川西冕宁-德昌稀土矿带霓长岩的地球化学特征及地质意义   总被引：2，自引：0，他引：2  

舒小超  刘琰  李德良  贾玉衡 《岩石学报》2019,35(5):1372-1388

霓长岩化作用是指碳酸岩(或碱性岩)流体对围岩的交代蚀变,它是碳酸岩型稀土(REE)矿床常见的蚀变类型,其所形成的岩石即为霓长岩。对霓长岩的深入研究可以鉴别碳酸岩体的存在,厘定碳酸岩岩浆(或流体)的地球化学性质及源区特征,这对于找寻碳酸岩相关的矿产资源(尤其是REE)以及剖析矿床成因机制有着重要的地质意义。川西冕宁-德昌稀土矿带是中国最重要的轻稀土矿带之一,包括牦牛坪超大型、大陆槽大型、木落寨和里庄中小型REE矿床以及一系列矿点。REE矿化与碳酸岩-碱性岩杂岩体密切相关,受一系列新生代走滑断裂的控制。该矿带广泛发育霓长岩化蚀变带,尤以大陆槽及里庄矿床为显著。岩相学分析表明,大陆槽和里庄霓长岩中的矿物多呈他形粒状结构,主要由长石、黑云母、霓辉石以及少量副矿物组成;主微量元素分析表明,霓长岩的碱质(K_2O+Na_2O)、MgO、Fe_2O_3T含量较高,且富集REE、Sr、Ba等微量元素;电子探针分析表明,霓长岩中的霓辉石Fe OT含量较高,长石Na_2O及K_2O含量较高,Ca O含量极低。An-Ab-Or三角图解显示长石主要为透长石和钠长石,属碱性长石系列;黑云母的地球化学成分图解表明云母的成因类型为交代型且具有相对富镁、贫铁等特征,属镁质黑云母。霓长岩化作用的交代流体含有较高的CO_2组分,且富含碱质、Mg、Fe及REE、Sr、Ba等元素。对比霓长岩与原岩的主微量元素发现:相比于正长岩原岩,在主量元素中,霓长岩的Fe、Mg、Ca等元素含量增加,Si、Al等元素含量降低;微量元素中,霓长岩的REE及Sr、Ba等元素显著增加。这意味着交代流体含有的Fe_2O_3T、MgO、CaO等组分在霓长岩化过程中被带进了围岩,而SiO_2和Al_2O_3等从围岩中被逐出。大陆槽及里庄矿区发育的角砾岩指示了矿区曾经历过频繁的角砾岩化事件,这提高了霓长岩作用的强度,并且为矿脉的穿插及REE矿物的沉淀提供了空间。在霓长岩化过程中,流体-围岩的组分交换反复发生,这削弱了REE络合物的稳定性,伴随多期次的热液活动及构造事件,最终完成REE活化→迁移→沉淀的过程。  相似文献   

基于分段副产物瞬时选择性的反应器网络综合     

胡仰栋  周勇  伍联营 《中国海洋大学学报(自然科学版)》2020,50(3):61-66

针对第三类反应体系的反应器网络综合问题,提出将串联反应以反应物到目的产物的反应步数为依据的新分段策略。通过比较不分段目的产物、不分段目的产物和中间产品、分段副产物和分段目的产物这四种不同的瞬时选择性,提出以分段副产物瞬时选择性为参数,以其对关键组分浓度或转化率的导数为依据选择各阶段最合适的反应器,以目的产物总选择性最大为目标采用遗传算法优化反应器网络。通过三个实例验证了本文所建立方法在解决复杂反应反应器网络综合问题的有效性,且本方法同样适用于简单反应体系。  相似文献   

Deep gold mineralization features of Jiaojia metallogenic belt,Jiaodong gold Province: Based on the breakthrough of 3000 m exploration drilling     

