琼胶/SiO₂复合纤维的制备及性能研究     

吴大伟  颜廷波  李腾飞  王应霞  肖玉斌  薛志欣  夏延致 《海洋科学》2020,44(10):39-45

利用湿法纺丝技术制备了琼胶/SiO₂复合纤维，对琼胶分子在溶液中的分散性、纺丝液流变性、纤维的形貌、化学结构分别用DLS、旋转黏度计、SEM、FTIR和XRD进行了表征，并对纤维的力学性能、热性能和吸湿性能进行了测定。研究结果表明：琼胶分子在溶液中呈纳米尺度分布，纺丝液具有良好的流动性；琼胶/纳米SiO₂复合纤维具有良好的形态。随着纳米SiO₂的添加量逐渐提高，复合纤维的力学拉伸强度先增强后降低，复合纤维的吸水性降低，复合纤维的热稳定性逐渐增强。结合复合纤维综合性能，纳米SiO₂的最佳添加质量分数为0.5%。  相似文献   

耐230 ℃高温海水钻井液室内实验研究          下载免费PDF全文

邹志飞  熊正强  李晓东  付帆 《探矿工程》2022,49(1):49-56

为了解决深海油气井工程和大洋科学钻探深部高温井段钻井液流变稳定性和护壁性能等变差问题,以复合粘土为造浆材料,通过优选抗温抗盐降滤失剂、防塌剂和高温稳定剂等关键处理剂及钻井液配方优化研究,研发了一套耐230 ℃高温海水钻井液配方。采用高温高压流变仪、六速旋转粘度计和高温高压滤失仪等仪器,开展耐230 ℃高温海水钻井液的综合性能评价,如热稳定性、高温流变性等。实验结果显示,密度1.5 g/cm³的钻井液在230 ℃老化16 h前后,表观粘度变化率为2.5%,高温高压滤失量为23 mL。研究结果表明,该海水钻井液抗温可达230 ℃,具有良好的抗高温稳定性、高温流变性能以及较低的高温高压滤失量,可满足深海高温硬岩钻探要求。  相似文献   

A depth average SPH model including μ(I) rheology and crushing for rock avalanches     

Alberto Longo  Manuel Pastor  Lorenzo Sanavia  Diego Manzanal  Miguel Martin Stickle  Chuan Lin  Angel Yague  Saeid Moussavi Tayyebi 《国际地质力学数值与分析法杂志》2019,43(5):833-857

Classical depth-integrated smoothed particle hydrodynamics (SPH) models for avalanches are extended in the present work to include a μ(I)− rheological model enriched with a fragmentation law. With this improvement, the basal friction becomes grain distribution dependent. Rock avalanches, where grain distribution tends to change with time while propagating, are the appropriate type of landslide to apply the new numerical proposal. The μ(I)− rheological models considered in the present work are those of Hatano and Gray, combined with two different fragmentation laws, a hyperbolic and a fractal-based law. As an application, Frank avalanche, which took place in Canada in 1903, is analyzed under the scope of the present approach, focusing in the influence of the rheological and fragmentation laws in the evolution of the avalanche.  相似文献   

冻土区天然气水合物勘探低温钻井液理论与试验   总被引：3，自引：2，他引：1       下载免费PDF全文

杨葳  杨阳  徐会文 《探矿工程》2011,38(7):29-31,56

天然气水合物是在特定的低温与高压条件下形成的产物。在天然气水合物勘探工作中,低温钻井液是获得天然气水合物真实样品的重要保证条件之一。低温钻井液应具有低的冰点、良好的抵制能力与良好的流动性。结合天然气水合物勘探工作的特点,在试验的基础上,对比分析了PAM、PHPA、PAC-141、Na-CMC与KHm的分子结构、官能团的种类与数量对钻井液的防塌能力和流动性的影响,得出了几种处理剂的耐低温能力大小的顺序为：PAC-141〈PHPA〈PAM〈Na-CMC〈KHm,为天然气水合物勘探中低温钻井液的配制与使用,奠定了重要的基础。  相似文献   

