黄海透光层悬浮半导体矿物组成及其促进微生物胞外电子传递过程初探     

刘佳  孙元  任桂平  鲁安怀  李艳  丁竑瑞 《岩石矿物学杂志》2020,39(1):96-104

在地球上最为活跃的海洋透光层体系中,矿物-微生物交互作用的形式十分丰富。系统采集了黄海近海透光层水体样品,测试分析发现其中分布大量悬浮半导体矿物及微生物群落。通过电感耦合等离子质谱仪(ICP-MS)、环境扫描电子显微镜(ESEM)及配有的EDX能谱仪,从宏观到微区对悬浮颗粒矿物的化学元素组成进行了测试分析,发现其主要矿物组成元素为Si、O、Na、K、Ca、Al等,且含有较高含量的Mn、Fe、Ti等金属元素;通过X射线衍射光谱(XRD)、拉曼光谱(Raman)测试从整体到局部分析悬浮颗粒矿物的物相组成,发现其主要组成矿物为石英、钠长石、方解石、云母和绿泥石等,还有锐钛矿、金红石、板钛矿、针铁矿等铁、钛金属氧化物半导体矿物。通过16S rRNA高通量测序分析海水中主要微生物群落为Proteobacteria、Actinobacteria、Bacteroidetes、Planctomycetes、Woeseia、Fluviicola等,并通过构建双室反应体系对海水微生物与悬浮矿物间氧化还原作用及胞外电子传递过程进行了表征,结果显示增加海水悬浮矿物作为电子受体后,体系开路电压由330. 80 mV提升至426. 59 mV,提升比率达130%,最大输出功率由8. 376 9 mW/m^2提升至12. 096 8 mW/m^2,为原体系的1. 44倍。实验研究表明,海水透光层悬浮矿物能有效参与并促进微生物胞外电子传递过程,为后续深入研究基于电子能量传递利用的半导体矿物-微生物协同作用以及元素循环调控机制奠定初步基础。  相似文献   

海南岛海岸带土地利用强度与生态承载力分析     

李通  闫敏  陈博伟  张丽  宋茜茜 《测绘通报》2020,(9):54-59

随着海南省进一步开放发展，海岸带区域的土地利用强度逐渐加强，生态保护需求日益增强。利用4期（1990、2000、2009、2015年）海岸带土地利用分类数据，研究海岸带土地开发利用强度，并分析了其生态承载力。结果表明：①耕地和林地是海南岛海岸带地区的主要土地类型。②25年间，海南岛海岸带土地利用强度整体较高且逐年上升，2000—2009年土地利用强度增速最高，达2.03%；海口市和澄迈县土地利用强度4期均值最大，分别为300.5和286.1。③25年来海南岛海岸带生态状况呈下降趋势，57%的海岸带市县实际生态承载压力增长了1倍以上。  相似文献   

郯庐断裂带南段继承性断裂构造控矿模式研究及其应用效果——以皖东北五河金矿整装勘查为例     

汪青松  张顺林  张金会  张家嘉  尤淼 《地质学报》2020,94(10):2965-2977

郯庐断裂带南段的皖东北地区地质构造复杂，多为厚覆盖区，找矿难度大。由于控矿条件难以调查清楚，缺乏具有区域特色的勘查理论指导，区内金矿勘查长期没有取得突破成果。笔者依托五河金矿整装勘查项目，进行了区域重磁异常特征和成矿规律分析研究，发现皖东北地区北东- 北北东向重力低异常具有弧形条带特征，并以郯庐断裂带为界，大致具有旋转对称性。重磁异常保存印支期构造格架痕迹信息，反映了郯庐断裂带南段时空演化特征，显示了北东- 北北东向主要断裂构造具有继承性，形成于印支期，燕山期继续活动，控制白垩纪“红层盆地”和燕山期成岩成矿作用。中低温热液型金多金属矿床和矽卡岩型铜金矿床是皖东北地区主要矿床类型，均受继承性断裂构造控制。结合郯庐断裂的演化特征，利用物探成果引领地质理论创新，提出了郯庐断裂带南段矿床的“继承性断裂构造控矿模式”。根据继承性断裂构造形成机理分析其空间分布规律，总结了矿化蚀变构造带的物探异常标志，解决了皖东北覆盖区成矿预测与找矿靶区圈定难题，在五河金矿整装勘查区应用取得了重要找矿成果，圈定6个金矿找矿靶区，得到了钻探验证，已发现中型规模金矿床2处、小型3处，估算潜在资源量可达特大型规模，实现了安徽省境内郯庐断裂带金矿找矿的重大突破。  相似文献   

Reliability analysis of the induced damage for single-hole rock blasting     

Mahdi Shadab Far  Yuan Wang  Yousif A. H. Dallo 《Georisk: Assessment and Management of Risk for Engineered Systems and Geohazards》2019,13(1):82-98

