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1.
《Chemie der Erde / Geochemistry》2017,77(4):633-636
Salts and brines have very low rare earth element (REE, La-Lu) concentrations. Thus, there is less knowledge of possible transfer of REE patterns during salt dissolution in water-rock interaction. REE levels in both media are close to or rather below limit of detection of commonly used methods. By dissolving salt samples in water followed by REE pre-concentration, REE contents of about 6.2 to 322 ng g−1 were measured for four samples from the Merkers salt mine, Germany. These salts previously were identified to consist mainly of carnallite, halite and/or sylvite. Assuming congruent dissolution, REE patterns of brines and salts differ. Thus, a more complex interaction with (secondary) phases and complexation of REE should be taken into account to explain REE patterns in brines. 相似文献
2.
讨论了~936)Cl的成因、~(36)Cl断代法的原理及测试方法。自1987年以来,应用该方法测得柴达木盆地尕斯库勒湖和大浪滩湖石盐的沉积年龄,并与~(14)C,~(230)Th和古地磁测年法所测得的年龄数据进行对比,结果均在误差(1δ)范围内相吻合,表明石盐的~(36)Cl断代法是可行的,获得的年龄数据是可靠的。 相似文献
3.
Differences in fluids origin, creation of overpressure and migration are compared for end member Neogene fold and thrust environments: the deepwater region offshore Brunei (shale detachment), and the onshore, arid Central Basin of Iran (salt detachment). Variations in overpressure mechanism arise from a) the availability of water trapped in pore-space during early burial (deepwater marine environment vs arid, continental environment), and b) the depth/temperature at which mechanical compaction becomes a secondary effect and chemical processes start to dominate overpressure development. Chemical reactions associated with smectite rich mud rocks in Iran occur shallow (∼1900 m, smectite to illite transformation) causing load-transfer related (moderate) overpressures, whereas mechanical compaction and inflationary overpressures dominate smectite poor mud rocks offshore Brunei. The basal detachment in deepwater Brunei generally lies below temperatures of about 150 °C, where chemical processes and metagenesis are inferred to drive overpressure development. Overall the deepwater Brunei system is very water rich, and multiple opportunities for overpressure generation and fluid leakage have occurred throughout the growth of the anticlines. The result is a wide variety of fluid migration pathways and structures from deep to shallow levels (particularly mud dykes, sills, laccoliths, volcanoes and pipes, fluid escape pipes, crestal normal faults, thrust faults) and widespread inflationary-type overpressure. In the Central Basin the near surface environment is water limited. Mechanical and chemical compaction led to moderate overpressure development above the Upper Red Formation evaporites. Only below thick Early Miocene evaporites have near lithostatic overpressures developed in carbonates and marls affected by a wide range of overpressure mechanisms. Fluid leakage episodes across the evaporites have either been very few or absent in most areas. Locations where leakage can episodically occur (e.g. detaching thrusts, deep normal faults, salt welds) are sparse. However, in both Iran and Brunei crestal normal faults play an important role in the transmission of fluids in the upper regions of folds. 相似文献
4.
The so called bituminous salts occurring in the Kłodawa dome, located in Central Poland, differ from the surrounding salts by their colour change from light to dark brown. This colour is associated with an extremely large amount of hydrocarbon, mainly located in the inclusions. The presence of numerous fluid inclusions has been documented in previous petrologic studies, distinguishing seven main types of fluid inclusion assemblages (FIA) in terms of size, shape as well as the ratio of filling material. However, four types of inclusions were selected in the current investigations according to their unusual optical behaviour. Raman micro-spectroscopy a modern, non-destructive method was used for investigating a single inclusion being a part of FIA. Presented in this paper Raman spectra revealed a unique pattern of bands characterizing the content of the inclusions. The hydrocarbons show a very complex character reflected in the appearance of a strong fluorescence background. A well-marked heterogeneity characterized the inclusions, by diversity in the intensity of the background and in the pattern of the bands characterizing the presence of certain components. One can distinguish the presence of carbonaceous matter showing the different degrees of order. The depth profile and the analysis of the various points of the inclusions indicate that the carbonaceous matter is not evenly distributed in the inclusions but forms a thin, disorganized film on their walls. This film was also found in sites where the inclusions are filled with brine. The certain characteristics associated with the presence of the incipient phase transformation of the organic matter, or slightly transformed organic matter and the lack of light hydrocarbons as well as a number of petrologic features of inclusions indicate that these salt rocks have been subdivided into thermal transformations, accompanied by the recrystallization of the halite and the escape of the more volatile compounds such as methane, ethane, etc. 相似文献
5.
