A Multi‐Element Ion‐Pair Extraction for Trace Metals Determination in Environmental Samples     

Şerife Saçmacı  Şenol Kartal 《洁净——土壤、空气、水》2011,39(6):577-583

A multi‐element ion‐pair extraction method was described for the preconcentration of Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) ions in environmental samples prior to their determinations by flame atomic absorption spectrometry (FAAS). As an ion‐pair ligand 2‐(4‐methoxybenzoyl)‐N′‐benzylidene‐3‐(4‐methoxyphenyl)‐3‐oxo‐N‐phenyl‐propono hydrazide (MBMP) was used. Some analytical parameters such as pH of sample solution, amount of MBMP, shaking time, sample volume, and type of counter ion were investigated to establish optimum experimental conditions. No interferences due to major components and some metal ions of the samples were observed. The detection limits of the proposed method were found in the range of 0.33–0.9 µg L^?1 for the analyte ions. Recoveries were found to be higher than 95% and the relative standard deviation (RSD) was less than 4%. The accuracy of the procedure was estimated by analyzing the two certified reference materials, LGC6019 river water and RTC‐CRM044 soil. The developed method was applied to several matrices such as water, hair, and food samples.  相似文献   

改进的无网格法及其在冻土区桩基温度场中的应用     

高志华  赵昭  曾辉辉  田威 《冰川冻土》2018,40(5):974-978

采用带权正交基函数对传统的无网格法中的基函数进行了改进,避免了计算过程中可能出现的矩阵不可逆情况,而且编程容易实现且计算效率高。并将其应用到冻土区桩基包括了热传导和相变潜热的温度场中,同时考虑了混凝土水化热释放对桩周冻土的影响,将计算结果和有限元计算结果及现场实测数据进行了比较分析,从趋势和最大数值看都反映了实测曲线的趋势,又把不同深度处桩侧和不同桩径处温度随时间的变化规律计算结果和有限元计算结果做了对比,都验证了该方法的可行性和优越性。  相似文献   

扩散-离子色谱法测定植物样中的氟          下载免费PDF全文

曹磊  赵斌  周泳德 《江苏地质》2012,36(2):216-218

采用扩散法提取植物样中的氟,用离子色谱法检测氟的含量。经试验,样品加标回收率在94.7%～104.7%之间,样品质量分数为7.10μg/g时,RSD为1.41%。此法操作简单,准确度高,精密度好,是一种测量植物样中氟含量的有效方法。  相似文献   

Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation     

Pasquale Crea  Concetta De Stefano  Demetrio Milea  Silvio Sammartano   《Marine Chemistry》2008,112(3-4):142-148

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).  相似文献   

西藏改则6.9级地震前的电离层电磁扰动   总被引：5，自引：1，他引：4  

张学民  刘静  钱家栋  申旭辉  蔡晋安  欧阳新艳  赵庶凡 《地震》2008,28(3)

2008年1月9日西藏改则县发生6.9级地震,震前2天法国DEMETER卫星飞过震中上空时记录到离子温度(Ti)和超低频电场异常。文中通过震前10天内多条轨道的数据对比和分析处理,对空间异常的识别和判定给出了两种有效的方法,同时也积累了空间地震电磁前兆震例和异常信号判别的经验。  相似文献   

拉果错盐湖卤水蒸发过程中Li⁺富集行为的分子动力学模拟          下载免费PDF全文

刘鑫  马艳芳  张志宏  付振海 《盐湖研究》2022,30(4):61-71

采用分子动力学模拟,研究了西藏拉果错盐湖卤水中阴、阳离子以及水分子间的相互作用行为。以盐湖卤水等温蒸发过程中粒子浓度变化的四个阶段为研究对象,分别计算了不同体系的扩散系数、配位数、均方位移和径向分布函数。计算结果表明,液相浓度越低时,H₂O分子对各离子之间的相互作用有抑制作用,液相中离子浓度越高时,SO₄2-易与CO₃2-竞争Li⁺形成离子对,从而影响盐湖卤水中Li⁺的富集。本文研究结果对盐湖卤水中Li⁺的迁移行为作出了机理解释,为盐湖卤水提锂的发展奠定了理论基础。  相似文献   

Effect of parallel electric field on electrostatic ion-cyclotron instability in anisotropic plasma in the presence of ion beam and general distribution function—Particle aspect analysis     