Rock explosion has always been a complex problem because neither rock characteristics nor explosion waves could be accurately estimated. As such, this imposes a high uncertainty on deterministic methodologies available for damage prediction. In this paper, by defining two damage zones around the blast hole, including crushed and cracked zones, a first-order reliability analysis (FORM) was adopted to address this issue. For this purpose, FORM was used in a double-loop algorithm, where the inner loop was responsible for converging the FORM, and the outer loop was assigned to feed the inner loop with new cases. Using such nested-loop algorithm, the probability of exceedance was calculated for any desired damage zone radius. The maximum effect of the involved parameters on the failure probability induced around the blast hole was additionally studied using a parametric reliability analysis. The results showed that the radii for crushed and cracked zones are limited to 0.5 and 4.2?m, respectively, so that the probability of going beyond these limits is less than 1%. Moreover, the analyses of decoupled explosions showed that increasing the gap between the explosion charge and wall of the borehole could severely reduce the failure probability; however, the maximum effect of decoupling ratio occurs in the small range of radii between 0.3?mm and 2.35?m.  相似文献   

拉林铁路板块缝合带隧道地应力分析     

欧小强  王奭  李永亮  刘志强  郑宗溪  吴剑 《吉林大学学报(地球科学版)》2019,49(6):1689-1697

青藏高原板块缝合带为印度板块和欧亚板块两大陆块的缝合区域，带区地质条件复杂，构造运动强烈。川藏线拉林铁路几乎沿雅鲁藏布江缝合带展布，高地应力问题十分突出，但目前针对板块缝合带隧道的地应力研究相对较少。本文采用空心包体法对拉林铁路沿线隧道进行了原位地应力测量，并与成兰、兰渝和锦屏等几个典型工程的地应力进行对比分析。研究表明：拉林铁路沿线隧道埋深大，构造应力突出，总体表现为最大水平主应力 > 垂直主应力 > 最小水平主应力；平均侧压系数（1.0~1.5）分布较为集中且处于较高水平；最大主应力量值大多在20~50 MPa之间，最大主应力与埋深的梯度为0.033 7 MPa/m，方向以北北西-北北东向为主。建议采用仰拱结构减小隧道墙脚处的应力集中现象。  相似文献   

Geochronology and geochemistry of Permo-Triassic sandstones in eastern Jilin Province (NE China): Implications for final closure of the Paleo-Asian Ocean     

《地学前缘(英文版)》2019,10(2):683-704

In the eastern part of the Central Asian Orogenic Belt (CAOB) in northeastern (NE) China, scattered outcrops of molasse deposits mark the ending of an orogeny and are crucial for understanding the evolution of the Paleo-Asian Ocean (PAO). However, the timing of tectonic events and the relationships among these strata remain controversial. To better constrain these geologic events, a comprehensive study of the detrital zircon U-Pb geochronology and geochemistry of the sandstones of the Kaishantun (KST) Formation and Kedao (KD) Group in eastern Jilin Province, NE China, was conducted. The KST Formation is traditionally considered a molasse deposit. The sandstones display low CIA, PIA and high ICV values and low Th/U and Rb/Sr ratios, which suggest that the rocks were derived from an immature intermediate-felsic igneous source and experienced a simple sedimentary recycling history with relatively weak chemical weathering. LA-ICP-MS U-Pb dating of detrital zircons from two samples of the KST Formation yields ages of 748–252 Ma, suggesting that the KST Formation was deposited between 254.5 Ma and 252 Ma in Late Permian. The zircons were mainly derived from the continental northern part of the North China Craton (NCC). In contrast, the U-Pb dating of detrital zircons from five samples of the KD Group yields ages of 2611–230 Ma, suggesting that the KD samples were deposited in the Early to Middle Triassic (ca. 248–233 Ma). The detrital zircon ages for the KD samples can be divided into groups with peaks at 2.5 Ga, 1.8 Ga, 800–1000 Ma, 500 Ma and 440–360 Ma, which suggest that the samples were derived from bidirectional provenances in the Jiamusi-Khanka Block and the NCC. These new data, combined with previously published results, suggest that at least three orogenic events occurred in central-eastern Jilin Province during the Early Permian (270–262 Ma), Early Triassic (254–248 Ma) and Middle–Late Triassic (242–227 Ma). The final closure of the PAO occurred during 242–227 Ma in the Middle–Late Triassic along the Changchun-Yanji suture zone. The detrital zircon geochronological data clearly record plate convergence and the scissor-like closure of the PAO in the eastern CAOB.  相似文献   

Growth and provenance of a Paleozoic subduction complex in the Broken River Province,Mossman Orogen: evidence from detrital zircon ages     

