A two-layer model for studying 2D dissolved pollutant runoff over impermeable surfaces     

Taotao Zhang  Yang Xiao  Dongfang Liang  Hongwu Tang  Junzeng Xu  Saiyu Yuan  Nairu Wang  Bin Luan 《水文研究》2021,35(5):e14152

Dissolved pollutants in stormwater are a main contributor to water pollution in urban environments. However, many existing transport models are semi-empirical and only consider one-dimensional flows, which limit their predictive capacity. Combining the shallow water and the advection–diffusion equations, a two-dimensional physically based model is developed for dissolved pollutant transport by adopting the concept of a ‘control layer’. A series of laboratory experiments has been conducted to validate the proposed model, taking into account the effects of buildings and intermittent rainfalls. The predictions are found to be in good agreement with experimental observations, which supports the assumption that the depth of the control layer is constant. Based on the validated model, a parametric study is conducted, focusing on the characteristics of the pollutant distribution and transport rate over the depth. The hyetograph, including the intensity, duration and intermittency, of rainfall event has a significant influence on the pollutant transport rates. The depth of the control layer, rainfall intensity, surface roughness and area length are dominant factors that affect the dissolved pollutant transport. Finally, several perspectives of the new pollutant transport model are discussed. This study contributes to an in-depth understanding of the dissolved pollutant transport processes on impermeable surfaces and urban stormwater management.  相似文献   

Estimation of the 3D correlation structure of an alluvial aquifer from surface-based multi-frequency ground-penetrating radar reflection data     

Zhiwei Xu  James Irving  Kyle Lindsay  John Bradford  Peimin Zhu  Klaus Holliger 《Geophysical Prospecting》2020,68(2):678-689

Knowledge about the stochastic nature of heterogeneity in subsurface hydraulic properties is critical for aquifer characterization and the corresponding prediction of groundwater flow and contaminant transport. Whereas the vertical correlation structure of the heterogeneity is often well constrained by borehole information, the lateral correlation structure is generally unknown because the spacing between boreholes is too large to allow for its meaningful inference. There is, however, evidence to suggest that information on the lateral correlation structure may be extracted from the correlation statistics of the subsurface reflectivity structure imaged by surface-based ground-penetrating radar measurements. To date, case studies involving this approach have been limited to 2D profiles acquired at a single antenna centre frequency in areas with limited complementary information. As a result, the practical reliability of this methodology has been difficult to assess. Here, we extend previous work to 3D and consider reflection ground-penetrating radar data acquired using two antenna centre frequencies at the extensively explored and well-constrained Boise Hydrogeophysical Research Site. We find that the results obtained using the two ground-penetrating radar frequencies are consistent with each other, as well as with information from a number of other studies at the Boise Hydrogeophysical Research Site. In addition, contrary to previous 2D work, our results indicate that the surface-based reflection ground-penetrating radar data are not only sensitive to the aspect ratio of the underlying heterogeneity, but also, albeit to a lesser extent, to the so-called Hurst number, which is a key parameter characterizing the local variability of the fine-scale structure.  相似文献   

