Carbonaceous chondrites as analogs for the composition and alteration of Ceres          下载免费PDF全文

Harry Y. McSween Jr.  Joshua P. Emery  Andrew S. Rivkin  Michael J. Toplis  Julie C. Castillo‐Rogez  Thomas H. Prettyman  M. Cristina De Sanctis  Carle M. Pieters  Carol A. Raymond  Christopher T. Russell 《Meteoritics & planetary science》2018,53(9):1793-1804

The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   

Mineralogy and temperature of crater Haulani on Ceres          下载免费PDF全文

F. Tosi  F. G. Carrozzo  A. Raponi  M. C. De Sanctis  G. Thangjam  F. Zambon  M. Ciarniello  A. Nathues  M. T. Capria  E. Rognini  E. Ammannito  M. Hoffmann  K. Krohn  A. Longobardo  E. Palomba  C. M. Pieters  K. Stephan  C. A. Raymond  C. T. Russell 《Meteoritics & planetary science》2018,53(9):1902-1924

We investigate the region of crater Haulani on Ceres with an emphasis on mineralogy as inferred from data obtained by Dawn's Visible InfraRed mapping spectrometer (VIR), combined with multispectral image products from the Dawn Framing Camera (FC) so as to enable a clear correlation with specific geologic features. Haulani, which is one of the youngest craters on Ceres, exhibits a peculiar “blue” visible to near‐infrared spectral slope, and has distinct color properties as seen in multispectral composite images. In this paper, we investigate a number of spectral indices: reflectance; spectral slopes; abundance of Mg‐bearing and NH₄‐bearing phyllosilicates; nature and abundance of carbonates, which are diagnostic of the overall crater mineralogy; plus a temperature map that highlights the major thermal anomaly found on Ceres. In addition, for the first time we quantify the abundances of several spectral endmembers by using VIR data obtained at the highest pixel resolution (~0.1 km). The overall picture we get from all these evidences, in particular the abundance of Na‐ and hydrous Na‐carbonates at specific locations, confirms the young age of Haulani from a mineralogical viewpoint, and suggests that the dehydration of Na‐carbonates in the anhydrous form Na₂CO₃ may be still ongoing.  相似文献   

Ceres's global and localized mineralogical composition determined by Dawn's Visible and Infrared Spectrometer (VIR)          下载免费PDF全文

M. C. De Sanctis  E. Ammannito  F. G. Carrozzo  M. Ciarniello  M. Giardino  A. Frigeri  S. Fonte  H. Y. McSween  A. Raponi  F. Tosi  F. Zambon  C. A. Raymond  C. T. Russell 《Meteoritics & planetary science》2018,53(9):1844-1865

The Visible and Infrared Spectrometer (VIR) instrument on the Dawn mission observed Ceres’s surface at different spatial resolutions, revealing a nearly uniform global distribution of surface mineralogy. Clearly, Ceres experienced extensive water‐related processes and chemical differentiation. The surface is mainly composed of a dark component (carbon, magnetite?), Mg‐phyllosilicates, ammoniated clays, carbonates, and salts. The observed species suggest endogenous, global‐scale aqueous alteration. While mostly uniform at regional scale, Ceres’s surface shows small localized areas with different species and/or variations in abundances. Few local exposures of water ice are seen, especially at higher latitudes. Sodium carbonates have been identified in several areas on the surface, notably in Occator bright faculae. Organic matter has also been discovered in several places, most conspicuously in a large area close to the Ernutet crater. The observed mineralogies, with the presence of ammoniated species and sodium salts, have a strong resemblance to materials found on other bodies of the outer solar system, such as Enceladus. This poses some questions about the original material from which Ceres accreted, suggesting a colder environment for such material with respect to Ceres’s present position.  相似文献   

Effects of soaking of shales on rock-slope instability and failure in southeastern Nigeria     

Una Chuku Okoro  Igwe Ogbonnaya  Anekwe Ejikeme Raymond 《Journal of the Geological Society of India》2015,86(5):570-578

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Adapting transportation to climate change on federal lands in Washington State,U.S.A.     

R. L. Strauch  C. L. Raymond  R. M. Rochefort  A. F. Hamlet  C. Lauver 《Climatic change》2015,130(2):185-199

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Hydroxyl stretching in phyllosilicates at high pressures and temperatures: an infrared spectroscopic study     

Alison R. Pawley  Raymond L. Jones 《Physics and Chemistry of Minerals》2011,38(10):753-765

The hydroxyl stretching frequencies of four phyllosilicates have been measured at high pressures and temperatures using an externally heated diamond-anvil cell and synchrotron infrared spectroscopy. Spectra were measured up to 26, 31, 21 and 8 GPa at room temperature for samples of talc, pyrophyllite, muscovite and 10-Å phase, respectively. Spectra were also measured in the range 273–500 K at ambient pressure for all samples and at 8–9 GPa for talc and pyrophyllite. The frequency of the Mg₃OH band in talc increases with pressure due to the absence of hydrogen bonding. The different orientation of the hydroxyl group in pyrophyllite and muscovite leads to hydrogen bonding and a decrease in the frequency of the Al₂OH band with pressure. 10-Å phase is approximately equivalent to talc with the addition of interlayer H₂O. In a spectrum of a sample synthesised for 143 h, two hydroxyl stretching bands are clearly resolved on compression. One is the same as the Mg₃OH band in talc, indicating the presence of intra-layer hydroxyl in a talc-like environment with no hydrogen bonding. The other, which separates from the talc-like band at 1 GPa, is associated with intra-layer hydroxyl that is hydrogen bonded to interlayer H₂O. There are equivalent bands in high-pressure spectra of a sample of deuterated 10-Å phase, synthesised for 400 h. This sample shows a greater extent of hydrogen bonding at ambient pressure than the 143 h sample. For all of the phases studied, increasing temperature leads to a decrease in frequency for every hydroxyl stretching vibration, both at low and high pressures. The shifts in frequency with temperature are an order of magnitude greater than the shifts with pressure when normalised to previously measured structural parameters.  相似文献   