《China Geology》2020,3(3):385-401

Recently, continuous breakthroughs have been made about deep gold prospecting in the Jiaodong gold province area of China. Approximately 5000 t of cumulative gold resources have been explored in Jiaodong, which has thus become an internationally noteworthy gold ore cluster. The gold exploration depth has been increased to about 2000 m from the previous <1000 m. To further explore the mineralization potential of the Jiaodong area at a depth of about 3000 m, the Shandong Institute of Geological Sciences has drilled an exploratory drillhole named “Deep drillhole ZK01” to a depth of 3266 m. Hence, as reported herein, the mineralization characteristics of the Jiaojia metallogenic belt have been successfully documented. ZK01 is, to date, the deepest borehole with an gold intersect in China, and constitutes a significant advance in deep gold prospecting in China. The findings of this study further indicate that the depth interval of 2000 m to 4000 m below the ground surface in the Wuyi Village area incorporates 912 t of inferred gold resources, while the depth interval of 2000 m to 4000 m below the surface across the Jiaodong area possesses about 4000 t of inferred gold resources. The Jiaojia Fault Belt tends to gently dip downward, having dip angles of about 25° and about 20° at vertical depths of 2000 m and 2850 m, respectively. The deep part of the Jiaojia metallogenic belt differs from the shallow and moderately deep parts about fracturing, alteration, mineralization, and tectonic type. The deep zones can generally be categorized from inside outward as cataclastic granite, granitic cataclasite, weakly beresitized granitic cataclasite, beresitized cataclasite, and gouge. These zones exhibit a gradual transitional relation or occur alternately and repeatedly. The mineralization degree of the pyritized cataclastic granite-type ore in the deep part of the Jiaojia metallogenic belt is closely related to the degree of pyrite vein development; that is, the higher the pyrite content, the wider the veins and the higher the gold grade. Compared to the shallow gold ores, the deep-seated gold ores have higher fineness and contain joseite, tetradymite, and native bismuth, suggesting that the deep gold mineralization temperature is higher and that mantle-sourced material may have contributed to this mineralization. ZK01 has also revealed that the deep-seated ore bodies in the Jiaojia metallogenic belt are principally situated above the main fracture plane (gouge) and hosted within the Linglong Granite, contradicting previous findings indicating that the moderately shallow gold ore bodies are usually hosted in the contact zone between the Linglong Granite and Jiaodong Group or meta-gabbro. These new discoveries are particularly significant because they can help correct mineralization prospecting models, determine favorable positions for deep prospecting, and improve metallogenic prediction and resource potential evaluation.  相似文献   

Melt migration and melt-rock reaction in the Alpine-Apennine peridotites:Insights on mantle dynamics in extending lithosphere     

Elisabetta Rampone  Giulio Borghini  Valentin Basch 《地学前缘(英文版)》2020,11(1):151-166

The compositional variability of the lithospheric mantle at extensional settings is largely caused by the reactive percolation of uprising melts in the thermal boundary layer and in lithospheric environments.The Alpine-Apennine(A-A)ophiolites are predominantly constituted by mantle peridotites and are widely thought to represent analogs of the oceanic lithosphere formed at ocean/continent transition and slow-to ultraslow-spreading settings.Structural and geochemical studies on the A-A mantle peridotites have revealed that they preserve significant compositional and isotopic heterogeneity at variable scale,reflecting a long-lived multi-stage melt migration,intrusion and melt-rock interaction history,occurred at different lithospheric depths during progressive uplift.The A-A mantle peridotites thus constitute a unique window on mantle dynamics and lithosphere-asthenosphere interactions in very slow spreading environments.In this work,we review field,microstructural and chemical-isotopic evidence on the major stages of melt percolation and melt-rock interaction recorded by the A-A peridotites and discuss their consequences in creating chemical-isotopic heterogeneities at variable scales and enhancing weakening and deformation of the extending mantle.Focus will be on three most important stages:(i)old(pre-Jurassic)pyroxenite emplacement,and the significant isotopic modification induced in the host mantle by pyroxenite-derived melts,(ii)melt-peridotite interactions during Jurassic mantle exhumation,i.e.the open-system reactive porous flow at spinel facies depths causing bulk depletion(origin of reactive harzburgites and dunites),and the shallower melt impregnation which originated plagioclase-rich peridotites and an overall mantle refertilization.We infer that migrating melts largely originated as shallow,variably depleted,melt fractions,and acquired Si-rich composition by reactive dissolution of mantle pyroxenes during upward migration.Such melt-rock reaction processes share significant similarities with those documented in modern oceanic peridotites from slow-to ultraslow-spreading environments and track the progressive exhumation of large mantle sectors at shallow depths in oceanic settings where a thicker thermal boundary layer exists,as a consequence of slow-spreading rate.  相似文献   

