Application of Lithium Isotope Geochemistry to the Study of the Continental Geothermal System     

Xiaocan Yu  Chenglin Liu  Chunlian Wang 《地球科学进展》2020,35(3):246-258

The lithium-rich brine in salt lakes is the main raw material of the world’s lithium products, while the continental geothermal fluids with a high salinity often contain a high concentration of lithium. Continental geothermal system is the focus in the study of geothermal formation mechanism. However, less attention is paid to the system due to the complexity of lithology, and the application of lithium isotopes in this field has not been systematically recognized. The newest application and progress of lithium isotope geochemistry in continental geothermal research in recent years were discussed, the problems in this field were put forward, and future research methods and directions were expected. The study of continental geothermal fluids should attach great importance to the application of Li-B-Sr-U multi-isotopic method, and should also be combined with water-rock reaction experiments under different temperature conditions. Moreover, in the future, the research on continental geothermal system should pay more attention to the various sediment/rock lithium isotopic compositions and their spatio-temporal distribution characteristics in the regional or geothermal field’s scales, mineralogy of reservoir rock, and behaviors of lithium isotopes related to the formation of secondary minerals in the process of water-rock interaction, in order to reveal the complex process of fluid evolution in the geothermal system and provide scientific reference for the exploration, exploitation and utilization of lithium resources in the system.  相似文献   

A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

HY-2B卫星散射计海面风场产品质量分析 *     

陈克海  解学通  张金兰  邹巨洪  张毅 《热带海洋学报》2020,39(6):30-40

星载微波散射计是获取全球海面风场信息的主要手段, HY-2B卫星散射计的成功发射为全球海面风场数据获取的持续性提供了重要保障。本文利用欧洲中期天气预报中心(European Center for Medium-Range Weather Forecasts, ECMWF)再分析风场数据、热带大气海洋观测计划(Tropical Atmosphere Ocean Array, TAO)和美国国家数据浮标中心(National Data Buoy Center, NDBC)浮标获取的海面风矢量实测数据, 对HY-2B散射计海面风场数据产品的质量进行统计分析。分析表明, HY-2B风场与ECMWF再分析风场对比, 在4~24m·s^-1风速区间内, 风速和风向均方根误差(root mean square error, RMSE)分别为1.58m·s^-1和15.34°; 与位于开阔海域的TAO浮标数据对比, 风速、风向RMSE分别为1.03m·s^-1和14.98°, 可见HY-2B风场能较好地满足业务化应用的精度要求(风速优于2m·s^-1, 风向优于20°)。与主要位于近海海域的NDBC浮标对比, HY-2B风场的风速、风向RMSE分别为1.60m·s^-1和19.14°, 说明HY-2B散射计同时具备了对近海海域风场的良好观测能力。本文还发现HY-2B风场质量会随风速、地面交轨位置等变化, 为用户更好地使用HY-2B风场产品提供参考。  相似文献   

钾稳定同位素研究综述     

王昆  李伟强  李石磊 《地学前缘》2020,27(3):104-122

钾稳定同位素是重要的非传统稳定同位素体系,也是近年来迅速发展的热门研究课题。对钾同位素研究历史和现状进行综述,具体包括以下内容:(1)总结了钾元素的地球化学和宇宙化学性质,包括钾在主要地质储库(地幔、地壳、海洋)中的丰度及其分配,钾在岩浆演化中的不相容大离子亲石性,常见含钾火成岩/沉积岩矿物以及钾在表生过程中的循环,也包括主要行星物质(球粒陨石、非球粒陨石、火星和灶神星陨石以及月球样品)中钾的含量、赋存状态、主要矿物,钾在太阳星云冷凝、行星积聚以及岩浆海过程中的中等挥发性质;(2)介绍了钾同位素的研究历史,从1922年Dempster利用最早的质谱仪测量钾同位素在自然界的丰度,到Taylor和Urey在1938发表的经典的钾同位素分馏实验,再到Humayun和Clayton在1995年发表的钾同位素领域的经典研究,最后到近几年的进展;(3)介绍了对钾的前处理(离子交换柱法)以及钾同位素的主要测量方法,包括早期热电离质谱仪法(TIMS),二次离子质谱仪法(SIMS)和近十几年以来高速发展的多接收电感耦合等离子体质谱仪法(MC-ICP-MS)及其不同的技术路线;(4)介绍了高精度钾同位素比值在低温地球化学和生物地球化学中的应用,包括钾同位素在地表的风化过程中、海水洋壳的反向风化作用中的分馏及其在示踪全球钾元素循环和洋壳俯冲等过程中的应用;(5)介绍了高精度钾同位素比值在高温地球化学中的应用,包括钾同位素在岩浆分异和矿物结晶过程中的分馏;(6)介绍了高精度钾同位素比值在宇宙化学中的应用,包括在太阳星云冷凝、行星凝聚、月球形成大碰撞、岩浆海、火山喷发去气过程中的分馏作用。  相似文献   