生物土壤结皮对风沙土和黄绵土膨胀特性的影响     

王国鹏  肖波  李胜龙  姚小萌  孙福海 《中国沙漠》2020,40(1):97-104

作为重要的土壤物理性质，膨胀性在影响土壤导水性、持水性、抗蚀性以及土壤结构的形成和发育等方面发挥着重要作用。为了探讨生物土壤结皮（BSCs）土壤的膨胀特性及其主要影响因素，针对黄土高原风沙土和黄绵土两种典型土壤，利用膨胀仪测定并比较了有、无藓结皮及其在不同因素（初始含水量、干湿循环、冻融循环、温度）下膨胀率的差异，分析了BSCs对土壤膨胀性的影响及其与环境因素和BSCs性质的关系。结果显示：风沙土上藓结皮的膨胀率为1.93%，较无结皮增加了8.65倍；而黄绵土上藓结皮的膨胀率为2.05%，与无结皮相比降低了76.68%。藓结皮的生物量和厚度与其膨胀率在风沙土上均呈线性正相关关系（P < 0.05），在黄绵土上分别呈二次函数（P=0.02）和线性正相关关系（P=0.02）。初始含水量同时影响了土壤最大膨胀率和稳定膨胀时间，影响程度风沙土远大于黄绵土（包括藓结皮和无结皮）；干湿循环次数对无结皮土壤膨胀率的影响程度大于藓结皮土壤，其中风沙土和黄绵土上无结皮的膨胀率分别是50.00%~620.00%和-2.28%~10.81%，而两种土壤上藓结皮的膨胀率分别是-5.70%~10.88%和-10.24%~-21.46%；冻融循环下4种土壤的膨胀率均有不同程度的降低，降幅为0~18.54%。黄绵土无结皮的膨胀率受温度影响程度较大，50℃下黄绵土无结皮的膨胀率分别是25℃和35℃下的1.17倍和1.21倍。BSCs显著地改变了风沙土和黄绵土表层的膨胀性，其影响的程度和方向取决于土壤类型。同时，BSCs的膨胀性受含水量、温度、干湿以及冻融循环等关键因素影响。  相似文献   

刘公岛海洋牧场底层海水溶解氧浓度的变化特征     

李兆钦  李欣  孙利元  刘子洲  顾艳镇  翟方国  李培良 《海洋与湖沼》2019,50(1):86-99

由于缺乏长期观测资料,前人对山东半岛邻近海域海水溶解氧的时间变化和空间分布特征的研究较少。本文基于威海刘公岛海洋牧场于2016年7月20日至2017年3月14日期间,利用生态环境实时在线观测系统获得的底层海水的温度、盐度、水深、溶解氧数据,分析了该牧场海水溶解氧浓度的时间变化特征及其影响因素,并探讨了低氧灾害发生的可能性。结果表明在观测期间,该牧场海水溶解氧浓度以季节变化为主,冬季最大、夏季最小,其中2月份平均值最高,约为10.86mg/L,8月份平均值最低,约为5.91mg/L。同时海水溶解氧浓度也存在显著的小时变化和日变化,且变化幅度于8月份最大、3月份最小。影响海水溶解氧浓度变化的主要因素是海水温度,溶解氧浓度随着温度的季节性变化而变化。夏季,水体分层会使溶解氧浓度发生大幅度的降低,大风过程对于溶解氧浓度也有一定的影响,通过打破夏季的季节性温跃层使水体发生垂向混合从而为海底提供氧气,但大风过程之后的几天会出现溶解氧浓度降低的现象。本次研究发现刘公岛海洋牧场在观测期间不存在低氧现象。  相似文献   

四川米易海塔地区混合岩型铀矿流体包裹体特征     

郭锐  陈友良  刘凯鹏  郑玉文  胡漾 《矿物学报》2020,40(2):137-148

混合岩型铀矿是康滇地轴上最有希望取得找矿突破的铀矿类型,海塔地区的铀矿化即是该类型铀矿的典型代表。本文针对区内的长英质脉矿石、富晶质铀矿石英脉矿石和含矿热液石英脉中的石英流体包裹体进行了研究。结果表明,海塔地区混合岩型铀矿的成矿作用可分为2个阶段:早期混合岩化热液成矿阶段为高温、中低盐度流体,流体包裹体均一温度集中在380~540℃,盐度变化范围为16.15%~23.18%NaCl eqv,是区内铀成矿的主要阶段;晚期热液叠加改造成矿阶段为中低温、低盐度流体,流体包裹体均一温度集中在140~220℃,盐度变化范围为5.56%~23.18%NaCleqv,是区内富铀矿的形成阶段。流体包裹体的气相成分测试表明,长英质脉矿石石英包裹体中以CH4、CO2为主,其次为H2O和N2;而富晶质铀矿石英脉及含矿热液石英脉石英包裹体中以H2为主,部分含有CO2、CH4、H2O。氢、氧同位素研究表明,早期混合岩化成矿阶段的成矿流体可能为岩浆水与变质水的混合,而晚期热液叠加改造成矿阶段成矿流体中可能有大气降水的加入。  相似文献   