An experimental study of effect of pre‐existing fabric on deformation of foliated mylonite at high temperature and pressure     

Gui Liu  Yongsheng Zhou  Changrong He  Wenming Yao  Junlai Liu  Yuanyuan Zhang 《Geological Journal》2016,51(1):92-112

We performed deformation experiments on a foliated mylonite under high temperature and pressure conditions in this study. To investigate the effect of pre‐existing fabric on the rheology of rocks, our samples were drilled from natural mylonite with the cylinder axis parallel to the foliation (PAR) and perpendicular to the foliation (PER). We performed 25 tests on seven PAR samples and 21 tests on seven PER samples at temperatures ranging from 600 to 890 °C, confining pressures ranging from 800 to 1400 MPa, and steady‐state strain rates of 1 × 10⁻⁴, 1 × 10⁻⁵ and 2.5 × 10⁻⁶ s⁻¹. In the temperatures of 600–700 °C, the deformation is accommodated by semi‐brittle flow, with the average stress exponent being 6–7 assuming power law flow; in the temperature range of 800–890 °C, deformation is mainly by plastic flow, with an average stress exponent of n = 3 and activation energies of Q = 354 ± 52 kJ/mol (PER and PAR samples). The experimental results show that the strengths of PER samples are higher than those of PAR samples. Deformation microstructures have been studied by optical and electron microscopy. The original foliation of PER samples is destroyed by deformation and replaced by a new foliation, but the deformation of PAR samples followed the original foliation. Electron backscatter diffraction (EBSD) measurements show a strong lattice preferred orientation (LPO) of the quartz c axis fabrics of the starting samples and deformed PER and PAR samples. However, the c axis fabric of quartz in experimentally deformed PER and PAR samples varied with temperature and strain rate is different from that seen in the starting mylonite sample. The initial quartz c axis fabric of the starting mylonite sample has been transformed into a new fabric during experimental deformation. Dehydration melting of biotite and hornblende occurred in both PER and PAR samples at temperatures of 800–890 °C. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Rheological properties of the upper mantle of Northern Eurasia and nature of regional boundaries according to the data of long-range seismic profiles   总被引：1，自引：0，他引：1  

N.I. Pavlenkova 《Russian Geology and Geophysics》2011,52(9):1016-1027

Deep seismic investigation carried out in Russia in long-range profiles with peaceful nuclear explosions allowed clarifying in details the structure of the upper mantle and the transition zone down to the depth of 700 km within the huge territory of old and young platforms of Northern Eurasia. Variability of horizontal heterogeneity of the upper mantle depending on the depth serves to qualitative estimation of its rheological properties. The upper part of the mantle to the depth of 80–100 km is characterized by the block structure with significant velocity steps of seismic waves at the blocks often divided by deep faults. This is the most rigid part of lithosphere. Below 100 km horizontal heterogeneity is insignificant, i.e., at these depths the substance is more plastic and not capable to retain block structure. On the lithosphere bottom at the depth of 200–250 km plasticity increase is observed as well but the zone of the lower velocities that might have been bound with the area of partial melting (asthenosphere) has not been found. These three layers with different rheological properties are divided by seismic boundaries presented by thin layering zones with alternating higher and lower velocities. At the specified depths any phase boundaries have been distinguished. These thin layering zones are assumed to form due to higher concentration of deep fluids at some levels of depths where mechanical properties and permeability of substance change. Insignificant number of fluids may result in appearance of streaks with partial or film melting at relatively low temperature—to the rise of the weakened zones where subhorizontal shifts are possible. According to seismic data in many world regions seismic boundaries are also observed at the depth of about 100 and 200 km; they may be globally spread. There are signs that areas of xenoliths formation and earthquake concentration, i.e., zones of high deformations, are confined to these depths.  相似文献   

