Geochemical characteristics and sedimentary environment of the Middle Devonian organic-rich shales in the Northwest of Guizhong Depression,Southwest China     

《China Geology》2020,3(4):567-574

In order to figure out the redox conditions and paleo-sedimentary environment of the Middle Devonian shales in the northwest of Guizhong Depression, the trace element analysis was conducted on the Middle Devonian cores (320.35–938.50 m) of the typical shale gas investigation well (GY-1) at a 1.50 m sampling interval through X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). According to the test result, the average values of V/(V+Ni), V/Cr and Ni/Co in Nabiao formation (Fm.) are larger than 0.67, 4.65 and 7.71 respectively, and Nabiao Fm. is rich in biological assemblages such as tabasheer, ammonite, etc. These evidences indicate the rising sea level rose relatively in the sedimentation period of Nabiao Fm. and a deepwater shelf environment, which was favorable for the preservation of organic matters. The V/(V+Ni), V/Cr and Ni/Co in Luofu Fm. and Tangting Fm. are 0.38–0.65, 0.73–4.10 and 3.70–6.72 respectively, indicating that the sea level dropped relatively in their sedimentation period, during which the water bodies became shallow, and the sedimentary environment was a weak oxidizing shallow water shelf environment. In addition, the variation of TOC has a high correlation with the enrichment degree of Ba element, indicating the favorable conditions for the enrichment and preservation of organic matters under an oxygen-deficient environment. Moreover, according to the identification of trace element indexes, the northwest of Guizhong Depression experienced the sedimentary cycle of relative rise to relative fall of sea level from bottom to top in the Middle Devonian sedimentation period. The relative sea level rose to the highest in the sedimentation period of Nabiao Fm., in which the organic-rich shales with stable thickness and high organic content were deposited. Hence, the Nabiao Fm. could be regarded as the favorable exploration target interval in this area.  相似文献   

Geochemistry,detrital zircon geochronology and Hf isotope of the clastic rocks in southern Tibet: Implications for the Jurassic-Cretaceous tectonic evolution of the Lhasa terrane     

《Gondwana Research》2020

In order to reconstruct tectonic evolution history of the southern margin of Asia (i.e., Lhasa terrane) before the India-Asia collision, here we present a comprehensive study on the clastic rocks in the southern Lhasa terrane with new perspectives from sedimentary geochemistry, detrital zircon geochronology and Hf isotope. Clasts from the Jurassic-Early Cretaceous sedimentary sequences (i.e., Yeba and Chumulong Formations) display high compositional maturity and experienced moderate to high degree of chemical weathering, whereas those from the late Early-Late Cretaceous sequences (Ngamring and Shexing Formations) are characterized by low compositional maturity with insignificant chemical weathering. Our results lead to a coherent scenario for the evolution history of the Lhasa terrane. During the Early-Middle Jurassic (∼192-168Ma), the Lhasa terrane was speculated to be an isolated geological block. The Yeba Formation is best understood as being deposited in a back-arc basin induced by northward subduction of the Neo-Tethys ocean with sediments coming from the interiors of the Lhasa terrane. The Middle Jurassic-Early Cretaceous Lhasa-Qiangtang collision resulted in the formation of a composite foreland basin with southward-flowing rivers carrying clastic materials from the uplifted northern Lhasa and/or Qiangtang terranes. During the late Early-Late Cretaceous (∼104-72Ma), the Gangdese magmatic arc was uplifted rapidly above the sea level, forming turbidites (Ngamring Formation) in the Xigaze forearc basin and fluvial red beds (Shexing Formation) on the retro-arc side. At the end of Late Cretaceous, the Lhasa terrane was likely to have been uplifted to high elevation forming an Andean-type margin resembling the modern South America before the India-Asia collision.  相似文献   