“Global warming” versus “climate change”: A replication on the association between political self-identification,question wording,and environmental beliefs     

Alistair Raymond Bryce Soutter  René Mõttus 《Chemie der Erde / Geochemistry》2011

Climate change is one of the greatest threats to humanity and requires immediate action. Schuldt, Konrath, and Schwarz (2011) suggested that beliefs in environmental phenomena can be influenced by the terminology used to describe it: changing question wording from global warming to climate change resulted in a 6.3 percentage point increase in belief in environmental phenomena. This association was moderated by political self-identification, with Republicans being 16.2 percentage points more likely to believe in climate change than in global warming, with Democrats showing no difference. The potential for connotative meanings to shift over time and the sociopolitical changes since the original study, potential policy and environmental campaign implications, and an expansion of these findings to other countries, motivated an attempt to replicate this important finding. This pre-registered study repeated the original procedures in the United States of America and two other countries (United Kingdom and Australia; total N = 5,717). Although question wording no longer had a significant effect on beliefs in climate change/global warming, the association of political self-identification with beliefs in environmental phenomena replicated in all three countries, with Conservatives consistently believing less in climate change/global warming than Liberals. The potential impacts of temporal and methodological differences on the discrepancies between this study's and the original's findings are discussed.  相似文献   

High-temperature emplacement of the Cerro Galán and Toconquis Group ignimbrites (Puna plateau,NW Argentina) determined by TRM analyses     

Chiara Lesti  Massimiliano Porreca  Guido Giordano  Massimo Mattei  Raymond A. F. Cas  Heather M. N. Wright  Chris B. Folkes  Josè Viramonte 《Bulletin of Volcanology》2011,73(10):1535-1565

Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated up to or above the highest blocking temperature (T _b) of the magnetic minerals (T _b = 580°C for magnetite; T _b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components. The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement, all ensuring minimal heat loss.  相似文献   

Assessing spatial associations between perceptions of landscape value and climate change risk for use in climate change planning   总被引：1，自引：0，他引：1  

Christopher M. Raymond  Gregory Brown 《Climatic change》2011,104(3-4):653-678

This study examines spatially referenced perceived landscape values and climate change risks collected through public participation geographic information systems for potential use in climate change planning. Using survey data from the Southern Fleurieu Peninsula, South Australia, we present a method for identifying perceived landscape values and climate change risks to describe and quantify their spatial associations. Two spatial data models??vector and raster??and two analytical methods??Jaccard coefficients and spatial cross-correlations were used to describe the spatial associations. Results indicate that perceptions of climate change risk are driven, in part, by the values people assign or hold for places on the landscape. Biodiversity and intrinsic landscape values have strong spatial association with biodiversity loss risk while recreation values have strong spatial association with riparian flooding, sea-level rise and wave action risks. Other landscape values show weak to no spatial association with perceived climate change risks. The methodology described in this research provides a mechanism for government agencies to develop place-based adaptation strategies based on these associations.  相似文献   

Thresholds for post-wildfire debris flows: Insights from the Pinal Fire,Arizona, USA     

Carissa A. Raymond  Luke A. McGuire  Ann M. Youberg  Dennis M. Staley  Jason W. Kean 《地球表面变化过程与地形》2020,45(6):1349-1360

Wildfire significantly alters the hydrologic properties of a burned area, leading to increases in overland flow, erosion, and the potential for runoff-generated debris flows. The initiation of debris flows in recently burned areas is well characterized by rainfall intensity-duration (ID) thresholds. However, there is currently a paucity of data quantifying the rainfall intensities required to trigger post-wildfire debris flows, which limits our understanding of how and why rainfall ID thresholds vary in different climatic and geologic settings. In this study, we monitored debris-flow activity following the Pinal Fire in central Arizona, which differs from both a climatic and hydrogeomorphic perspective from other regions in the western United States where ID thresholds for post-wildfire debris flows are well established, namely the Transverse Ranges of southern California. Since the peak rainfall intensity within a rainstorm may exceed the rainfall intensity required to trigger a debris flow, the development of robust rainfall ID thresholds requires knowledge of the timing of debris flows within rainstorms. Existing post-wildfire debris-flow studies in Arizona only constrain the peak rainfall intensity within debris-flow-producing storms, which may far exceed the intensity that actually triggered the observed debris flow. In this study, we used pressure transducers within five burned drainage basins to constrain the timing of debris flows within rainstorms. Rainfall ID thresholds derived here from triggering rainfall intensities are, on average, 22 mm h⁻¹ lower than ID thresholds derived under the assumption that the triggering intensity is equal to the maximum rainfall intensity recorded during a rainstorm. We then use a hydrologic model to demonstrate that the magnitude of the 15-min rainfall ID threshold at the Pinal Fire site is associated with the rainfall intensity required to exceed a recently proposed dimensionless discharge threshold for debris-flow initiation. Model results further suggest that previously observed differences in regional ID thresholds between Arizona and the San Gabriel Mountains of southern California may be attributed, in large part, to differences in the hydraulic properties of burned soils. © 2019 John Wiley & Sons, Ltd.  相似文献