发生的,与欧亚地区持续大气环流异常密切相关.在"北脊南槽"和西太平洋副高偏北偏强的形势下,冷暖气流在我国南方地区频繁交汇,使对流层中低层形成逆温层和局地经向环流产生异常,造成了此次持续低温雨雪冰冻过程.面对灾害引发的公共事件,广东省气象部门打破常规、准确预警,启动预案,通过媒体和"公共事件预警信息发布平台",及时传播权威的公共预警信息,为安定民心、稳定社会、减少灾害起到积极作用.灾后反思发现,山区冰灾的监测、灾害的评估、公共信息发布等的能力和规范均亟待加强. 相似文献
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天然与风干状态下冷生亚黏土的崩解形态特征 总被引：1，自引：1，他引：0
土的崩解形态是描述土的崩解过程及探讨其崩解机理重要的必要条件之一,选取了一种高孔隙率、粉黏粒含量较高,且不具有湿陷性的原状冷生轻质亚黏土作为研究对象,对其天然含水量及风干含水量状态下的土样品进行崩解试验. 结果表明：天然状态的土样呈块状崩解,而风干状态下的呈鳞片状崩解,且鳞片状崩解的强度及平均速率都大于块状崩解;块状崩解的速率随时间变化较为缓和,而鳞片状崩解的速率随时间变化起伏较大. 崩解形态与崩解速率有着紧密的对应关系,与崩解形态相对比,发现崩解速率降低的过程是水侵入土样,且土样中空气压力增大的过程,而速率上升的过程则是土样崩解的过程. 相似文献
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Comparison of two methods for ground level vapour sampling and influence of meteorological parameters on its stable isotopic composition at Roorkee,India 
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下载免费PDF全文 Ground level vapour (GLV) samples were collected at Roorkee, Uttarakhand, India using two methods: liquid condensation (LC) at 0 °C and cryogenic trap (CT) at ?78 °C for the period 2009–2011. The study reveals that there is a considerable fluctuation in stable isotopic composition of GLV throughout the year. The study area receives complex moisture source during different seasons, which is evident from the moisture flux received during different seasons. The isotopic composition of the GLV in both methods shows depleted nature during rainout process. CT method shows exact isotopic signature of GLV because of maximum trapping of air moisture and its condensation, whereas LC method shows depleted or enriched character because of the prevalence of kinetic and diffusive fractionation. The d value shows that LC method acts as magnifier of the CT method and clearly shows seasonal effect than the clustered CT method. Hence, to decipher the original isotopic signature of GLV, isotopic composition of GLVLC can be converted to GLVCT by deriving an empirical relationship with changing season and locations. Meteorological parameters show varied behaviour with GLVCT and LC because of moisture sources in all seasons. The GLVCT and LC method shows significant correlation with meteorological parameters when the region is dominated by single moisture source. The GLVLC method magnifies the correlation with meteorological parameters when the region is influenced by more than one source. The study shows that the GLVLC methods can be used in place of GLVCT when the objective is to understand the influence of different moisture sources on GLV. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献