江南造山带东段陈蔡地区新元古代高硅埃达克质花岗闪长岩的发现及其构造启示     

谭清立  王岳军  张玉芝  杨雪  芶琪钰  周永智  张立敏 《岩石学报》2019,35(6):1907-1923

华南由扬子板块与华夏板块在新元古代拼合而成,其拼合时间与演化模式一直广受争议。江南造山带是其重要的拼合带,带内保留一系列新元古代沉积作用-岩浆活动记录,是研究扬子板块与华夏板块拼贴碰撞时间与演化机制的理想场所。本文针对江南造山带东段陈蔡地区花岗闪长岩,开展了LA-ICP-MS锆石U-Pb年代学、全岩主微量元素及Sr-Nd同位素地球化学研究。代表性样品的~(206)Pb/~(238)U加权平均年龄为838±5Ma和836±4Ma,为花岗闪长岩的原岩结晶年龄。样品K_2O含量为1.30%～2.57%,铝饱和指数(A/CNK)为1.01～1.54,为钙碱性过铝质花岗闪长岩。样品高Si O_2(63.38%～68.97%)、Al_2O_3(15.30%～16.70%)、Na_2O(3.89%～6.24%)、Sr(306×10~(-6)～628×10~(-6))、Sr/Y(26～80)和低Mg O含量(0.64%～1.99%)、K_2O/Na_2O(0.17～0.64)、低Y含量(3.38×10~(-6)～16.10×10~(-6))和Yb含量(0.42×10~(-6)～1.67×10~(-6)),δEu异常不明显,相对富集轻稀土和大离子亲石元素、强烈亏损重稀土和高场强元素、低~(87)Sr/~(86)Sr初始值(0.7015～0.7022)和高ε_(Nd)(t)值(+4.10～+6.13),具有与高硅埃达克岩相似的特征。结合区域构造演化背景,认为陈蔡花岗闪长岩是扬子板块与华夏板块之间的古洋壳向双溪坞陆弧地体俯冲的过程中,俯冲板片熔体被少量地幔楔橄榄岩同化和交代的产物,暗示838～836Ma时江南造山带东段仍处于俯冲消减阶段,扬子与华夏尚未完成最终拼合。综合现有证据,认为扬子与华夏在江南造山带各区段于ca.825～820Ma完成拼合。  相似文献   

Chronological and geochemical constraints on the pre-variscan tectonic history of the Erzgebirge,Saxothuringian Zone     

《Gondwana Research》2020

A combined U–Pb zircon geochronological and whole-rock isotopic and geochemical study has been carried out on high-grade orthogneiss, meta-basite, and meta-sediments from the Erzgebirge. The results indicate multiple pulses of Ediacaran–Ordovician magmatism in a transitional volcanic-arc to rift-basin setting. Orthogneiss from high-pressure nappes exhibit a step-like pattern of inherited zircon ages and emplacement ages of 500–475 Ma. In contrast, granite gneiss from the medium-pressure core of the Erzgebirge is characterised by three pulses of magmatism in the Early Cambrian, Late Cambrian, and Early Ordovician. A trend of decreasing Th/U ratios in zircon is observed to c.500 Ma, after which significant increases in the trend and variability of the data is inferred to mark the transition from arc-related to rift-related magmatism. Sediments deposited in the Early Cambrian have continental island arc affinity. Major detrital peaks in the Ediacaran and subordinate Tonian, Palaeoproterozoic, and Neoarchaean data are consistent with an Avalonian-Cadomian Arc and West African Craton derivation. The Early Cambrian sediments were locally reworked by a thermal event in the Ordovician resulting in leucocratic banding and recorded in Ordovician zircon rims characterised by systematically lower Th/U ratios. Ptygmatically folded leucocratic bands containing Ordovician zircon rims, associated with low Th/U ratios, are further observed in the granite gneiss core of the Erzgebirge. Variscan ages are rare, except in a fine-grained high-pressure micaschist, which contains exclusively small, structure-less, zircon with a weighted mean age of 350 ± 2 Ma. These data, along with a re-evaluation of previously published data, have been interpreted as the product of flattening subduction during the Early Cambrian; followed by the opening of slab windows in the Late Cambrian; and finally delamination in the Early Ordovician. Delamination of the orphaned slab led to asthenospheric upwellings triggering extension, bimodal magmatic pulses, recycling of fertile crust, high-temperature metamorphism, and cratonisation of relatively young crust.  相似文献   

郯庐断裂带新沂—泗洪段土壤气Rn体积活度和CO2浓度特征研究     

缪阿丽  张扬  方震  李锋  王维  高力 《地震》2019,39(1):48-57

郯庐断裂带江苏段地区4个剖面进行了土壤气Rn体积活度和CO₂浓度测量结果显示, 自北向南土壤气Rn体积活度均值分别为22.9 kBq/m³、 35.5 kBq/m³、 40.2 kBq/m³、 26.6 kBq/m³; 自北向南土壤气CO₂浓度均值分别为0.669%、 0.400%、 0.503%、 1.109%。 土壤气Rn体积活度和CO₂的浓度在空间分布上具有较好的一致性, 这可能与CO₂是Rn的载气有关。 综合分析土壤气Rn和CO₂测量结果以及水准资料可得, 2017年土壤气Rn高值出现在晓店段可能与区域应力应变调整有关。 本研究不仅为研究区以后的土壤气研究提供了参考, 同时也可为研究区的构造活动研究提供地球化学资料参考。  相似文献   

