Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

Labour struggles and the formation of demands: The spatial politics of Red Clydeside     

《Geoforum》2015

This paper combines labour history and labour geography through an analysis of the making of labour demands in Glasgow during the early twentieth century. The paper asserts how revisiting histories such as Red Clydeside reveals complexities within labour movements and links to more recent debates within labour geography. Archival research provides a relational account of the place-based politics of Glasgow that emerged during the forty hours movement in 1919. This allows the paper to juxtapose the broader international linkages forged by Scottish workers alongside racialised hostilities within the city. In particular, the paper compares and contrasts the progressive internationalism of the strike newspaper with the Broomielaw race riot between local and foreign sailors during the same month as the strike. This comparison also raises the longer-term trajectories of labour grievances to foreground the ambivalent and contested nature of labour demands, identities and histories. In particular, the paper pays close attention to contrasting practices of labour internationalism emerging from the relevant archives. This historical approach makes a broader contribution to debates within labour geography by engaging with the complexities and tensions of labour organising and demand making.  相似文献   

不同压应力作用下黏土体积变形的微观特征     

陈宝  朱嵘  常防震 《岩土力学》2011,32(Z1):95-99

为了研究黏土体积变形的微观结构变化特征,选取上海第4层淤泥质黏土为研究对象,分别采用各向等压和K0压缩两种方法制备体积变化率相同的土样,经冷冻真空干燥后对土样进行压汞试验并测定土中孔隙大小分布状况。压汞试验结果表明:试验黏土中孔隙可分为大孔隙、中孔隙、小孔隙和微孔隙,小孔隙占据土中孔隙的大部分空间,且其变化能够反映微观结构的主要特性;在各向等压应力状态下,随着压应力增高、体积压缩量增大,黏土颗粒发生空间平移使颗粒间变得更为紧密,孔隙分布曲线变化以孔隙波峰往孔隙变小方向偏移为主要特征,孔隙尺寸变小而孔隙形态基本不变;在K0压缩应力状态下,随着压应力增高,黏土颗粒发生旋转使孔隙变得扁平,表现为孔隙波峰位置基本不发生偏移,而以峰值降低为主要特征,孔隙结构形态明显改变。  相似文献   

抗拔桩变形分析与有效桩长预测   总被引：1，自引：0，他引：1  

郑大龙 《上海国土资源》2011,32(2):75-78

以抗拔桩变形的理论分析为基础,选择双曲线荷载传递函数对桩的极限侧阻力进行合理取值,通过迭代法得到桩身受力情况,由此预测抗拔桩的＂有效桩长＂。结合工程实例进行了计算验证,证明该方法具有实用价值和推广意义。  相似文献   

城市空间智能计算平台研究     

朱钥  李琦 《地理与地理信息科学》2011,27(1):11-15,20

该文提出了空间智能平台的概念,阐述了其研究意义和内容,明确了空间智能计算平台核心计算模型的建模对象和目标。在此基础上,分析了宏观数学模型、群体行为模型两种用来构建空间活动模型的建模方法以及适用于空间活动分析的物理环境建模技术。从融合多尺度行为模型、构建城市日常生活模型、验证和校验核心模型以及平衡效率和效果4方面探讨了构建空间智能计算平台的关键技术。从实际功能看,城市空间智能平台是联系宏观复杂问题和微观机制的桥梁,是分析城市问题的工程化实验平台,具有广阔的应用前景。  相似文献   

长江口沙波统计特征及输移规律   总被引：4，自引：1，他引：3  

郭兴杰  程和琴  莫若瑜  杨忠勇 《海洋学报》2015,37(5):148-158

利用多波束测深系统对长江口南港、北槽、横沙通道和北港水下地貌进行测量,对沙波波高、波长、迎流倾角、背流倾角、水深和沉积物特征进行统计,并根据流速、沉积物粒径及水深估算其潮周期内净位移。结果表明:长江口沙波基本都为大型沙波,且沙波大小与其所在区域沉积物粒径呈正比关系;长江口各个区域沙波的对称性不同,涨、落潮优势流越明显,则沙波对称性越差,净位移越大;沙波对称性能反映此区域水动力强弱及潮周期内沙波净位移大小。  相似文献   

