三元插层材料的合成及其在聚丙烯老化中的应用          下载免费PDF全文

郭凡  刘志启  王庭胜  李丽娟  李娜 《盐湖研究》2020,28(3)

以FeCl3?6H2O、NiCl2?6H2O、MgCl2?6H2O为原料，以NaOH为沉淀剂采用水热法合成了镁镍铁水滑石 (MgNiFe-LDH)，通过X射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和扫描电镜 (SEM) 分析了MgNiFe-LDH结构及形貌，探讨了不同陈化时间和水热温度对MgNiFe-LDH合成的影响。将制得的MgNiFe-LDH添加至聚丙烯 (PP) 中，制备MgNiFe-LDH/PP复合材料，通过对材料的加速老化测其力学性能，研究了添加MgNiFe-LDH前后材料力学性能的差异。研究结果表明，当Mg2+:Ni2+:Fe3+=2:1:1，反应温度为140℃、陈化时间为24 h时，合成的MgNiFe-LDH为片状，形貌较为规整，颗粒粒径约为2μm；经加速老化后，填充MgNiFe-LDH 复合材料的抗老化性能优于纯PP，当MgNiFe-LDH的填充量为6 wt% 复合材料拉伸强度不变，可明显提高PP的抗老化性能。  相似文献   

Fe₃O₄/Mg(OH)₂复合材料的制备及形貌控制          下载免费PDF全文

韩文生  李丽娟  宋富根  时东  张禹泽  李娜  郭凡 《盐湖研究》2020,28(3):93-98

通过种子沉积法制备出Fe_3O_4/Mg(OH)_2复合材料并进行XRD、SEM测试分析。探究了氨水的浓度与加入速度、搅拌速度及等因素对磁性复合材料形貌的影响。氨水浓度与注入速度的降低,对氢氧化镁基体形貌的影响是相同的,但要使合成磁性复合材料形貌和四氧化三铁粒子在氢氧化镁中分散性均匀,应控制氨水浓度(ω=2.5%)或加入速度在一个合理的较低值。  相似文献   

层合板受鸟撞冲击过程的数值模拟     

童谣  剡小军  刘扬  赵帅磊  鞠殿伟  曲嘉 《地震工程与工程振动》2019,39(6)

近年来,经济的高速发展使人们寻求更快捷的出行方式和运输方式,飞机的方便快捷使其被大力发展,其安全问题也被人们关注并提上研究日程。基于SPH的方法,使用ANSYS/LS-DYNA软件建立了鸟撞层合板的仿真模型,通过仿真分析了鸟撞的四个阶段,首先研究了临界速度前鸟体初始速度与层合板的接触力及鸟体损伤能量的变化情况,然后对比了鸟体损失能量与鸟体质量的关系。结果表明当冲击速度小于临界速度时,接触力峰值随鸟体速度的增大而增加,速度的变化与鸟体损失能量之间呈抛物线关系。  相似文献   

Research on seismic performance of shear walls with concrete filled steel tube columns and concealed steel trusses   总被引：1，自引：1，他引：0  

Wanlin Cao  Jianwei Zhang  Hongying Dong  Min Wang 《地震工程与工程振动(英文版)》2011,10(4):535-546

In order to further improve the seismic performance of RC shear walls, a new composite shear wall with concrete filled steel tube (CFT) columns and concealed steel trusses is proposed. This new shear wall is a double composite shear wall; the first composite being the use of three different force systems, CFT, steel truss and shear wall, and the second the use of two different materials, steel and concrete. Three 1/5 scaled experimental specimens: a traditional RC shear wall, a shear wall with CFT columns, and a shear wall with CFT columns and concealed steel trusses, were tested under cyclic loading and the seismic performance indices of the shear walls were comparatively analyzed. Based on the data from these experiments, a thorough elastic-plastic finite element analysis and parametric analysis of the new shear walls were carried out using ABAQUS software. The finite element results of deformation, stress distribution, and the evolution of cracks in each phase were compared with the experimental results and showed good agreement. A mechanical model was also established for calculating the load-carrying capacity of the new composite shear walls. The results show that this new type of shear wall has improved seismic performance over the other two types of shear walls tested.  相似文献   

秸秆地质聚合物复合材料保温性及耐高温性能研究     

金漫彤  孙烨  陈林伟 《矿物学报》2015,35(2):185-190

为弥补传统秸秆建筑材料在抗压强度、防火性能、保温能力等方面的不足,本实验将秸秆掺入地质聚合物中合成一种新型复合保温建筑材料,研究了不同秸秆含量对材料保温性能的影响,并考察了材料的耐高温性能。结果表明:秸秆地质聚合物具有良好的保温性能,秸秆掺量由1%增至6%时,材料的导热系数由0.0981 W/m·K减至0.0692 W/m·K。秸秆掺入量为4%时,抗压强度为32.78 MPa。耐高温实验结果显示,当煅烧温度低于250℃时,地质聚合物对秸秆具有一定的保护作用。当材料在600℃温度下煅烧120 min后,其抗压强度依然达到35.94MPa。温度在800℃以内材料具有稳定的矿物组成,热稳定性良好。  相似文献   

“MgO/AC”复合材料对水溶液中Cu~(2+)和Cr(Ⅵ)的吸附性能研究     

孙金香  王海增  郭鲁钢  侯少芹  孙宝维 《中国海洋大学学报(自然科学版)》2010,40(6)