川西中三叠统雷口坡组三段-四段白云岩特征与成因——来自于岩相学及地球化学的约束   总被引：1，自引：0，他引：1  

钱一雄  武恒志  周凌方  黄康俊  邓美洲  李勇  董少峰  王琼仙 《岩石学报》2019,35(4):1161-1180

白云岩化是影响储层发育是否的重要沉积-成岩过程。作者通过在对川西地区的中三叠统雷口坡组的雷三至雷四段的岩相学,碳、氧、锶、镁同位素以及元素地球化学等综合研究,划分出含膏的泥晶云岩AD0、泥晶云岩D0、泥粉晶云岩D1、粉细晶云岩D2、微生物云岩MD、含灰质藻云岩CD(交代结构)以及去云化的泥粉晶云岩(CD0CD1)等七类白云岩。白云石有序度及铁、锰含量较低。阴极发光以暗紫、暗紫红、蓝紫为主;次为玫瑰红、橙红及橙黄红色。δ~(13)CPDB=1. 95‰～2. 46‰,δ~(18)OPDB=-4. 05‰～2. 70‰;~(87)Sr/~(86)Sr=0. 70778～0. 70807,δ~(26)Mg=-1. 872‰～-2. 124‰,其中δ~(13)C_(PDB)、~(87)Sr/~(86)Sr的平均值与中三叠世全球海水相似;δ~(18)O_(PDB)为弱负漂及正偏移。从D2、D1至D0、AD0,Sr、Na和大部分微量元素含量及比值和δ~(18)O_(PDB)逐渐增加; AD0、少量D0或MD相对富含硅、铝,并与高(低镁)方解石、黏土、有机质等共生。离子组成反映出白云石的前驱物以方解石型为主,少量为文石、原白云石结构。存在广盐、稍咸和超盐度的碱性等沉积环境。白云岩形成主要受向上变浅米级旋回序列,干燥、炎热为主、偶夹潮湿古气候以及古地貌-古水文条件等因素影响。存在浅潟湖的萨勃哈(AD0或D0)、环潮缘至局限台地(D0-D1、微生物诱导MD)、潮间-潮下的微生物礁(席)构成的障壁的台缘带(MD-CD1-CD)、潮坪-开阔台地(D0-D2-CD1、MD)等环境,以萨勃哈和受蒸发泵-密度差驱动的"渗透-回流白云石化"模式为主。  相似文献   

An integrated ore prospecting model for the Nyasirori gold deposit in Tanzania     

《China Geology》2019,2(4):407-421

The Nyasirori gold deposit, located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania, is a tectonic altered rock type gold deposit controlled by shear tectonic zone. This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets, utilized induced polarization (IP) intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore (mineralized) bodies, and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore (mineralized) bodies. The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body. Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold (mineralized) ore bodies. Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb, and As and Sb anomalies have a good indication to gold orebodies. Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit, this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.  相似文献   

黔中—渝南铝土矿含矿岩系微量元素区域分布特征及物质来源探讨          下载免费PDF全文

刘平  韩忠华  廖友常  聂坤 《贵州地质》2020,37(1):1-13

黔中—渝南成矿带石炭纪铝土矿含矿岩系,分别形成于修文、息烽—遵义和黔北—渝南三个沉积区,大多数铝土矿属产于碳酸盐岩侵蚀面上的、少数为产于泥页岩侵蚀面上的硬水铝石沉积型铝土矿床。修文沉积区铝土矿中Zr、RE2O3含量最多,息烽—遵义沉积区铝土矿中Ga含量最多,黔北—渝南沉积区Li含量最多,各有特色。修文沉积区铝土矿含矿岩系的母岩,是其下伏寒武系碳酸盐岩与下奥陶统页岩、灰岩、白云岩;息烽—遵义沉积区含矿岩系的母岩为下伏下奥陶统页岩、灰岩及白云岩;黔北—渝南沉积区含矿岩系的母岩,是下伏下志留统泥、页岩和上石炭统石灰岩。碳酸盐岩中Al2O3与稳定的微量元素含量甚少,要演变成大面积铝土矿,必须要配以足够的含Al2O3和微量元素较多的泥、页岩,才可能满足形成大规模铝土矿的物质需求。  相似文献   

