Increasing of efficiency of desulphurisation processes of coals during thermal destruction     

Turchanina Oksana Satin Vladimir Derevyanko Aleksey 《中国地球化学学报》2006,25(B08):51-52

As is well known, a high content of sulphur in coals is an effect of the post-depositional history of coal seams and one of the most important criteria of its use as a fuel. Sulphur in coals can cause a serious environmental and technological problem during their utilization. This problem is very actual for the Donetsk Basin because 734 mined seams out of the total of 1009 （73%） are comprised of coals with sulphur content -2%. The chemical pre-treatment as a first stage in their processing is widely used in order to effectively obtain the thermal destruction products of coals （such as semi-coke, coke, adsorbents, etc.） and to simultaneously utilize coal wastes. Development in pre-treatment methods for high-sulphur, low-rank coals is especially desirable for reducing the sulphur contents of the solid products. The aim of the present work is to investigate the influence of coal pre-treatment on the yield and composition of thermal destruction products, and the sulphur distribution among different components of the coals of different genetic types by reductivity （low-reduced LRC and reduced RC coals）. The thermal behavior of the coals was studied by means of the Fisher method （heated to 520℃, at a rate of 7℃/min）. The composition of the semi-coking gas was investigated by means of a VTI gas analyzer. The coal samples were chemically treated directly before thermal destruction by the introduction of 1-% solutions of radical polymerization initiator AAD （acrylic acid dinitrile C8H12N4） and products of coal-tar distillation （absorber oil）. Coal pre-treatment increases the semi-coke yield and its coking ability, and changes the liquid/gaseous product ratio.  相似文献   

The ＂CO2-rich gas vents＂ of Mt. Amiata volcano （Tuscany, Central Italy）： Geochemistry,genetic mechanism and hazard evaluation     

Franco Tassi Orlando Vaselli Elena Lognoli Fabrizio Cuccoli Barbara Nisi Elena Ramaldi Sandro Moretti Luca Lombardi Bruno Capaccioni 《中国地球化学学报》2006,25(B08):70-71

Mt. Amiata （Southern Tuscany, Central Italy） is an extinct Quaternary volcano located in an area still marked by high heat-flow that is caused by deep seated （6-10 km） hot masses related to Pliocene magmatic activity. The anomalous geothermal gradient gives rise, within the Mesozoic limestone formation （Tuscan series）, to geothermal systems that fed the Ca-SO4 thermal springs characterizing this area. Besides of thermal fluids, several cold, dry CO2-rich gas emissions seep out on the NE flank of the volcano. These gas vents mostly consist of large sub-circular craters at variable depth and diameter （5-15 m and 10-50 m, respectively）, and represent a serious hazard for the local population, as testified by the several asphyxia casualties that have been repeatedly occurred within these morphological depressions. In this work, the chemical and isotopic compositions of the Mt. Amiata ＂CO2-rich gas vents＂ and the estimation of both the CO2 flux from the soil and the CO2 distribution in air of their surroundings, has been carried out in order to： （1） assess the origin of gases, （2） recognize the mechanism of formation for these gas emissions and their relationship with local tectonics, and （3） to evaluate the CO2 hazard in the high flux emanations. The chemical composition of the gases is largely dominated by CO2 （up to 98 % by vol） and shows relatively high concentrations of N2, CH4 and H2S （up to 1.1%, 0.9% and 3.9 % by vol, respectively）. These features, coupled with the carbon and nitrogen isotopic signatures, suggest that the origin of the main gas compounds may be related to the contribution of deep （i.e., thermometamorphic processes on carbonate formations for CO2） and shallow （i.e. thermal decomposition of organic material for CH4, N2 and H2S） sources.  相似文献   