Sergey Zubtsov Franois Renard Jean-Pierre Gratier Robert Guiguet Dag K Dysthe Vladimir Traskine 《Tectonophysics》2004,385(1-4):45-57
Experimental observations are reported of weakening of sediment-like aggregates by addition of hard particles. Sieved mixtures of calcite and halite grains are experimentally compacted in drained pressure cells in the presence of a saturated aqueous solution. The individual halite grains deform easily by pressure solution creep whereas calcite grains act as hard objects and resist compaction. The fastest rate of compaction of the mixed aggregate is not obtained for a 100% halite aggregate but for a content of halite grains between 45% and 75%. We propose that this unusual compaction behavior reflects the competition between two mechanisms at the grain scale: intergranular pressure solution at grain contacts and grain boundary healing between halite grains that prevent further compaction. 相似文献
6.
Halite clogging in a deep geothermal well – Geochemical and isotopic characterisation of salt origin
The sandstone formation of the Middle Buntsandstein (Lower Triassic) in the geothermal well Groß Buchholz Gt1, Hanover, Northern Germany, was hydraulically stimulated to generate a heat exchanger surface, using 20000 m3 of fresh water. After six months of enclosure the recovered water was oversaturated with respect to halite at surface conditions. Due to cooling induced precipitation a salt plug formed between 655 and 1350 m depth in the tubing. While the Na/Br and the Cl/Br ratio of the recovered water reflect the signature of a relic evaporative solution the recovered water contains tritium, indicating a significant proportion of fresh water. Leaching experiments of the reservoir rocks point towards presence of traces of soluble salt minerals in the formation. Therefore we assume that the salinity cannot be attributed solely to halite dissolution nor to the production of a pure formation brine. The recovered water is a result of a combination of both salt dissolution by injected fresh water and of mixing with a formation brine which has undergone water–rock interaction. The calculated fresh water proportion in the recovered water is around 40%. The presence of salt mineral traces in pores of a target formation is a potential threat for the operation of geothermal wells, as cooling-induced salt scaling jeopardizes their performance. 相似文献
7.
Aro V. Arakel 《Geodinamica Acta》2013,26(4):169-184
AbstractContemporary layered halite in the Hutt Lagoon, Western Australia, forms distinct precipitational and clastic fades, which are ascribed to seasonal ponding and playa development in the lagoon respectively. Field and laboratory documentation of the halite types and monitoring of surface water chemistry for several annual hydrologic cycles indicate that following evaporative concentration of ponded seawater halite layers, characterized by zoned and clear halite crystal varieties, are developed. During early stages of annual playa development, vadose solution and precipitation appear to be most active within and above the capillary fringe zone, causing diagenetic modification of the halite textures, fabrics and structures. Ultimately, clastic halite facies are produced by wind reworking of the earlier deposits, in response to progressive evaporative drawdown of the brine level in the main depression area of the lagoon.The co-existence of the halite precipitates and clastites is related to a dynamic equilibrium in the water budget of the Hutt Lagoon. This equilibrium is best exemplified by limitation of brine level fluctuations to a narrow repetitive zone. Identification of similar early diagenetic features, such as vadose solution, precipitation, overgrowth, replacement and mechanical reworking of surface halite sediments, in ancient evaporite deposits may aid in a better understanding of the role of brine level fluctuation on genesis and diagenesis of subaqueous/subaerial halite. 相似文献
8.
Differences in fluids origin, creation of overpressure and migration are compared for end member Neogene fold and thrust environments: the deepwater region offshore Brunei (shale detachment), and the onshore, arid Central Basin of Iran (salt detachment). Variations in overpressure mechanism arise from a) the availability of water trapped in pore-space during early burial (deepwater marine environment vs arid, continental environment), and b) the depth/temperature at which mechanical compaction becomes a secondary effect and chemical processes start to dominate overpressure development. Chemical reactions associated with smectite rich mud rocks in Iran occur shallow (∼1900 m, smectite to illite transformation) causing load-transfer related (moderate) overpressures, whereas mechanical compaction and inflationary overpressures dominate smectite poor mud rocks offshore Brunei. The basal detachment in deepwater Brunei generally lies below temperatures of about 150 °C, where chemical processes and metagenesis are inferred to drive overpressure development. Overall the deepwater Brunei system is very water rich, and multiple opportunities for overpressure generation and fluid leakage have occurred throughout the growth of the anticlines. The result is a wide variety of fluid migration pathways and structures from deep to shallow levels (particularly mud dykes, sills, laccoliths, volcanoes and pipes, fluid escape pipes, crestal normal faults, thrust faults) and widespread inflationary-type overpressure. In the Central Basin the near surface environment is water limited. Mechanical and chemical compaction led to moderate overpressure development above the Upper Red Formation evaporites. Only below thick Early Miocene evaporites have near lithostatic overpressures developed in carbonates and marls affected by a wide range of overpressure mechanisms. Fluid leakage episodes across the evaporites have either been very few or absent in most areas. Locations where leakage can episodically occur (e.g. detaching thrusts, deep normal faults, salt welds) are sparse. However, in both Iran and Brunei crestal normal faults play an important role in the transmission of fluids in the upper regions of folds. 相似文献
9.
