阿拉尔河悬浮物对铀的吸附影响研究          下载免费PDF全文

钟翼  许建新  韩积斌  徐凯 《盐湖研究》2020,28(1):112-122

为了解阿拉尔河悬浮物对铀的吸附特性,通过静态吸附实验,研究了吸附时间、pH值、温度和铀初始浓度等因素对模拟含铀水中U(VI)去除率的影响,并从热力学和动力学方面对吸附过程进行了分析。结果表明,在T=25℃,溶液初始pH=7,接触时间为16 h时,悬浮物对铀的平衡吸附率最佳,为95.48%。随着铀初始浓度的增加,吸附量增加,但吸附率随之下降,升高温度有利于铀的吸附。铀在悬浮物上的吸附过程符合Langmuir等温吸附方程,说明悬浮物对铀为单分子层吸附,且化学吸附占主导地位。吸附动力学过程可用准二级吸附动力学模型描述,表明吸附主要受动力学控制,由两个以上步骤共同控制。FTIR和EDS分析结果表明,吸附过程中铀主要与悬浮物表面活性基团螯合并以表面络合吸附为主。吸附前后的能谱对比分析表明,吸附过程中存在离子交换行为。因此,悬浮物对铀的吸附机理是以表面络合吸附和离子交换为主、物理吸附为辅的混合吸附过程。  相似文献   

A fully coupled THM model based on a non‐equilibrium thermodynamic approach and its application          下载免费PDF全文

Z. Zhang  X. Cheng 《国际地质力学数值与分析法杂志》2017,41(4):527-554

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The influence of coupled physical swelling and chemical reactions on deformable geomaterials     

Yue Ma  Xiao‐Hui Chen  Lee J. Hosking  Hai‐Sui Yu  Hywel R. Thomas  Simon Norris 《国际地质力学数值与分析法杂志》2021,45(1):64-82

Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.  相似文献   

Grain‐scale pressure variations and chemical equilibrium in high‐grade metamorphic rocks     

L. Tajčmanová  Y. Podladchikov  R. Powell  E. Moulas  J.C. Vrijmoed  J.A.D. Connolly 《Journal of Metamorphic Geology》2014,32(2):195-207

In the classical view of metamorphic microstructures, fast viscous relaxation (and so constant pressure) is assumed, with diffusion being the limiting factor in equilibration. This contribution is focused on the only other possible scenario – fast diffusion and slow viscous relaxation – and brings an alternative interpretation of microstructures typical of high‐grade metamorphic rocks. In contrast to the pressure vessel mechanical model applied to pressure variation associated with coesite inclusions in various host minerals, a multi‐anvil mechanical model is proposed in which strong single crystals and weak grain boundaries can maintain pressure variation at geological time‐scales in a polycrystalline material. In such a mechanical context, exsolution lamellae in feldspar are used to show that feldspar can sustain large differential stresses (>10 kbar) at geological time‐scales. Furthermore, it is argued that the existence of grain‐scale pressure gradients combined with diffusional equilibrium may explain chemical zoning preserved in reaction rims. Assuming zero net flux across the microstructure, an equilibrium thermodynamic method is introduced for inferring pressure variation corresponding to the chemical zoning. This new barometric method is applied to plagioclase rims around kyanite in felsic granulite (Bohemian Massif, Czech Republic), yielding a grain‐scale pressure variation of 8 kbar. In this approach, kinetic factors are not invoked to account for mineral composition zoning preserved in rocks metamorphosed at high grade.  相似文献   

A bounding surface model for anisotropically overconsolidated clay incorporating thermodynamics admissible rotational hardening rule     

Yanni Chen  Zhongxuan Yang 《国际地质力学数值与分析法杂志》2020,44(5):668-690

A bounding surface model is formulated to simulate the behavior of clays that are subject to an anisotropic consolidation stress history. Conventional rotational hardening is revisited from the perspective of thermodynamics. As the free energy cannot be accumulated infinitely upon critical state failure, the deviatoric back stress must vanish. This requires the rotated yield surface to be turned back to eventually align on the hydrostatic axis in the stress plane. Noting that most of the previous propositions violate this restriction, an innovative rotational hardening rule is formulated that is thermodynamically admissible. The bounding surface framework that employs the modified yield surface is applied to simulate elastoplastic deformations for overconsolidated clays, with which the overprediction of strength on the “dry” side can be greatly improved with reasonable results. Other important features, including contractive or dilative response and hardening or softening behavior, can also be well-captured. It has been shown that the model can simulate three types of reconstituted clays that are sheared with initial conditions over a wide range of anisotropic consolidation stress ratios and overconsolidation ratios under both triaxial undrained and drained conditions. Limitations and potential improvement of the model regarding the fabric anisotropy at critical state have been discussed.  相似文献   