时域反射仪（TDR）测定土壤含水量标定曲线评价与方案推荐     

徐玲玲  高彩虹  王佳铭  金会军  吴青柏  DYCK Miles  何海龙 《冰川冻土》2020,42(1):265-275

时域反射仪（Time Domain Reflectometry）可用于室内和田间快速、 准确、 自动测定土壤含水量， 是目前应用最广泛的土壤含水量测定方法之一。适宜的土壤含水量标定曲线（即土壤表观介电常数和土壤含水量之间的关系）是TDR准确测定土壤含水量的关键。目前文献中存在大量的土壤含水量标定曲线， 但尚未有研究对这些标定曲线进行系统的验证和分析评价。因此， 它们的准确性和适用范围尚不明晰， 严重影响到与土壤含水量测定相关的研究。通过查阅大量国内外文献， 收集整理了一系列土壤含水量标定曲线的经验公式（19个）和半经验半物理模型（5个）， 并利用大量的文献实测数据对其进行综合评价。同时运用均方根差（RMSE）， 平均误差（AD）， 纳什效率系数（NSE）等三个指标对比分析和评价这些标定曲线的准确性和可靠性。研究结果表明： 经验公式中Topp、 Roth（1992）2、 Jacobosen、 Yoshikawa2、 Alharathi模型和半经验模型中Malicki1公式及其修订模型综合性能较好。研究成果可为利用TDR准确测定土壤含水量及土壤含水量标定曲线的选择提供参考和指导。  相似文献   

Calibration of oxygen isotope fractionation and calcite-corundum thermometry in emery at Naxos,Greece     

Rachelle B. Turnier  Yaron Katzir  Kouki Kitajima  Ian J. Orland  Michael J. Spicuzza  John W. Valley 《Journal of Metamorphic Geology》2020,38(1):53-70

Corundum (Crn), including sapphire, occurs in emery pods surrounded by marble on the island of Naxos, Greece. The emery formed from bauxite deposited in karst that was metamorphosed to 400–700°C at 20–15 Ma. Many of these rocks initially appeared well suited for refractory accessory mineral (RAM) thermometry, which uses oxygen isotope fractionation between a RAM – corundum – and a modally dominant phase with faster diffusion of oxygen – calcite (Cc) – to determine peak metamorphic temperatures. However, previous attempts at oxygen isotope thermometry were confounded by highly variable fractionations (Δ¹⁸O) measured at mm-scale and the uncertain calibration of Δ¹⁸O(Cc-Crn) versus temperature. Secondary ion mass spectrometry (SIMS) permits in situ analysis of δ¹⁸O in corundum and calcite at the 10-μm scale in adjacent grains where textures suggest peak metamorphic equilibrium was attained. SIMS analyses of adjacent mineral pairs in eight rocks yield values of Δ(Cc-Crn) that systematically decrease from 7.2 to 2.9‰ at higher metamorphic grade. Pairing these data with independent temperature estimates from mineral isograds yields an empirical calibration of 1,000 lnα(Cc-Crn) = 2.72 ± 0.3 × 10⁶/T² (T in K). The new fractionations (2.7‰ at 1,000 K) are significantly smaller than those calculated from the modified increment method (6.5‰ at 1,000 K; Zheng, Geochimica et Cosmochimica Acta, 1991, 55:2299–2307; Zheng, Mineral Mag, 1994, 58A:1000–1001), which yield unreasonably high temperatures of 630 to 1,140°C when applied to the new Naxos data. The new calibration of Δ(Cc-Crn) can be combined with published fractionations to calculate A-factors for corundum versus a range of 14 other minerals. These new fractionation factors can be used for thermometry or to constrain the genesis of corundum. A compilation of gem corundum δ¹⁸O values shows that many igneous sapphires, including important deposits of basalt-associated sapphire, are mildly elevated in δ¹⁸O relative to the calculated range in equilibrium with mantle values (4.4–5.7‰) and formed from evolved magmas.  相似文献   