R. A. Henderson  C. L. Fergusson 《Australian Journal of Earth Sciences》2019,66(5):607-624

A Paleozoic subduction complex dominates the Mossman Orogen developed at the northern extremity of the Tasmanides, eastern Australia. Its southern part, displayed in the Broken River Province, is characterised by dismembered ocean-plate stratigraphy in which turbidite-dominated packages and widespread tectonic mélange development are characteristic. The Broken River complex is characterised by formations with quartzose sandstone alternating with those largely formed of sandstone of more labile character. The two compositional groups are considered to reflect separate, age-significant sedimentary regimes, but their ages have hitherto been poorly constrained. With the use of 1082 concordant detrital zircon ages from 13 samples we provide age control for the complex and track its sedimentary provenance. Of quartzose units, the Tribute Hills Arenite and Pelican Range Formation are late Cambrian–Early Ordovician, and the Wairuna Formation is Middle to Late Ordovician, in age. The more labile units (Greenvale, Perry Creek and Kangaroo Hills formations) are collectively of late Silurian–mid-Devonian age. Development of the complex spanned some 130 Myr. Continent-derived sediment involved in accretion of much the complex, from mid-Ordovician to mid-Devonian, was largely sourced from a nearby magmatic arc of late Cambrian–Devonian age, now represented by granitoid plutons of the Macrossan and Pama igneous associations. An older far-field Pacific-Gondwana sediment source is characteristic of early-phase (late Cambrian–Early Ordovician) accretion, in common with sedimentary units of this age generally developed in the Tasmanides. We consider the complex to have grown largely by underplating that positioned younger components beneath those that are older, with out-of-sequence thrust interleaving of these components occurring late in the accretionary history. A Late Devonian contractional folding and cleavage development (Tabberabberan orogenesis) is uniformly expressed across the entire complex and reflects an abrupt change in plate engagement with imposition of a compressional stress regime.  相似文献   

Conversion relationship of rainfall-soil moisture-groundwater in Quaternary thick cohesive soil in Jianghan Plain,Hubei Province,China     

《China Geology》2020,3(3):462-472

The scientific field test site of rainfall-soil moisture-groundwater conversion in Dabie Mountain Area–Jianghan Plain is located in the northern region of the Jianghan Plain, the transition zone between the Dabie Mountain Area and Jianghan Plain. It’s a great field test site to study the material and energy exchange among rainfall, soil moisture, and groundwater of the Earth ’s critical zone in subtropical monsoon climate plain areas. This paper analyzed the connection between rainfall and volume water content (VWC) of soil at different depths of several soil profiles, and the dynamic feature of groundwater was discussed, which reveals the rainfall infiltration recharge of Quaternary Upper Pleistocene strata. The results show that the Quaternary Upper Pleistocene aquifer groundwater accepts a little direct rainfall recharge, while the lateral recharge is the main supplement source. There were 75 effective rainfall events among 120 rainfall events during the monitoring period, with an accumulated amount of 672.9 mm, and the percentages of effective rainfall amount and duration time were 62.50% and 91.56%, respectively. The max evaporation depth at the upper part in Quaternary cohesive soil was no less than 1.4 m. The soil profile was divided into four zones: (1) The sensitive zone of rainfall infiltration within 1.4 m, where the material and energy exchange frequently near the interface between atmosphere and soil; (2) the buffer zone of rainfall infiltration between 1.4 m and 3.5 m; (3) the migration zone of rainfall infiltration between 3.5 m and 5.0 m; and (4) the rainfall infiltration and groundwater level co-influenced zone below 5.0 m. The results revealed the reaction of soil moisture and groundwater to rainfall in the area covered by cohesive soil under humid climate in Earth ’s critical zone, which is of great theoretical and practical significance for groundwater resources evaluation and development, groundwater environmental protection, ecological environmental improvement, drought disaster prevention, and flood disaster prevention in subtropical monsoon climate plain areas.  相似文献   

藏南冈底斯岩基日多地区花岗岩体形成时代和地球化学特征   总被引：2，自引：2，他引：0  

王海涛  曾令森  高利娥  胡昭平  王亚飞  赵令浩  高家昊  徐倩 《岩石学报》2019,35(2):439-454

冈底斯岩基广泛发育三叠纪-中新世的岩浆岩,是研究与新特提斯洋北向俯冲和印度-欧亚大陆碰撞相关的构造岩浆作用特征的天然实验室。日多地区花岗岩体位于藏南墨竹工卡县东侧日多乡附近,其主体为花岗岩,被花岗闪长玢岩脉侵入。锆石U-Pb地质年代学表明:主体花岗岩形成于62.7±0.5Ma,侵入其中的花岗闪长玢岩脉形成于59.5±1.5Ma,并捕获了大量的侏罗纪岩浆岩锆石(155.4±1.8Ma)。日多地区花岗岩体的全岩地球化学特征为:(1)高Si O_2、Na_2O、Al_2O_3,低Fe O~T、MgO、Ti O_2;(2)富集轻稀土(LREE),亏损重稀土(HREE)及高场强元素Nb、Ta、Ti、P元素;(3)具有Eu负异常,总体显示高钾钙碱性、过铝质花岗岩和岛弧型岩浆岩特征。锆石Hf同位素特征暗示其岩浆源区为基性下地壳物质。花岗闪长玢岩脉裹挟大量侏罗纪岩浆型锆石,表明冈底斯岩基拉萨以东地区可能经历了较广泛的晚侏罗世岩浆作用。  相似文献   

Drying increases organic colloidal mobilization in the karst vadose zone: Evidence from a 15-year cave-monitoring study     

Jin Liao  Chaoyong Hu  Xiuli Li  Jiaoyang Ruan 《水文研究》2021,35(4):e14163

Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems.  相似文献