Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers     

Chen Wang  Martin A. Briggs  Frederick D. Day-Lewis  Lee D. Slater 《水文研究》2021,35(5):e14184

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   

The thermal maturity of sedimentary basins as revealed by magnetic mineralogy     

Mansour M. Abdelmalak  Stéphane Polteau 《Basin Research》2020,32(6):1510-1531

The thermal evolution of sedimentary basins is usually constrained by maturity data, which is interpreted from Rock-Eval pyrolysis and vitrinite reflectance analytical results on field or boreholes samples. However, some thermal evolution models may be inaccurate due to the use of elevated maturities measured in samples collected within an undetected metamorphic contact aureole surrounding a magmatic intrusion. In this context, we investigate the maturity and magnetic mineralogy of 16 claystone samples from Disko-Svartenhuk Basin, part of the SE Baffin Bay volcanic margin. Samples were collected within thermal contact metamorphic aureoles near magma intrusions, as well as equivalent reference samples not affected by intrusions. Rock-Eval pyrolysis (T_max), and vitrinite reflectance (Ro) analysis were performed to assess the thermal maturity, which lies in the oil window when 435°C ≤ T_max ≤ 470°C and 0.6%–0.7% ≤ Ro ≤ 1.3%. In addition, we performed low- (<300K) and high-temperature (>300K) investigations of isothermal remanent magnetization to assess the magnetic mineralogy of the selected samples. The maturity results (0.37% ≤ Ro ≤ 2%, 22°C ≤ T_max ≤ 604°C) show a predominance of immature to early mature Type III organic matter, but do not reliably identify the contact aureole when compared to the reference samples. The magnetic assemblage of the immature samples consists of iron sulphide (greigite), goethite and oxidized or non-stoichiometric magnetite. The magnetic assemblage of the early mature to mature samples consists of stoichiometric magnetite and fine-grained pyrrhotite (<1 μm). These results document the disappearance of the iron sulphide (greigite) and increase in content of magnetite during normal burial. On the other hand, magnetite is interpreted to be the dominant magnetic mineral inside the contact aureole surrounding dyke/sill intrusions where palaeotemperatures indicate mature to over-mature state. Interestingly, the iron sulphide (greigite) is still detected in the contact aureole where palaeotemperatures exceeded 130°C. Therefore, the magnetic mineralogy is a sensitive method that can characterize normal burial history, as well as identify hidden metamorphic contact aureoles where the iron sulphide greigite is present at temperatures beyond its stability field.  相似文献   

高强耐热铝合金钻杆材料优选          下载免费PDF全文

梁健  尹浩  孙建华  李亚红  王成彪  张金昌 《探矿工程》2020,47(4):65-71

铝合金钻杆的使用性能是制约深部钻探技术发展的“瓶颈”。本文综合考虑孔内工况因素和钻杆性能因素，以钻柱组合设计为基础准则，从特深孔钻探工程技术需求出发，开展了高强耐温铝合金钻杆材质选择和评价的试验研究。试验结果表明：2219铝合金固溶时效制度分别为535 ℃/1 h、165 ℃/20 h，2618铝合金固溶时效制度分别为530 ℃/1 h、200 ℃/20 h；2219铝合金在高温长时间暴露后的室温力学性能优于2618铝合金，在高温瞬时条件下的力学性能劣于2618铝合金；2219铝合金中含有Zr，该元素在热暴露过程中起到减缓溶质扩散速率的作用，这对提高热暴露后的剩余强度是有利的。  相似文献   

利用双视角消除太阳矢量磁场观测中的180◦不确定性          下载免费PDF全文

周茹芸  汪毓明  宿英娜  毕少兰  刘睿  季海生 《天文学报》2021,62(4):41

随着"环日轨道器"(Solar Orbiter, SO)的在轨运行,太阳磁场观测进入了双视角遥测的时代.对利用太阳磁场的双视角观测改正矢量磁图中存在的横场(垂直于视线方向的磁场分量) 180°不确定性进行了模拟,首先模拟了对解析解得到磁图的双视角观测,然后利用"日震学和磁学成像仪"(Helioseismic and Magnetic Imager, HMI)在不同时间观测到的一个老化黑子的磁图模拟了双视角观测.发现要改正一个磁图中横场方向的180°不确定性,在观测上只需要另外一个平行于视线方向的磁场即纵向磁场观测的协助.利用HMI的磁场观测模拟,估算显示30°的张角能够改正50 Gs磁场中的180°不确定性.更大的张角虽然更有利于更弱磁场的改正,但是考虑到投影效应的不利影响, 30°左右的张角应该是未来空间设备进行多视角观测太阳磁场的最佳张角.  相似文献   