Ruchi Mishra 《Planetary and Space Science》2006,54(2):188-199

Dispersion relation, resonant energy transferred, growth rate and marginal instability criteria for the electrostatic ion-cyclotron wave with general loss-cone distribution in low-β anisotropic, homogeneous plasma in the auroral acceleration region are discussed by investigating the trajectories of the charged particles. Effects of the parallel electric field, ion beam velocity, steepness of the loss-cone distribution and temperature anisotropy on resonant energy transferred and growth rate of the instability are discussed. It is found that the effect of the parallel electric field is to stabilize the wave and enhance the transverse acceleration of ions whereas the effect of steepness of loss-cone, ion beam velocity and the temperature anisotropy is to enhance the growth rate and decrease the transverse acceleration of ions. The steepness of the loss-cone also introduces a peak in the growth rate which shifts towards the lower side of the perpendicular wave number with the increasing steepness of the loss-cone.  相似文献   

Li₂SO₄溶液中离子间的缔合相互作用:基于密度泛函理论和分子动力学模拟的研究   总被引：1，自引：1，他引：0  

胡俊  夏斐斐  杨凤丽  郑纯智  房春晖  曾德文  易海波 《盐湖研究》2018,26(1):39-47

基于密度泛函理论,使用B3LYP/aVDZ方法对[Li_2SO_4(H_2O)_n]~0(n=0~10、18)水合团簇的结构和性质进行了系统地研究,并结合Car-Parrinello分子动力学(CPMD)模拟了不同浓度的Li_2SO_4溶液结构,目的在于理解在Li_2SO_4溶液中离子间缔合相互作用及可能存在的物种。研究发现,对于[Li_2SO_4(H_2O)_n]~0(n=0~10、18)水合团簇,双配位单齿螯合接触离子对结构比双配位双齿螯合接触离子对结构更稳定,溶剂共享离子对结构最不稳定。同时,CPMD模拟结果表明,在3.09和3.17 mol/kg的Li_2SO_4溶液中,双配位单齿螯合接触离子对结构仍然是主要物种。以上结果表明在饱和的Li_2SO_4溶液(3.16 mol/kg)中,Li~+和SO_4~(2-)离子间的相互缔合作用主要以双配位单齿螯合接触离子对结构的物种存在,而具有双配位双齿螯合离子对结构的物种占少数,溶剂共享离子对结构几乎不存在。  相似文献   

三氟乙酸锂-15-冠醚-5体系电迁移法分离锂同位素          下载免费PDF全文

黄超驰  孙进贺  张茜  张鹏瑞  汪词明  薛子轩  景燕  贾永忠 《盐湖研究》2021,29(3):83-89

锂同位素(~6Li和~7Li)在核工业中有着重要作用。锂汞齐法是目前唯一实现锂同位素工业化生产的方法,然而由于汞的使用,该方法具有较大的环境风险。开发绿色高效的锂同位素分离方法对国家能源安全具有重要意义。在本论文中,制备了溶解锂盐的冠醚溶液,并以其作为阳极液,施加电场驱动锂离子向阴极液迁移;与溶有15-冠醚-5的锂盐水溶液作为阳极液相比,研究发现在阳极液体系中引入水分子可以促进锂同位素的分离。同时还考察了不同隔膜对锂同位素分离的影响,发现使用强疏水性隔膜时,短时间内有较好的分离效应。  相似文献   

新型抗水氯氧镁水泥防渗渠在自然环境的水化产物、相转变规律及其对强度的影响          下载免费PDF全文

石天阳  余红发  麻海燕  李颖 《盐湖研究》2021,29(3):38-46, 55

氯氧镁水泥(Magnesium oxychloride cement, MOC)具有快凝、早强、高强、防火和不腐蚀玻璃纤维等优点,非常适合于制作玻璃纤维增强薄壁制品,在农业灌溉工程中具有良好的应用前景。采用XRD和TOPAS分析了新型抗水氯氧镁水泥制成内蒙古防渗渠的物相组成,探讨了氯氧镁水泥制品在自然环境的水化产物与相转变规律、以及相组成对强度的影响。结果表明,在水分缺少的条件下,氯氧镁水泥的水化产物主要为5Mg(OH)_2·MgCl_2·8H_2O(5·1·8)和Mg(OH)_2;在水分充足的条件下,水化产物主要为Mg(OH)_2和5·1·8,碳化产物为碳化氯氧化镁Mg(OH)_2·MgCl_2·2MgCO_3·6H_2O(1·1·2·6)和水菱镁矿4MgCO_3·Mg(OH)_2·4H_2O(4·1·4)。水化产物对强度有促进作用,而碳化产物会降低强度。通过10年的工程环境考验,证明新型氯氧镁水泥制品在环境中能够保持主要强度相5·1·8的稳定性,具有良好的长期力学性能。  相似文献