基岩倾角对盆地地震响应的影响分析          下载免费PDF全文

卓发成 《地震工程学报》2020,42(4):1035-1042

为了研究盆地基岩倾角对盆地地表动力反应的影响,选取了一个跨度2 km,深度500 m的二维成层盆地为研究对象进行有限元动力反应分析。以持时0.25 s的狄拉克脉冲作为输入地震动,探讨了P波和SV波垂直入射时,盆地基岩倾角从10°\,20°\,30°\,40°依次增加的情况下盆地地震反应。结果表明:入射波在倾斜基岩处发生波型转化,同时产生面波,在盆地中心区域发生汇聚;随着基岩倾角的增加地表中心处的卓越频率有减小的趋势。  相似文献   

Field experiment and numerical study on active vibration isolation by horizontal blocks in layered ground under vertical loading     

《Soil Dynamics and Earthquake Engineering》2015

In this paper, a series of field experiments were carried out to investigate the active vibration isolation for a surface foundation using horizontal wave impedance block (WIB) in a multilayered ground under vertical excitations. The velocity amplitude of ground vibration was measured and the root-mean-square (RMS) velocity is used to evaluate the vibration mitigation effect of the WIB. The influences of the size, the embedded depth and the shear modulus of the WIB on the vibration mitigation were also systematically examined under different loading conditions. The experimental results convincingly indicate that WIB is effective to reduce the ground vibration, especially at high excitation frequencies. The vibration mitigation effect of the WIB would be improved when its size and shear modulus increase or the embedded depth decreases. The results also showed that the WIB may amplify rather than reduce the ground vibration when its shear modulus is smaller or the embedded depth is larger than a threshold value. Meanwhile, an improved 3D semi-analytical boundary element method (BEM) combined with a thin layer method (TLM) was proposed to account for the rectangular shape of the used WIB and the laminated characteristics of the actual ground condition in analyzing the vibration mitigation of machine foundations. Comparisons between the field experiments and the numerical analyses were also made to validate the proposed BEM.  相似文献   

西湖凹陷渐新世层序地层格架与沉积充填响应   总被引：2，自引：0，他引：2  

于兴河  李顺利  曹冰  侯国伟  王亚风  皇甫志远 《沉积学报》2017,35(2):299-314

东海陆架盆地是中国近海最大的沉积盆地，而西湖凹陷又是其中规模最大的富油气凹陷。多年的勘探实践证明渐新统花港组为西湖凹陷主力产气层段，但其层序地层划分长期存在较大争议。在分析了西湖凹陷盆地结构与构造格局的基础上，依据测井、岩芯以及地震反射特征，将西湖凹陷渐新统划分出5个三级层序与12个体系域，建立了其等时地层格架；并通过大量岩芯的写实性描述，结合沉积构造与遗迹化石鉴别以及地球化学资料分析对沉积环境进行了判识，分析结果认为西湖凹陷渐新统花港组沉积时期发生过两次较大的海侵事件，形成“南海北陆”的沉积格局，并发育了河流、三角洲、潮控河口湾以及无障壁海岸四种沉积体系，其沉积体系类型较多，从南到北变化巨大。西湖凹陷渐新世整体表现为“东西短轴三角洲”、“南部潮汐河口湾”、“东北缓岸滩坝”的沉积体系展布格局。系统分析了沉积相在各层序中的展布特征及其对海平面变化的响应、层序演化过程及其对海平面变化的响应，构建了东海陆架盆地西湖凹陷构造-沉积成因模式，明确了“断坳转换，海陆交替”的盆地构造背景与沉积充填的响应关系。  相似文献   

某外海工程超长大直径钢管桩变形原因简析与加强方案研究     

徐定山  梁胜发  乐治齐 《海洋工程》2012,30(2):136-142

某外海工程在沉设超长大直径钢管桩施工过程中,发生钢管桩在海床泥面附近严重变形的情况。通过对本工程超长大直径钢管桩产生变形的可能性原因进行分析,同时对其变形处局部加强处理方案进行一系列的研究论证,并对加强处理方案进行比选优化后,最后采用一可靠的加强处理方案。为类似工程避免发生此类质量事故和钢管桩局部变形水下加强处理提供参考。  相似文献