Interstitial water chemistry of the inner continental shelf sediments off the gironde estuary     

H. El Ghobary 《Estuarine, Coastal and Shelf Science》1983,16(6)

The interstitial water composition ( , alkalinity, Ca²⁺, Mg²⁺, Sr²⁺, Na⁺, K⁺) and the cation exchange capacity (CEC) were determined for the muddy sediments of the continental shelf off the Gironde Estuary (France), in the area where the sediment represents the deposit of the muddy suspension of the river. In comparison with seawater concentrations, the pore waters below 10 cm depth, show depletions of and Ca²⁺ and below a 30 cm depth show depletions of Mg²⁺. Inversely, the upper 10 cm an enrichment of Ca²⁺ concentration, and an increase of K⁺ concentration to a 40 cm depth. High values of are observed at the top 4 cm. Alkalinity enrichment is observed along the length of the core. Applying the alkalinity models for the sediment below a 10 cm depth demonstrates generally that calculated alkalinities are higher than the measured ones. Ca²⁺ dissolution occurs at the first 10 cm and authigenic carbonate precipitation starts beneath that level. Mg²⁺ depletion is accompanied by bicarbonate loss. This proves that Mg²⁺ depletion is due to a Mg-silicate reaction. The result of the CEC does not confirm the Mg²⁺ uptake by clay minerals in exchangeable site, under reducing conditions. Diffusion and bioturbation play an important role in the pore water concentration at the top of the core.  相似文献   

低硼氢氧化镁的制备及热分解动力学参数     

高荣杰  冯丽娟  杜敏  宁滨  梁丽 《中国海洋大学学报(自然科学版)》2002,32(5):789-794

本文以水合氯化镁、工业氨水为原料制备出了低硼含量的纯度 >99%的氢氧化镁和氧化镁。利用差热 -热重 (DTA- TG)、X-射线衍射 (XRD)、透射电子显微镜 (TEM)等手段 ,对氢氧化镁的热稳定性、相结构、表观状态以及脱水动力学参数进行了分析。结果为 :氢氧化镁以束状纤维和片状粉末共存 ,在 6 2 3K基本完成脱水反应生成氧化镁 ,其脱水反应的表观活化能 E为135 .4 k J· mol-1,指前因子 A为 5 .15× 10 10 ,反应级数 n为 1.10  相似文献   

Growth Aspects and Magnesium Carbonate Concentrations of the Reef Building Octocoral Heliopora coerulea (Pallas) after Transplantation     

B. Velimirov 《Marine Ecology》1980,1(2):155-168

Abstract. An experiment to test C have's hypothesis on temperature dependent MgCO₃ concentrations in marine calcareous skeletons was undertaken by transplanting colonies of Heliopora coerulea. The corals were transferred from a shallow lagoon with high average temperatures to the outer bottom of a fringing reef, 16 m depth, with low average temperatures. Against expectation, a statistically significant increase of average mol % concentrations from 0.48 to 0.54 % for upper growth regions and from 0.49 to 0.62% for lower growth regions was obtained. Temperature records during the experimentation period and the above data indicate that the mol% MgCO₃ concentration in the skeleton of living Heliopora colonies increases when transplanted to an environment with a lower temperature average than that of their original growth site, and with seasonal temperature fluctuations which are smaller in the experimental site than in the control site. Temperature fluctuations at the control site were up to 2.5 times greater than at the experimental site for most of the observation months. This supports the conclusion that the parameters a) minimum temperature and b) temperature stability of the environment are essential for the incorporation of Mg into the carbonate skeleton matrix of marine organisms. Within this study the results of a quantitative chemical analysis of the carbonate skeleton of H. coerulea are presented and growth data of transplanted colonies compared with those from the control site.  相似文献   

新疆罗布泊盐湖卤水资源综合开发研究   总被引：10，自引：3，他引：7  

李浩  唐中凡  刘传福  雷光元 《地球学报》2008,29(4):517-524

罗布泊盐湖赋存有丰富的含钾硫酸镁亚型卤水,现已探明仅罗北凹地区段孔隙度储量2.67×109t(折合KCl),属特大型钾盐卤水矿藏,是生产硫酸钾的理想原料;此外,卤水中含有丰富的钠、镁、锂、硼等资源,综合回收利用价值较大。本文针对罗布泊盐湖卤水资源,在有效利用盐湖钾资源同时,加快其他共生资源的综合开发进程,将新疆罗布泊盐湖资源开发建设推向持续、合理、有效、高值的循环经济发展的道路,为国家西部经济开发做出贡献。  相似文献   

微波消解-火焰原子吸收光谱法测定石英砂中的氧化钙和氧化镁     

鲁青庆 《岩矿测试》2005,24(4):314-316

采用微波消解-硼酸络合-火焰原子吸收光谱法测定石英砂中的氧化钙和氧化镁。样品在MK-Ⅲ型实验室微波炉上消解,消解压力为2.0 MPa、消解时间为5 m in,以硼酸络合消除氢氟酸的影响。方法已用于实际样品的测定,7次测定的相对标准偏差(RSD)小于5%,加标回收率为95.0%~104.2%。  相似文献   