Contrasting hydrography and phytoplankton distribution in the upper layers of cyclonic eddies in the Mozambique Basin and Mozambique Channel     

T Lamont  RG Barlow 《African Journal of Marine Science》2017,39(3):293-306

Hydrographic data collected in cyclonic eddies in the Mozambique Channel and Basin revealed notable differences in temperature and salinity at a depth of 100 m, the upper mixed layer, the nitracline depths, and vertical distribution of chlorophyll-a (Chl-a). Differences in temperature and salinity did not show any consistent patterns. In contrast, the differences in the upper mixed layer, nitracline depths and the vertical Chl-a profile appeared to be driven by combined effects of eddy dynamics (i.e. shoaling of isopleths) and the seasonal variation in light availability and mixing conditions in the upper layers. Cyclonic eddies studied during austral spring and summer in the Mozambique Channel exhibited shallower upper mixed layers and nitracline depths, and deeper euphotic zones. Distinct subsurface Chl-a maxima (SCM) were associated with the stratified conditions in the upper layers of these eddies. In contrast, a cyclonic eddy studied during mid-austral winter in the Mozambique Basin had a shallower euphotic zone, deeper upper mixed layer and uniform Chl-a profiles. Another eddy sampled in the Mozambique Basin toward the end of winter showed a less pronounced SCM and roughly equal euphotic zone and upper mixed layer depths, suggestive of a transition from a well-mixed upper layer during winter to stratified conditions in summer.  相似文献   

Effect of grain‐scale pressure variations on garnet growth: a numerical approach          下载免费PDF全文

X. Zhong  J.C. Vrijmoed  L. Tajčmanová 《Journal of Metamorphic Geology》2017,35(1):19-33

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变质作用p-T-t轨迹的研究方法与进展          下载免费PDF全文

魏春景 《地学前缘》2011,18(2):1-16

变质作用p-T-t轨迹理论的提出完全改变了人们时变质作用过程的认识.地壳加厚区(造山带)内区域变质作用发生于地壳从热扰动到热松弛的动态演化过程中,岩石的p-T-t轨迹是地壳加厚的方式及机制、热松弛速率和岩石折返速率的综合函数.一维热模拟假设引起热扰动的构造作用在瞬间完成,岩石在折返过程中开始变质作用演化.二维热模拟结果...  相似文献   

Thermodynamic processes of lake ice and landfast ice around Zhongshan Station, Antarctica     

LEI RuiBo  LI ZhiJun  ZHANG ZhanHai  CHENG YanFeng 《极地研究(英文版)》2011,(3):143-152

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青藏高原北部活动层土壤热力特性的研究   总被引：3，自引：0，他引：3       下载免费PDF全文

李韧  赵林  丁永建  焦克勤  王银学  乔永平  杜二计  刘广岳  孙琳婵  肖瑶 《地球物理学报》2010,53(5):1060-1072

利用2003年10月～2004年9月期间高原北部可可西里(QT01)、北麓河(QT02)、开心岭(QT05)、通天河(QT06)等地活动层土壤温度梯度、土壤热通量及土壤水分的观测资料,计算了高原北部活动层土壤的导热率、土壤容积热容量、导温率等土壤热力参数.结果显示，QT02、QT05、QT06三站导热率、导温率夏秋季节较大而冬季较小，容积热容量则相反，表现为秋冬季节大而夏季较小；QT01站导热率表现为春季大，夏季较小；表层土壤粒度较小及较低的土壤湿度是冬季导热率较小的可能原因；冻土的热力特征参量可描述为相应深度的温度、体积含冰量及土壤盐度的函数，土壤含水量是融土热特征参数的主要影响因子；土壤水分含量小于某一临界值时，导温率随土壤水分含量的增大而增大，反之则减小.  相似文献