土石混合体分形几何特征与强度演化特征     

曾晋 《地质与勘探》2020,56(3):590-596

针对土石混合体的结构性特点,以含石量为20%、30%、40%、50%、60%的土石混合体为研究对象,基于多重分形原理研究多重分形特征,研究分形维数与强度之间的关系。研究表明,土石混合体具有双重分形特征,不同尺度条件下具有不同分形指标,包括块石粒度、土体粒度以及平均粒度等分形维数,与含石量相关。单轴压缩试验表明,抗压强度随含石量增加呈现先增大后减小的趋势,根据单维分形特征,确定最优含石量约为40%。建立了含石量、不同分形维数指标与抗压强度之间的关系,分析了双重因素综合影响下抗压强度的变化特征,确定了含石量与分形维数之间存在最优区域。  相似文献   

西藏雄村斑岩型铜(金)矿床Ⅰ、Ⅱ号矿体热液黑云母特征及地质意义     

肖鸿天  谢富伟  郎兴海  冉凤琴 《岩石矿物学杂志》2020,39(4):469-480

雄村铜(金)矿区位于西藏冈底斯成矿带中段南缘,由Ⅰ、Ⅱ、Ⅲ号矿体和多个矿化体组成。本文以Ⅰ、Ⅱ号矿体钾硅酸盐化蚀变带内的热液黑云母为研究对象,采用光薄片镜下鉴定、电子探针等分析方法,系统研究了热液黑云母的产状和成分特征。结果显示,雄村矿区Ⅰ号矿体黑云母类型主要为金云母和镁质黑云母;Ⅱ号矿体黑云母类型为镁质黑云母。两个矿体黑云母都具有低Ti(TiO_2 3%)、高Al(Al_2O_315%)的特点,且具有较高的MgO含量,Mg/Fe0.5,K/Na10,显示了与矿化良好的相关性。Ⅰ号矿体热液黑云母平均结晶温度470℃,氧逸度位于镍-氧化镍缓冲剂与磁铁矿-钛铁矿缓冲剂之间(NNO—HM);Ⅱ号矿体热液黑云母平均结晶温度234℃,氧逸度位于镍-氧化镍缓冲剂与铁橄榄石-石英-磁铁矿缓冲剂之间(NNO—FQM),说明Ⅰ号矿体形成于较高温、高氧逸度的热液系统,Ⅱ号矿体形成于相对较低温、低氧逸度的热液系统。此外,Ⅰ号矿体热液黑云母Ⅳ(F)值介于0.61～2.72之间,平均值1.26,Ⅳ(Cl)值介于-5.49～-4.53之间,平均值-5.03,Ⅳ(F/Cl)值介于5.63～7.89之间,平均值6.29;Ⅱ号矿体热液黑云母Ⅳ(F)值介于1.83～3.32之间,平均值2.66,Ⅳ(Cl)值介于-5.64～-4.89之间,平均值-5.31,Ⅳ(F/Cl)值介于7.14～8.68之间,平均值7.97,说明Ⅰ、Ⅱ号矿体都形成于富Cl的热液系统,且Ⅱ号矿体热液较Ⅰ号矿体更富Cl,贫F。富Cl流体易萃取流体中的Cu和Au等金属元素并以Cl的络合物形式运移,在沿构造裂隙向上运移的过程中,物理化学条件发生改变,使得流体中金属元素络合物溶解度降低,促使硫化物沉淀成矿。  相似文献   

Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献