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1.
Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   
2.
The groundwater divide is a key feature of river basins and significantly influenced by subsurface hydrological processes. For an unconfined aquifer between two parallel rivers or ditches, it has long been defined as the top of the water table based on the Dupuit–Forchheimer approximation. However, the exact groundwater divide is subject to the interface between two local flow systems transporting groundwater to rivers from the infiltration recharge. This study contributes a new analytical model for two-dimensional groundwater flow between rivers of different water levels. The flownet is delineated in the model to identify groundwater flow systems and the exact groundwater divide. Formulas with two dimensionless parameters are derived to determine the distributed hydraulic head, the top of the water table and the groundwater divide. The locations of the groundwater divide and the top of the water table are not the same. The distance between them in horizontal can reach up to 8.9% of the distance between rivers. Numerical verifications indicate that simplifications in the analytical model do not significantly cause misestimates in the location of the groundwater divide. In contrast, the Dupuit–Forchheimer approximation yields an incorrect water table shape. The new analytical model is applied to investigate groundwater divides in the Loess Plateau, China, with a Monte Carlo simulation process taking into account the uncertainties in the parameters.  相似文献   
3.
The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ34S-SO4) and oxygen (δ18O-SO4) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO3 film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO4 was not representative of the actual SO4 concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO4 in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   
4.
京津冀地热资源梯级综合开发利用(献县)科研基地大地构造位置位于华北平原沧县台拱带之献县断凸,利用其地下蓟县系岩溶裂隙热储层热水开展中低温地热发电与综合梯级利用研究。地热发电装机容量280 kW,采用ORC向心透平膨胀技术,系统工质为R245fa。分别于2018年2月4—6日(冬季)、2018年3月6—16日(春季)进行两次试运行,累计发电时长274h,累计发电量36956kWh,平均发电效率9.1%,最高10.4%。发电效率高于我国已有中低温地热发电项目,在目前国际中低温ORC地热发电项目中处于较高水平。试运行期间发电机组整体运行效果较好且运行稳定,冬季地热发电机组运行效果好于春季。科研基地建设完成后,将进行发电、供暖、地热生态园三级利用,按照90~95/25℃的地热水热能潜力,综合发电供暖两级利用计算能源综合利用率将达70%~76%。  相似文献   
5.
本文以渭河盆地地温场为研究对象,在收集补充新地热井资料及分析测试样品的基础上,通过盆地深部结构、构造特征、地温场特征、热储层特征、地热资源量等分析,建立了盆地不同岩性岩石热导率与深度关系图版,确定了盆地地温场变化规律及地热田控制因素,提出了渭河盆地地热田形成模式。评价了盆地地热资源有利区,为盆地后续的开发利用提供了理论支持。研究认为渭河盆地热地温梯度分布在2.34~5.85℃/100m之间,平均地温梯度为3.50℃/100m,代表性大地热流68.33mw/m~2,地温梯度及不同深度地层温度具有东高西低、南高北低的特点。热导率总体上具有随深度的增加,逐渐增大的规律,热导率随深度增加主要受压实程度增强控制。相同深度条件下泥岩热导率最低,砂岩热导率居中、白云岩热导率最高。渭河盆地主要为层状地热田,盆地内地热通过热传导及热对流两种方式进行传递,以热传导为主。渭河盆地地热资源丰富,热储层可分为三种类型:①新生界砂岩孔隙型;②下古生界碳酸盐岩岩溶型;③断裂型。渭河盆地地热资源有利区主要分布于西安凹陷、固市凹陷。盆地地温场及地热田分布与莫霍面、软流圈上隆、岩石圈厚度减薄的深部背景密切相关,主要受地热传导和深大断裂热对流控制,是岩石圈深部结构、盆地构造、基底岩性、储盖组合等多因素共同作用下形成的。最后结合当前渭河盆地地热资源开发利用现状及存在问题,提出了地热开发利用建议。  相似文献   
6.
为构建温度示踪方法测算地下水流速技术体系,并应用于区域地下水资源评价,基于最小二乘法和垂向一维非稳定流水-热运移方程数值解法,提出地表暖化情形下地下水流速计算方法,并对雷州半岛东北部地下水流速进行测算。结果表明:研究区域地下水补给速度为0.796 m/a,入渗以西北部降水和运河渗漏为主;地下水排泄速度为0.269 m/a,排泄入海主要发生在东海岛、南三岛和硵州岛附近。温度示踪解析区域地下水流动情况与地下水位分布情况基本一致,观测和计算地温数据具有较强相关性(R2>0.50)和较低均方根误差(均值0.748),表明提出方法率定得到的地下水流速具有较强的可靠性。参数敏感性分析结果表明,地质体热扩散率和地表温度均对地温计算结果产生较明显的影响,参数的准确率定对利用地温计算地下水流速十分重要。  相似文献   
7.