珠江口盆地荔湾凹陷上渐新统—早中新统物源特征及其对沉积充填的影响     

邢作昌  张忠涛  林畅松  张博  洪方浩  张正涛 《中国地质》2020,47(5):1577-1588

利用化学蚀变指数法恢复物源区的风化历史及沉积物通量是一种经济实用、行之有效的方法。前人对珠江口盆地荔湾凹陷对应物源区的研究相对薄弱。本文通过对区内岩心测试数据进行化学蚀变指数分析，恢复晚渐新世—早中新世物源区的风化历史，并进行沉积物通量的估算，在此基础上探讨物源特征对研究区内沉积充填的控制作用。研究表明，晚渐新世研究区对应物源区经历了强烈风化阶段，该阶段产生的丰富的沉积物供给是研究区西北部快速进积、规模壮观的陆架边缘三角洲及斜坡重力流沉积体系发育的重要控制因素之一；早中新世，西北物源区风化减弱，沉积供给减少，但研究区东部沉积物供应较西部要充分得多，表明早中新世，研究区南部除了来自西北部的主要物源外，局部物源对该时期的沉积具有重要影响；推测东部物源(东部古隆起、兴宁古隆起)的突然复活是促进研究区东部早中新世沟槽形成发育的重要原因之一。在超深水区进行沉积物源区的研究中，这种半定量的方法对盆内局部物源的确定具有重要的指示意义。  相似文献   

Adsorption of Arsenite from Groundwater Using Titanium Dioxide          下载免费PDF全文

Miriam Z. López Paraguay  José Apolinar Cortes  Juan F. Pérez‐Robles  María T. Alarcón‐Herrera 《洁净——土壤、空气、水》2014,42(6):713-721

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A new numerical approach to the hyperstatic reaction method for segmental tunnel linings     

Ngoc Anh Do  Daniel Dias  Pierpaolo Oreste  Irini Djeran‐Maigre 《国际地质力学数值与分析法杂志》2014,38(15):1617-1632

This paper proposes a numerical approach to the hyperstatic reaction method (HRM) for the analysis of segmental tunnel linings. The influence of segmental joints has been considered directly using a fixity ratio that is determined on the basis of the rotational stiffness. The parameters necessary for the calculation are presented. A specific implementation has been developed using a FEM framework. This code is able to consider the three‐dimensional (3D) effect of segment joints in successive rings on the tunnel lining behaviour. The present HRM allows one to take an arbitrary distribution of segment joints along the tunnel boundary into consideration. In addition, the rotational stiffness of segment joints has been simulated using nonlinear behaviour, as it is closer to the true behaviour of a joint than linear or bilinear behaviour. The numerical results of three hypotheses on ring interaction, which allow the 3D effect of a segmental tunnel lining to be taken into account, have been compared with data obtained from the shield‐driven tunnel of the Bologna–Florence high‐speed railway line project. The numerical results presented in the paper show that the proposed HRM can be used to effectively estimate the behaviour of a segmental tunnel lining. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Hydrothermal alteration processes in the giant Dahutang tungsten deposit,South China: Implications from litho-geochemistry and mass balance calculation     

《China Geology》2021,4(2):230-244

The giant Dahutang tungsten (W) deposit has a total reserve of more than 1.31 Mt WO₃. Veinlet-disseminated scheelite and vein type wolframite mineralization are developed in this deposit, which are related to Late Mesozoic biotite granite. Four major types of alterations, which include albitization, potassic-alteration, and greisenization, and overprinted silicification developed in contact zone. The mass balance calculate of the four alteration types were used to further understanding of the mineralization process. The fresh porphyritic biotite granite has high Nb, Ta, and W, but low Ca and Sr while the Jiuling granodiorite has high Ca and Sr, but low Nb, Ta, and W concentrations. The altered porphyritic biotite granite indicated that the Nb, Ta, and W were leached out from the fresh porphyritic biotite granite, especially by sodic alteration. The low Ca and Sr contents of the altered Neoproterozoic Jiuling granodiorite indicate that Ca and Sr had been leached out from the fresh granodiorite by the fluid from Mesozoic porphyritic biotite granites. The metal W of the Dahutang deposit was mainly derived from the fluid exsolution from the melt and alteration of W-bearing granites. This study of alteration presents a new hydrothermal circulation model to understand tungsten mineralization in the Dahutang deposit.  相似文献   

云南保山从干树金矿控矿条件及矿床成因讨论     

李先棋  涂向衡  杜彦强  李琼仙 《云南地质》2011,30(2):130-133,140

从干树金矿赋存于怒江构造带高黎贡山岩群变质岩系中,有两个明显的次级矿化带,具多期次成矿作用特点:前期可能为沉积变质赋矿,后期为剪切(构造热液)成矿。晚期在浅部风化淋滤富集。剪切作用形成的金矿是主体。  相似文献   

云南沧源羊缅金矿成因     

高李阳  王爱萍 《云南地质》2011,30(3):273-274

羊缅金矿位于昌宁-孟连有色金属贵金属成矿带,金矿受压扭性断裂控制,分布于变余辉长辉绿岩中,典型的低温热液蚀变型金矿床。  相似文献