基于稀疏表示的地面磁共振信号提取方法          下载免费PDF全文

王琦  田宝凤  张健  蒋川东 《地球物理学报》2018,61(8):3446-3456

在多孔隙含水层中地面磁共振（surface nuclear magnetic resonance，SNMR）信号呈现多弛豫衰减特性，常规盲源分离方法和单指数拟合方法引起信号严重失真和信息缺失等问题.本文提出了基于稀疏表示的随机噪声背景下多弛豫SNMR信号的提取方法.根据SNMR信号的衰减特征，设计了精确刻画SNMR信号且与随机噪声不相关的离散衰减余弦冗余字典.其次，针对多弛豫SNMR信号稀疏度未知的问题，通过设置合理的残差比阈值控制迭代次数，改进了广义正交匹配追踪（generalized orthogonal matching pursuit，gOMP）算法，使得该方法应用于SNMR信号的提取时，具有更好的自适应性和普适性.再次，鉴于SNMR测量数据为多次独立重复采集的结果，提出了基于数据流的SNMR信号提取策略，在提高算法鲁棒性的同时，保证了信号提取结果的唯一性.最后，通过仿真和实测数据证明了基于gOMP算法的稀疏表示方法可以显著地提升多弛豫SNMR信号的提取质量，降低随机噪声对含水层反演结果的影响，提高SNMR探测能力.  相似文献   

Measuring hydrological connectivity inside a soil by low field nuclear magnetic resonance relaxometry   总被引：1，自引：0，他引：1       下载免费PDF全文

Pellegrino Conte  Vito Ferro 《水文研究》2018,32(1):93-101

Hydrological connectivity inside the soil is related to the spatial patterns inside the soil (i.e., the structural connectivity). This, in turn, is directly associated with the physical and the chemical processes at a molecular level (i.e., the functional connectivity). Nuclear magnetic resonance (NMR) relaxometry can be successfully applied to reveal both structural and functional components of soil hydrological connectivity. In the present study, the low field NMR relaxometry was applied on water suspended soils sampled at the upstream‐ and downstream‐end of three different length plots. Also the sediments collected from the storage tanks at the end of each plot were water suspended and monitored by NMR relaxometry. The results from the NMR investigations were elaborated by using a mathematical approach in order to quantify both the functional and structural connectivity components. In particular, following integration of the T₁ distribution curve, an S‐shaped curve was obtained. It revealed two plateaus corresponding to the shortest (low component) and the longest (high component) intervals of relaxation times, respectively. According to relaxometry theory, the two T₁ intervals, associated to the different plateaus, were attributed to micro and macro soil pores, respectively. The two T₁ intervals were used to define a functional connectivity index, while the central part of the S‐shaped distribution was used to define a structural connectivity index. Here we provide the physical meaning of the our mathematical approach, thereby revealing that functional connectivity index increases with plot length, as a result of a selective eroded particle transport. Moreover, the relationship structural connectivity index versus plot length resulted quasi‐independent of grainsize distribution, whereas the values of the structural connectivity index for the sediment samples resulted lower than those obtained for the corresponding soils.  相似文献   

珠江三角洲海相沉积软土压缩和剪切变形特性试验研究   总被引：3，自引：0，他引：3       下载免费PDF全文

张岩  耿济世  毛磊  刘芙荣 《地震工程学报》2018,40(4):745-751

为了研究近代海相沉积软土的变形特征,本文对珠江三角洲河口地区的全新世海相沉积的软土进行了室内单轴压缩与不同围压下作用下的三轴固结不排水(CU)、不固结不排水(UU)的剪切试验。试验结果表明:原状土和重塑土样的孔隙比随压力的增大而下降,且与加压方式有密切关系,加压幅度越小,土的扰动破坏越小;原状土样固结系数随着压力增加而递减,整体近似符合指数函数分布,重塑土样固结系数随着压力增加逐渐增大,整体近似符合线性函数分布。在相同的固结压力下,原状土样的强度低于重塑土样的强度。土样的应力应变曲线为应变硬化型,且围压对重塑土的影响小于原状土。  相似文献   