北山造山带中部(甘肃段)花岗岩成因及构造背景   总被引：2，自引：2，他引：0  

白荣龙  刘显凡  周慧玲 《岩石学报》2020,36(6):1731-1754

北山造山带中部花岗岩体以陶勒努图洪岩体和跃进山南岩体为代表,本文对这两个岩体进行了LA-ICP-MS锆石U-Pb定年、全岩地球化学和原位锆石Lu-Hf同位素分析,结果表明:岩体成岩年龄分别为410±2. 8Ma、427±2. 5Ma;主量元素呈现高硅、高钾钙碱性、准铝质-弱过铝质特征;微量元素表现为富集Th、Zr、Hf等及大离子亲石元素(Rb、U、K等),亏损Ba、Sr、Eu及高场强元素(Nb、Ta、P、Ti等);球粒陨石标准化稀土元素曲线呈轻稀土富集、重稀土亏损的右倾模式。综合分析认为跃进山南岩体属A型花岗岩,陶勒努图洪岩体属S型花岗岩。陶勒努图洪和跃进山岩体锆石ε_(Hf)(t)分别为-2. 90～-0. 12(平均值为-1. 53)、-1. 99～2. 82(平均值为0. 26),t_(DM2)分别为1. 41～1. 58Ga、1. 23～1. 54Ga。研究表明:陶勒努图洪黑云母花岗闪长岩岩浆源区主要为由元古界北山杂岩组成的以变质杂砂岩为主的古老地壳物质(含中基性岩石)部分熔融的产物,跃进山南二长花岗岩体可能在元古界北山杂岩组成的以变质杂砂岩为主的古老地壳物质重熔过程中有幔源岩浆的参与。在中志留世(427Ma)明水-小黄山洋已向南侧马鬃山-公婆泉弧之下俯冲至后期,板块后撤引发明水-旱山地体南缘弧后形成裂解环境导致幔源岩浆底侵,诱发地壳物质重熔形成花岗质岩浆,岩浆侵位形成跃进山南二长花岗岩体;至早泥盆世(410Ma),俯冲结束发生弧-陆碰撞造山导致地壳增厚,引发下地壳发生部分熔融产生的花岗质岩浆侵位形成陶勒努图洪岩体;两岩体是在早、晚古生代交接时段同一俯冲-碰撞构造背景下不同部位、不同亚构造环境下的产物。  相似文献   

Petrology and geochemistry of mafic and ultramafic cumulate rocks from the eastern part of the Sabzevar ophiolite (NE Iran): Implications for their petrogenesis and tectonic setting     

《地学前缘(英文版)》2020,11(6):2347-2364

The Late Cretaceous Sabzevar ophiolite represents one of the largest and most complete fragments of Tethyan oceanic lithosphere in the NE Iran. It is mainly composed of serpentinized mantle peridotites slices; nonetheless, minor tectonic slices of all crustal sequence constituents are observed in this ophiolite. The crustal sequence contains a well-developed ultramafic and mafic cumulates section, comprising plagioclase-bearing wehrlite, olivine clinopyroxenite, olivine gabbronorite, gabbronorite, amphibole gabbronorite and quartz gabbronorite with adcumulate, mesocumulate, heteradcumulate and orthocumulate textures. The crystallization order for these rocks is olivine ​± ​chromian spinel → clinopyroxene → plagioclase → orthopyroxene → amphibole. The presence of primary magmatic amphiboles in the cumulate rocks shows that the parent magma evolved under hydrous conditions. Geochemically, the studied rock units are characterized by low TiO₂ (0.18–0.57 ​wt.%), P₂O₅ (<0.05 ​wt.%), K₂O (0.01–0.51 ​wt.%) and total alkali contents (0.12–3.04 ​wt.%). They indicate fractionated trends in the chondrite-normalized rare earth element (REE) plots and multi-element diagrams (spider diagrams). The general trend of the spider diagrams exhibit slight enrichment in large ion lithophile elements (LILEs) relative to high field strength elements (HFSEs) and positive anomalies in Sr, Pb and Eu and negative anomalies in Zr and Nb relative to the adjacent elements. The REE plots of these rocks display increasing trend from La to Sm, positive Eu anomaly (Eu/Eu1 ​= ​1.06–1.54) and an almost flat pattern from medium REE (MREE) to heavy REE (HREE) region [(Gd/Yb)_N ​= ​1–1.17]. Moreover, clinopyroxenes from the cumulate rocks have low REE contents and show marked depletion in light REE (LREE) compared to MREE and HREE [(La/Sm)_N ​= ​0.10–0.27 and (La/Yb)_N ​= ​0.08–0.22]. The composition of calculated melts in equilibrium with the clinopyroxenes from less evolved cumulate samples are closely similar to island arc tholeiitic (IAT) magmas. Modal mineralogy, geochemical features and REE modeling indicate that Sabzevar cumulate rocks were formed by crystal accumulation from a hydrous depleted basaltic melt with IAT affinity. This melt has been produced by moderate to high degree (~15%) of partial melting a depleted mantle source, which partially underwent metasomatic enrichment from subducted slab components in an intra-oceanic arc setting.  相似文献