10.
This study provides evidence for the existence of halite and sylvite solid inclusions in igneous quartz and feldspars, the first to be reported in intrusive rocks, and to partially constrain the physicochemical environment that lets halides crystallize under magmatic conditions.Halite and sylvite solid inclusions were found included in quartz and feldspars from a micrographic–granophyric assemblage in a miarolitic aplite and, rarer, in alkali-feldspar from a miarolitic monzogranite. Monzogranite and aplite represent I-type, K-enriched postcollisional rocks of the Late Cambrian–Early Ordovician Sierra Norte–Ambargasta batholith in the Eastern Sierras Pampeanas. Both granitoids fall among the most evolved felsic rocks of the batholith, with aplite approaching haplogranitic compositions. Halite is far more common than sylvite and the presence and distribution of one or both halides are erratic within the felsic intrusive bodies. Halides occur as small skeletal grains, commonly in cross-shaped aggregates of less than 50 μm. No K or Na was found at the detection limits of EDS in either halite or sylvite respectively. Textural relationships suggest that the alkali-chlorides separated from the melt near the minima along the quartz–feldspar cotectics of PH2O > 160 < 200 MPa in a silica-, and potassium-rich magmatic system at approximately 750–700 °C, prior to the H2O-vapor saturated miarole-forming stage.Computed ratios for the magmatic volatile phase (MVP) coexisting with melt at the early stage of aplite crystallization are: NaCl/HCl = 0.11–0.97 and KCl/HCl = 0.24–1.62, being the highest range of values (0.79–0.97 and 1.45–1.62, respectively) found in those alkali-chloride-bearing samples. Maximum HCl/ΣCl(MVP) (0.28 to 0.31) indicates higher total Cl concentration in the MVP of alkali-chloride-bearing aplites, which is much higher in the halite-free aplite samples (HCl/ΣCl(MVP) = 0.59 to 0.74). One miarolitic monzogranite sample, where halite solid inclusions are present, also yielded the highest ratios for NaCl/HCl(MVP) (0.91) and KCl/HCl(MVP) (1.46), and the HCl/ΣCl(MVP) is 0.30. A high HCl concentration in the fluid phase is suggested by the log f(HF)/f(H2O) = − 4.75 to − 4.95, log f(HCl)/f(H2O) = − 3.73 to − 3.86, and log f(HF)/f(HCl) = − 0.88 to − 1.22, computed at 750 °C after biotite composition. The Cl concentrations at 800 °C, computed with a Dv/lCl = 0.84 + 26.6P (P at 200 MPa), yielded values within the range of 70 to 700 ppm Cl in the melt and 4000 to 40 000 ppm Cl in the coexisting MVP. The preferential partitioning of Cl in the vapor phase is controlled by the Dv/lCl; however, the low concentration of Cl in the melt suggests that high concentrations of Cl are not necessary to saturate the melt in NaCl or KCl.Cl-saturation of the melt and coexisting MVP might have been produced by a drop in Cl solubility due to the near-haplogranitic composition of the granitoids after extreme fractionation, probably enhanced by fluctuating reductions of the emplacement pressure in the brittle monzogranite host. Liquid immiscibility, based in the differential viscosity and density among alkali-chloride saturated hydrosaline melt, aluminosilicate felsic melt, and H2O-rich volatiles is likely to have crystallized halite and sylvite from exsolved hydrosaline melt. High degrees of undercooling might have been important at the time of alkali-chloride exsolution. The effectiveness of alkali-chloride separation from the melt at magmatic temperatures is in line with the interpretation of “halite subtraction” as a necessary process to understand the origin of the “halite trend” in highly saline fluid inclusions from porphyry copper and other hydrothermal mineralizations, despite the absence of the latter in the Cerro Baritina aplites, where this process preceded the exsolution of halite-undersaturated fluids.Pervasive alteration of the monzogranite country rock as alkali-metasomatic mineral assemblages, the mineral chemistry of some species, and the association of weak molybdenite mineralization are compatible with the activity of alkaline hypersaline fluids, most likely exsolved during the earliest stages of aplite consolidation. 相似文献