吐哈盆地十红滩铀矿床水文地球化学特征   总被引：6，自引：0，他引：6  

乔海明  张天太  张复新  尚高峰  宋哲 《铀矿地质》2005,21(6):345-352

本文根据水化学资料的研究,探讨了十红滩铀矿床含矿含水层高矿化度地下水的成因,分析了高矿化度水对铀溶解迁移的影响及碳酸盐的形成机理.  相似文献   

焦炉烟气重点有毒有害物质筛选分析方法研究     

张兰英  尚庆坤 《长春地质学院学报》1997,27(4):474-475

  相似文献   

燃煤烟气中SO2治理方法综述   总被引：2，自引：0，他引：2  

余江  陈攀江  龙炳清  宋薇薇  赵仕林 《地质灾害与环境保护》2001,12(2):45-48

对燃煤烟气中SO2的脱除方法进行综述和分析。  相似文献   

布雅煤矿——井田煤中硫的特征及脱硫方法     

徐进  敬益武 《煤田地质与勘探》2001,29(5):14-16

从宏观、微观和煤化学几个方面，研究了新疆和田县布雅煤矿一号井田主采煤层中硫的赋存形态、含量、变化规律及成因。并提出几种脱硫方法，对煤矿生产出质量好的洁净煤，有一定的参考价值。  相似文献   

减轻煤炭对生态影响的一条捷径——提高发电厂生产效率     

良可 《国土资源情报》2009,(11):26-26

毋庸置疑，对煤进行洁净处理和脱硫或者采用碳捕获与储存技术，可以最大限度地减轻燃煤发电对环境的影响，但还有一种选择，就是减少煤的用量。  相似文献   

潮间带沉积物厌氧烃降解细菌的多样性及Desulfovibrio subterraneus ND17的分离鉴定     

张琪  邓晔  邵宗泽  王万鹏 《海洋学报》2022,44(8):78-86

潮间带作为海陆交界处,易受到来自海洋的石油污染,且各类石油烃进入沉积物后的降解过程尚不清楚。前人在各类生境中对好氧微生物烃降解方面已有较多研究,但对近海潮间带环境中的厌氧烃降解鲜有报道。本研究对青岛女岛湾潮间带沉积物深层样品以混合烃（中长链烷烃、多环芳烃）为碳源,硫酸盐作为电子受体进行厌氧富集培养。富集菌群的细菌多样性表明在混合烃作为碳源的作用下,优势菌群转变为脱硫叠球菌科（Desulfosarcinaceae）、脱硫杆菌科（Desulfobacteraceae）等具有石油烃降解潜力的硫酸盐还原菌。经分离纯化得到一株厌氧烃降解菌ND17,与地下脱硫弧菌属模式种Desulfovibrio subterraneus HN2T 16S rRNA基因序列的相似度为99.93%。进一步实验表明,菌株ND17在厌氧条件下对二十四烷和菲的降解率可分别达到53.9%和35.7%。这也是首次对脱硫弧菌属单菌在厌氧条件下进行石油烃降解的研究。脱硫弧菌作为一种广泛分布在厌氧环境的细菌,本研究为进一步认识其在海洋石油污染环境中的修复潜力提供了支撑。  相似文献   

脱硫海水排放对附近海域的生态环境影响初步研究     

王云鹏  纪良  时国梁  汝少国 《中国海洋大学学报(自然科学版)》2014,44(5):61-68

通过跟踪监测华电青岛发电有限公司脱硫海水排放口附近海域的水质、表层沉积物质量和海洋生物群落结构,初步探讨了脱硫海水排放对海泊河口及附近海域生态环境的影响。结果表明:(1)脱硫海水特征污染物排放对排水口下游水域会造成一定不利影响,主要表现在pH值和DO的明显降低以及水温的明显升高,影响范围局限于排水口下游400m范围内的河口段;(2)脱硫海水排放不会明显增加排水口下游COD、N、P的污染负荷;(3)脱硫海水排放未显著增加附近海域重金属的综合潜在生态危害程度,重金属的潜在污染风险较小;(4)调查海域冬、夏两季生物多样性较高,群落结构较稳定,脱硫海水排放未对生物群落结构和生物多样性造成明显的不利影响。  相似文献   

低温甲醇洗净化气中硫含量的影响因素分析     

刘学武 《地球物理学进展》2012,40(3)

山东兖矿国宏化工有限责任公司低温甲醇洗装置是典型的鲁奇七塔流程,设计处理气量为218000m2／h（标态）。本项目以高硫煤为原料,经德士古气化制得原料气,经中温部分变换,低温甲醇洗工艺脱硫脱碳,使出工段净化气中总硫体积分数≤0．1×10^-6,φ（CO2）≤3％,净化气经联合压缩机加压至8．2MPa进合成塔得到粗甲醇。  相似文献