排序方式： 共有33条查询结果，搜索用时 19 毫秒
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浊点是非离子表面活性剂的一个特性参数，它是非离子表面活性荆溶液由透明变浑浊，和由浑浊变透明的平均温度。聚乙二醇辛基苯基醚是一种非离子表面活性剂，通过实验测定了有机酸、醇、无机盐、聚合物等添加剂对聚乙二醇辛基苯基醚浊点的影响。结果表明，不加任何添加剂时，聚乙二醇辛基苯基醚的浊点为89℃；添加有机酸时，浊点随浓度升高先下降后上升；添加醇时，碳链短的随浓度升高浊点升高，碳链长的随浓度升高而下降；添加无机钠盐时，浊点随浓度升高而下降；添加聚合物时。浊点超过100℃。 相似文献
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Organic pollutants associated with macromolecular soil organic matter: Mode of binding 总被引：2，自引：0，他引：2
H. H. Richnow R. Seifert J. Hefter M. Link W. Francke G. Schaefer W. Michaelis 《Organic Geochemistry》1997,26(11-12)
A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process. 相似文献
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气相色谱-质谱法分析土壤中十溴联苯醚 总被引：4，自引：0，他引：4
通过优化分析仪器的条件设置,建立了使用气相色谱-质谱技术分析十溴联苯醚(BDE 209)的仪器分析方法。通过实施严格的质量控制和质量保证(QA/QC)措施,建立了使用加速溶剂萃取(ASE)技术测试土壤中十溴联苯醚的分析检测方法。该方法的仪器检出限为9.75pg,方法检出限3.25ng/g,方法的精密度为5.56%,平均回收率为86.8%。比较了加速溶剂萃取、微波萃取、超声萃取、索氏抽提等方法的萃取回收效率,实验结果表明,四种方法的萃取回收率在97.7%~108%,都可以作为分析检测土壤中BDE 209的萃取方法。 相似文献
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设计合成一种尚未见文献报道的酚醚型双臂开链冠醚化合物L(L=2,6-二(8’-喹啉氧甲基)-4-甲基-苯甲醚)，经元素分析、IR、1HNMR、MS等方法确定了其组成和结构。其Ag(Ⅰ)、Cu(Ⅱ)、Ni(Ⅱ)固体配合物的元素分析结果表明金属离子不同，则其配合物的配位比(M∶L)不同，Ag(Ⅰ)配合物为1∶1，Cu(Ⅱ)、Ni(Ⅱ)配合物为2∶3。并运用热重-差热分析对其热稳定性进行初步研究。 相似文献
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This study was carried out to investigate the scour phenomenon at the toe of seawalls and the different parameters that affected it. Experiments were achieved using different wave steepnesses, bed material grain sizes, wall positions and inclinations. Based on experimental results, the parametric plots of toe scour for smooth impermeable inclined seawalls were prepared. Also, this paper presents the bed changes prediction at seawalls toe using artificial neural networks on the basis of experimental data to widen the range of application. Suitability of using a neural network model was developed, and a model was validated. It is proposed that this model can be used in coastal engineering applications. 相似文献
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Arkadiusz Derkowski Wojciech Franus Halina Waniak-Nowicka Adriana Czímerová 《International Journal of Mineral Processing》2007
Zeolite Na–X (FAU type) was synthesized from F-class fly ash in simple and economical way. Several months of storage of fly ash in NaOH solution, at room temperature, without any prior treatment, results in the production of material with ca. 50% content of Na–X zeolite. The most efficient reaction takes place at (OH)− activity of 0.1–0.15 mol (OH)−/g of ash and at S/L ratio of 33 to 67 g/dm3. Higher S/L value causes an accelerating dissolution–crystallization equilibrium attainment. Cl− ion acts as the inhibitor of this reaction. 相似文献