脐带缆螺旋滑移分析及力学性能研究   总被引：1，自引：0，他引：1  

李英  吴潘  冯雅萍  曹静萱 《海洋工程》2018,36(6):58-68

针对脐带缆内部螺旋层,应用Darboux标架建立螺旋结构空间坐标系,推导弯曲载荷下螺旋结构的局部变形和滑移。考虑螺旋构件间的接触和摩擦作用,建立螺旋结构的受力平衡偏微分方程,并研究螺旋角和摩擦系数对螺旋结构滑移的影响。基于同层螺旋结构本构关系相同假设,将所有螺旋结构力学性能线性叠加,拟合脐带缆整体弯曲刚度。运用建立的理论解析方法,对某双层铠装脐带缆的力学性能进行研究,并与数值模拟结果进行对比验证。对比结果表明,理论解析得到的螺旋滑移结果与数值模拟结果一致,理论解析得到的脐带缆弯曲刚度与数值模拟结果在全滑动阶段比较接近。  相似文献   

珊瑚颗粒形状对钙质粗粒土的压缩性能影响     

张斌  柴寿喜  魏厚振  孟庆山  陈杨 《工程地质学报》2020,28(1):85-93

珊瑚颗粒形状不规则是其显著区别于陆源土的一大特征。为揭示珊瑚颗粒形状对钙质粗粒土压缩性能的影响,人工挑选出不同形状(块状、枝状、棒状、片状)的珊瑚颗粒,以块状颗粒为基础,与其他3种不同形状的粗颗粒任意一种混合,控制不同颗粒形状配比制成钙质粗粒土试样,完成室内压缩试验,对比分析试验前后珊瑚颗粒的圆度、长宽比、扁平度和凹凸度等形状参数,评价颗粒形状对压缩性能的影响。结果表明:(1)粒径为10~20 mm钙质粗粒土的压缩模量是4~5. 5 MPa,回弹系数为42~53;(2)随枝状、棒状或片状颗粒掺量的增加(0、10%、20%、30%),试样压缩模量呈小幅波状变化,回弹系数呈持续减小趋势;(3)各加载区间应力-应变曲线包括应力快速增长阶段、应力-应变同步增长阶段、应变增长阶段共3个阶段和1个稳定点;(4)随枝状颗粒掺量的增加,试样的长宽比和凹凸度逐渐增加,圆度和扁平度基本无变化;因颗粒破碎的影响,试验后试样的长宽比及扁平度有所增加,圆度及凹凸度则有所减小。选择钙质粗粒土地基时,应考虑其压缩性能,避免施工初期的快速加载。  相似文献   

临夏盆地新近纪郭泥沟剖面磁组构特征及其环境意义          下载免费PDF全文

孔艳芬  孙蕗  沈中山  葛俊逸  邓成龙 《地球物理学报》2018,61(11):4518-4529

临夏盆地在东亚新生代地层、古气候、古生物研究方面占有举足轻重的地位.本文对盆地东部的郭泥沟剖面进行了详细的岩石磁学和磁组构研究，以揭示从早中新世到早上新世临夏盆地的沉积演化过程.郭泥沟剖面沉积物中的磁性矿物有磁铁矿、磁赤铁矿、赤铁矿和针铁矿，但剩磁载体以磁铁矿和赤铁矿为主.从上庄组和东乡组的褐红色粉砂质粘土到柳树组和何王家组的褐黄色粘土，赤铁矿含量呈现降低的趋势，与沉积物颜色变化一致.郭泥沟剖面沉积物磁组构类型为正常沉积磁组构.结合岩石磁学结果和磁组构参数特征可揭示临夏盆地早中新世-早上新世沉积的演化过程：早中新世上庄组为稳定湖相沉积，古水流方向为NNW，与南北向的大夏河方向一致；中中新世气候发生较明显的干湿波动，形成了东乡组的褐红色湖相粉砂质粘土夹粉砂、砂和青灰色泥灰质粘土条带，古水流方向主要为NNW，沉积过程主要受大夏河控制；中中新世晚期，受青藏高原构造运动影响，沉积相由湖相细粒沉积物转变为虎家梁组河流相砂砾层；同时，盆地的水动力条件也发生改变，晚中新世柳树组湖相沉积过程同时受南北向大夏河和东西向洮河控制，两个方向近垂直的河流共同作用导致柳树组内沉积各向异性度较低，面理和线理均不发育，磁化率最大轴偏角分布比较分散，磁组构确定的古流向为东西向和南北向；早上新世期间，由于受青藏高原隆升影响，沉积了何王家组下部的河流相砂砾层；受构造抬升影响，大夏河重新主导何王家组上部洪泛平原相沉积过程，水动力条件较为单一稳定，古流向主要为N向，与大夏河流向一致.  相似文献