用造纸草浆黑液和氯化镁为原料制得氧化镁/活性炭("MgO/AC")复合材料,分别测定了该复合材料对水溶液中Cu2+与Cr(Ⅵ)的脱除性能。Cu2+的吸附随pH值的升高而增大,pH=3时基本达到平衡;在实验考察的pH范围内(1~8),Cr(Ⅵ)的吸附呈单调递减趋势。动力学拟合结果表明,"MgO/AC"复合材料对Cu2+和Cr(Ⅵ)的吸附过程均符合伪二级动力学方程;两过程的吸附速率均随吸附温度的升高而增大,表现为吸热吸附;吸附活化能Ea分别为50.19,51.42 kJ.mol-1;"MgO/AC"复合材料对Cu2+的吸附优于对Cr(Ⅵ)的吸附。Cu2+在"MgO/AC"复合材料上的吸附过程用Langmuir模型描述更为合适,在293~323 K范围内,Cu2+的饱和吸附量为19.46~90.91 mg.g-1;Cr(Ⅵ)的吸附过程则更符合Freundlich模型。  相似文献   

贝壳生物矿化的研究进展   总被引：4，自引：1，他引：3       下载免费PDF全文

张文兵  姚春凤  麦康森 《海洋科学》2008,32(2):74-79

生物体硬组织是高度结构化多功能复合材料的绝佳典范.这些硬组织包括骨组织(骨和茸角)、牙组织(牙本质和牙釉质)、棘皮动物骨骼单位、海绵动物骨针和贝类贝壳.在遗传因素的控制下,生物体通过节能和环境友好途径合成这些生物复合材料.这些有关生物硬组织功能和结构的研究,在医学和工程学上找到了广阔的应用前景.一方面使更好地促进骨骼和牙齿的再生成为可能.  相似文献   

Uplift of symmetrical anchor plates by using grid-fixed reinforced reinforcement in cohesionless soil     

Hamed Niroumand  Khairul Anuar Kassim 《中国海洋工程》2014,28(1):115-126

Uplift response of symmetrical anchor plates with and without grid fixed reinforced （GFR） reinforcement was evaluated in model tests and numerical simulations by Plaxis. Many variations of reinforcement layers were used to reinforce the sandy soil over symmetrical anchor plates. In the current research, different factors such as relative density of sand, embedment ratios, and various GFR parameters including size, number of layers, and the proximity of the layer to the symmetrical anchor plate were investigated in a scale model. The failure mechanism and the associated rupture surface were observed and evaluated. GFR, a tied up system made of fiber reinforcement polymer （FRP） strips and end balls, was connected to the geosynthetic material and anchored into the soil. Test results showed that using GFR reinforcement significantly improved the uplift capacity of anchor plates. It was found that the inclusion of one layer of GFR, which rested directly on the top of the anchor plate, was more effective in enhancing the anchor capacity itself than other methods. It was found that by including GFR the uplift response was improved by 29%. Multi layers of GFR proved more effective in enhancing the uplift capacity than a single GFR reinforcement. This is due to the additional anchorage provided by the GFR at each level of reinforcement. In general, the results show that the uplift capacity of symmetrical anchor plates in loose and dense sand can be significantly increased by the inclusion of GFR. It was also observed that the inclusion of GFR reduced the requirement for a large L/D ratio to achieve the required uplift capacity. The laboratory and numerical analysis results are found to be in agreement in terms of breakout factor and failure mechanism pattern.  相似文献   

不同无机晶须/PVC复合材料力学性能的研究          下载免费PDF全文

李列  乃学瑛  景艳伟  朱成财  李武 《盐湖研究》2014,(4):32-37

采用溶液共混法制备出硼酸镁晶须(MBOw)、硼酸钙晶须(Ca BOw)、硼酸铜铝晶须(Cu Al BOw)、碱式硫酸镁晶须(MOSw)、碳酸钙晶须(Ca CO3w)及硫酸钙晶须(Ca SO4w)增强的PVC复合材料,研究不同晶须对PVC力学性能的影响。采用扫描电镜分析PVC复合材料的拉伸断面及晶须分散情况。结果表明,除MOS外其它晶须对PVC的拉伸强度和弹性模量有不同程度的提高,MBOw对PVC复合材料的增强效果最显著,当MBOw含量为20%时,所得复合材料力学性能最佳,拉伸强度和弹性模量与纯PVC比较分别提高了38.08%和71.43%。  相似文献   

中建西北院预制耗能墙技术获国家专利     

薛晓宁 《中国勘察设计》2014,(10):9-9

近日,中国建筑西北设计研究院（以下简称“中建西北院”）申请的专利技术“预制纤维增强混凝土耗能墙“获得国家知识产权局授权。预制纤维增强混凝土耗能墙由工程纤维增强水泥基复合材料（ECC）预制而成,其延性、耗能能力是普通混凝土墙的2倍～3倍,可作为抗侧力耗能构件安装于主体结构所需部位。由于耗能墙在主体完工后安装,不承担竖向荷载,其截面尺寸较小,具有布置灵活、不影响建筑美观及使用功能、价格低廉、低碳环保的优势,能够有效地解决混凝土结构设计过程中诸如结构扭转不规则、竖向不规则、剪重比不足、框架一剪力墙（核心筒）结构中外框分配剪力不足等一系列问题,可作为屈曲约束支撑的中端替代产品（价格约为屈曲约束支撑的1／3）,应用范围十分广阔。  相似文献