High-harmonic geoid signatures related to glacial isostatic adjustment and their detectability by GOCE     

L.L.A. Vermeersen  H.H.A. Schotman   《Journal of Geodynamics》2008,46(3-5):174

The Earth’s asthenosphere and lower continental crust can regionally have viscosities that are one to several orders of magnitude smaller than typical mantle viscosities. As a consequence, such shallow low-viscosity layers could induce high-harmonic (spherical harmonics 50–200) gravity and geoid anomalies due to remaining isostasy deviations following Late-Pleistocene glacial isostatic adjustment (GIA). Such high-harmonic geoid and gravity signatures would depend also on the detailed ice and meltwater loading distribution and history.ESA’s Gravity field and steady-state Ocean Circulation Explorer (GOCE) satellite mission, planned for launch in Summer 2008, is designed to map the quasi-static geoid with centimeter accuracy and gravity anomalies with milligal accuracy at a resolution of 100 km or better. This might offer the possibility of detecting gravity and geoid effects of low-viscosity shallow earth layers and differences of the effects of various Pleistocene ice decay scenarios. For example, our predictions show that for a typical low-viscosity crustal zone GOCE should be able to discern differences between ice-load histories down to length scales of about 150 km.One of the major challenges in interpreting such high-harmonic, regional-scale, geoid signatures in GOCE solutions will be to discriminate GIA-signatures from various other solid-earth contributions. It might be of help here that the high-harmonic geoid and gravity signatures form quite characteristic 2D patterns, depending on both ice load and low-viscosity zone model parameters.  相似文献   

Deep crustal structure and rheology of the Gascoyne volcanic margin,western Australia     

Frey  Øivind  Planke  Sverre  Symonds  Phillip A.  Heeremans  Michel 《Marine Geophysical Researches》1998,20(4):293-311

Interpretation of deep seismic reflection data across the Gascoyne Margin reveals six distinct seismic facies units related to the tectono-magmatic breakup history. On the outer Exmouth Plateau four large scale units are identified: (1) an extensively block-faulted upper crust; (2) a middle-crustal unit of discontinuous, undulatory reflectors; (3) a reflection-free deep crustal unit; and (4) a lower-crustal band of low-frequency, high-amplitude reflectors. Two additional units are found near the continent-ocean boundary (COB); (5) seaward-dipping reflectors (SDR); and (6) landward-dipping reflectors in the lower crust below the SDR. The lower-crustal high-reflectivity band, located near the top of a high-velocity unit (V_p > 7 kms^–1), is interpreted as magmatic underplating. There is a spatial correlation between the underplated area and the presence of extensive upper-crustal block-faulting and intrusive rocks in the shallow crust. The undulatory middle-crustal reflector unit is also only identified in the outer plateau area, and is interpreted as a zone in which the upper-crustal faults terminate. The inner parts of the margin consist of a deep basin showing little upper-crustal faulting and no evidence of middle crustal deformation or underplating. Theoretical modeling of the effect of rifting and magmatic underplating on crustal strength profiles suggests that the brittle-ductile transition may migrate at least 5 km upwards during several million years after the underplating event. Based on the seismic interpretation and crustal strength modeling we propose that the seismic structure of the outer Exmouth Plateau is severely modified by a transient change in the crustal rheological structure associated with magmatic underplating.  相似文献   

Simple models for late Holocene and present-day Patagonian glacier fluctuations and predictions of a geodetically detectable isostatic response   总被引：1，自引：0，他引：1  

Erik R. Ivins  & Thomas S. James 《Geophysical Journal International》1999,138(3):601-624

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土流变学研究现状与趋势   总被引：1，自引：0，他引：1  

王常明 《世界地质》1998,17(4):33-37

土流变学是研究土流变性的科学,包括宏观力学和微观结构两个研究方面。其中就这两方面阐述了国际土流变学的研究现状和我国土流变学研究水平,并对今后的研究趋势作了展望。  相似文献