为了防止商业综合体建设过剩,形成商业综合体之间的恶性竞争。本文基于微信易出行插件里面的城市热力图数据,以杭州市5个商业综合体为例,获取可以量化的热力值数据,对不同类型的商业综合体活力影响因素进行对比分析研究。研究发现:① 城市商业综合体布局密度、周边用地用途、销售模式、内部功能布局以及内部空间活力5个要素对商业综合体活力的影响最明显;② 商业综合体的高密度布局对其活力存在抑制作用,通过对比各个服务半径内的商业综合体的活力变化,发现商业综合体合理的服务半径应该大于1.0 km。商业综合体周边的居住用地、广场和公园用地对其活力具有增强作用,办公用地对商业综合体活力的影响较弱;③ 针对不同消费对象制定的不同销售模式,也会对商业综合体活力变化产生显著影响;④ 在公共活动空间相对缺乏的区域内,以零售为主且兼具城市公共活动空间的商业综合体比以主力店为主的商业综合体的活力更高,空间利用率越高的商业综合体活力也越高,商业综合体承担部分城市公共活动空间的职能对商业综合体的活力起到了提升作用。  相似文献   
8.
地下水是张掖盆地的重要水资源,其硝酸盐污染尚未得到足够重视。对张掖盆地2004、2015年地下水硝酸盐浓度进行了系统分析,并采用美国环境保护署(USEPA)推荐的健康风险评价模型评估了地下水硝酸盐的健康风险。结果表明:自2004年以来张掖盆地地下水硝酸盐污染日趋严重。2015年硝酸盐浓度最高已达到283.32 mg·L-1,17.61%的采样点硝酸盐氮浓度超过GB5749-2006《生活饮用水卫生标准》中饮用地下水限量值(20 mg·L-1)。研究区人群经皮肤接触途径摄入硝酸盐的健康风险在可接受水平,而饮水摄入硝酸盐的健康风险较高,总风险中饮水途径引起健康风险的贡献率占99.40%,远大于皮肤接触途径。儿童经饮水摄入和皮肤接触两种途径的健康风险均显著高于成人,分别为成人的1.544倍和1.039倍。32.39%的采样点地下水硝酸盐对儿童的健康风险超出了可接受水平,14.79%的采样点地下水硝酸盐对成人的健康风险不可接受。甘州区城区、临泽县北部边缘及高台县城区周围硝酸盐浓度最高,这些区域内所有人群都面临硝酸盐引发的高健康风险,其余区域硝酸盐引发的健康风险相对较低。  相似文献   
9.
Monitoring of the fluctuations of groundwater storage is particularly important in arid and semi-arid regions where water scarcity brings about various challenges. Remote sensing data and techniques play a preponderant role in developing solutions to environmental problems. The launch of Gravity Recovery and Climate Experiment (GRACE) satellites has eased the remote monitoring and evaluation of groundwater resources with an unprecedented precision over large scales. Within the scope of the current study, the latest release (RL06) of GRACE mass concentrations (Mascons) from Jet Propulsion Laboratory (JPL) dataset as well as Global Land Data Assimilation System (GLDAS) models of Noah and Catchment Land Surface Model (CLSM) were used to provide Groundwater Storage Anomalies (GWSA) over Turkey. The temporal interactions of the estimated GWSA with the climatic variables of precipitation and temperature (derived from the reanalysis datasets of CHELSA [Climatologies at High resolution for the Earth's Land Surface Areas] and FLDAS [the Famine Early Warning Systems Network Land Data Assimilation System], respectively) were investigated statistically. The results suggest that there is a descending trend (from 2003 to 2016) for Terrestrial Water Storage Anomalies (TWSA) and GWSA over Turkey with a total loss of 11 and 6 cm of water, respectively. The statistical analysis results also indicate that the monthly variations of GWSA over Turkey are highly correlated with precipitation and temperature at 2-month lag. The analysis of the climatology (long-term) values of monthly GWSA, precipitation and temperature also revealed high agreement between the variables.  相似文献   
10.
The transition area between rivers and their adjacent riparian aquifers, which may comprise the hyporheic zone, hosts important biochemical reactions, which control water quality. The rates of these reactions and metabolic processes are temperature dependent. Yet the thermal dynamics of riparian aquifers, especially during flooding and dynamic groundwater flow conditions, has seldom been studied. Thus, we investigated heat transport in riparian aquifers during 3 flood events of different magnitudes at 2 sites along the same river. River and riparian aquifer temperature and water‐level data along the Lower Colorado River in Central Texas, USA, were monitored across 2‐dimensional vertical sections perpendicular to the bank. At the downstream site, preflood temperature penetration distance into the bank suggested that advective heat transport from lateral hyporheic exchange of river water into the riparian aquifer was occurring during relatively steady low‐flow river conditions. Although a small (20‐cm stage increase) dam‐controlled flood pulse had no observable influence on groundwater temperature, larger floods (40‐cm and >3‐m stage increases) caused lateral movement of distinct heat plumes away from the river during flood stage, which then retreated back towards the river after flood recession. These plumes result from advective heat transport caused by flood waters being forced into the riparian aquifer. These flood‐induced temperature responses were controlled by the size of the flood, river water temperature during the flood, and local factors at the study sites, such as topography and local ambient water table configuration. For the intermediate and large floods, the thermal disturbance in the riparian aquifer lasted days after flood waters receded. Large floods therefore have impacts on the temperature regime of riparian aquifers lasting long beyond the flood's timescale. These persistent thermal disturbances may have a significant impact on biochemical reaction rates, nutrient cycling, and ecological niches in the river corridor.  相似文献   
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