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials   总被引：6，自引：1，他引：6  

Jean Carignan  Damien Cardinal  Anton Eisenhauer  Albert Galy  Mark Rehkamper  Frank Wombacher  Nathalie Vigier 《Geostandards and Geoanalytical Research》2004,28(1):139-148

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.  相似文献   

离子质谱计测定地质样品中镁同位素组成方法学研究     

周瑶琪  柴之芳 《岩矿测试》1995,14(1):7-14

应用信通公司研制的离子质谱计（ＳＴ－ＩＭＳ），建立了地质样品镁同位素分析的实验流程和误差分析方法，为进一步分析微量地质样品中镁同位素组成和分布奠定了基础。  相似文献   

磷矿石中磷、钙、镁、锶、氟测定方法评述   总被引：2，自引：0，他引：2  

孙琳 《贵州地质》2007,24(4):322-324

本文系统分析了磷矿石高含量磷、钙、镁、锶、氟诸元素存在时对其测定的相互影响及其测定中存在的问题,比较全面地总结了国内分析工作者针对该问题,对诸难测元素在常规分析方法方面的工作进展。  相似文献   

Soils and Land use on Lithologically Diverse Ophiolitic Alluvia on the Coastal Plain of Palawan,Philippines     

I .C. Baillie  N. B. Inciong  P. M. Evangelista 《Singapore journal of tropical geography》2001,22(1):1-14

The soils on the southeastern coastal plain of Palawan, Philippines are developed on alluvium derived from various lithologies of the Palawan Ophiolitic Complex. There is little lateral mixing of the alluvium. The soil pattern is interpreted as the result of increasing weathering and leaching with age on deposits of different lithological origins. In the ultramafic catchment the younger soils are infertile due to several unfavourable characteristics, including high contents of heavy metals and Mg, deficiencies of P and micro‐nutrients, and impermeability. These soils improve with increased weathering and leaching, and the older soils have better physical and Mg characteristics. In felsic alluvia the reverse is found, and the soils on younger deposits are the most fertile, while the older soils have unfavourable combinations of subsoil compaction, acidity and dominance by aluminium. These patterns are reflected in the current land use, with areas of sparse settlement and cultivation on the less fertile soils on younger ultramafic and older felsic alluvia. These areas have been avoided or abandoned, rather than overlooked, by farmers and cannot be considered as “empty lands”. Their sustainable development will require careful management. Most of the more fertile land is already cultivated.  相似文献   

新疆北部的两类埃达克岩   总被引：27，自引：32，他引：27  

赵振华 王强熊小林  张海祥牛贺才许继峰  白正华乔玉楼 《岩石学报》2006,22(5):1249-1265

新疆北部有两类埃达克岩，一是俯冲型，形成于早、中泥盆世-早石炭世晚期（≥320Ma），包括了埃达克岩、富Nb玄武岩、高（富）Mg安山岩。第二类埃达克岩是底侵型，形成于中晚二叠世（≤280Ma）。第一类埃达克岩分布于西天山的阿拉套山、博罗科努山，中天山的骆驼沟和巴仑台，东天山的土屋-延东，阿尔泰山陆缘南富蕴-青河南，准噶尔盆地中部陆梁，克拉玛依等地。在阿尔泰陆缘南，苦橄岩与埃达克岩、富Nb玄武岩和高（富）Mg安山岩密切组合。第二类埃达克岩分布于西天山的阿吾拉勒山和东天山的三岔口，未发现富Nb玄武岩和高（富）Mg安山岩组合。俯冲型埃达克岩、富Nb玄武岩和高（富）Mg安山岩的高Sr低Y、Yb、富Eu及高εNd（t）（＋1．5～＋10．0），低（^87Sr／^86Sr）；（〈0．7070）的同位素组成，均一致表明其源区物质为洋壳板片，部分为地幔楔、弧前棱柱，产于岛弧环境；而底侵型埃达克岩源于底侵的幔源玄武质物质，形成于后造山环境。两类埃达克岩及其组合岩石的地质及地球化学特点，展示了中亚型造山在本区晚古生代陆壳增生作用的多样性：在增生构造过程上，有洋壳板片的斜俯冲、俯冲板片的撕裂、板片窗、俯冲剥蚀及玄武质物质的底侵作用等；在增生方向上，有洋壳板片的侧向斜俯冲，也有玄武质物质垂向上底侵于壳-幔边界；在增生物质上，有洋壳板片、地幔楔、受地幔楔混染的洋壳板片熔体，弧前棱柱、地幔楔受板片熔体交代后形成熔体及底侵的幔源玄武质物质。与两类埃达克岩有关，尤其是第一类埃达克岩及其组合岩石，在本区广泛发育了Cu、Au成矿作用，其中部分达到大型-超大型规模。因此．对埃达克岩及其组合岩石的识别及相关Cu、Au成矿作用的找矿勘探应予以足够重视。  相似文献