Box-Behnken设计-效应面法优选百合防褐变加工工艺研究          下载免费PDF全文

万丹  沈冰冰  陈林 《应用海洋学学报》2020,36(8):167

目的：优选百合防褐变的加工工艺。方法：在单因素试验基础上,以王百合苷B含量、褐变度、浸出物为评价指标,采用Box-Behnken设计效应面法考察烫片时间、干燥温度、干燥时间对其质量的影响,优选百合的防褐变加工工艺参数。结果:百合防褐变加工工艺为烫片时间3.5 min,干燥温度90℃,干燥时间3.0 h。结论：优选的百合防褐变加工工艺合理可行,可适用于工业生产。  相似文献   

融合时间序列环境卫星数据与物候特征的水稻种植区提取   总被引：3，自引：0，他引：3  

柳文杰  曾永年  张猛 《遥感学报》2018,22(3):381-391

获取高精度的区域水稻种植面积对于农业规划、配置与决策具有重要意义。区域尺度的水稻面积获取依赖于高时空分辨率影像,但受卫星回访周期和气候影响,难以获取足够时间序列的高时空分辨率影像,从而影响水稻种植面积遥感提取的精度。为此,提出适应于中国南方多雨云天气地区,基于国产环境卫星(HJ-1A/1B)与MODIS融合数据的水稻种植面积提取的新方法。以洞庭湖区为实验区,利用STARFM模型融合环境卫星NDVI数据与MODIS13Q1数据,获取时间序列的环境卫星NDVI数据,利用水稻关键期的NDVI数据结合物候特征参数对水稻种植区域进行提取。结果表明,该方法能有效提取区域水稻种植的面积,水稻种植面积提取的总体精度与Kappa系数分别达到91.71%与0.9024,分类结果明显优于仅采用多光谱影像或NDVI数据。该研究为中国南方多雨云天气地区水稻种植面积提取提供了有效的方法。  相似文献   

Spatiotemporal Variations of Microwave Land Surface Emissivity (MLSE) over China Derived from Four-Year Recalibrated Fengyun 3B MWRI Data     

Rui LI  Jiheng HU  Shengli WU  Peng ZHANG  Husi LETU  Yu WANG  Xuewen WANG  Yuyun FU  Renjun ZHOU  Ling SUN 《大气科学进展》2022,39(9):1536-1560

Microwave Land Surface Emissivity (MLSE) over China under both clear and cloudy sky conditions was retrieved using measurements of recalibrated microwave brightness temperatures (Tbs) from Fengyun-3B Microwave Radiation Imager (FY-3B MWRI), combined with cloud properties derived from Himawari-8 Advanced Himawari Imager (AHI) observations. The contributions from cloud particles and atmospheric gases to the upwelling Tbs at the top of atmosphere were calculated and removed in radiative transfer. The MLSEs at horizontal polarizations at 10.65, 18.7, and 36.5 GHz during 7 July 2015 to 30 June 2019 over China showed high values in the southeast vegetated area and low values in the northwest barren, or sparsely vegetated, area. The maximum values were found in the belt area of the Qinling-Taihang Mountains and the eastern edge of the Qinghai-Tibet Plateau, which is highly consistent with MLSEs derived from AMSR-E. It demonstrates that the measurements of FY-3B MWRI Tbs, including its calibration and validation, are reliable, and the retrieval algorithm developed in this study works well. Seasonal variations of MLSE in China are mainly driven by the combined effects of vegetation, rainfall, and snow cover. In tropical and southern forest regions, the seasonal variation of MLSE is small due to the enhancement from vegetation and the suppression from rainfall. In the boreal area, snow causes a significant decrease of MLSE at 36.5 GHz in winter. Meanwhile, the MLSE at lower frequencies experiences less suppression. In the desert region in Xinjiang, increases of MLSEs at all frequencies are observed with increasing snow cover.  相似文献   

AS350B3型直升机在中高山航空物探测量中的优势     

李健  郭亮  肖刚毅  刘志强  徐明  金久强  王志博  邓茂盛  李冰 《物探与化探》2018,(1):192-198

中高山地区作业的航空地球物理勘探飞行器需要有高原适航性。通过对比空中国王350ER在起降条件、最大升限、最大续航能力及高原机动能力等特点,提出了在中高山地区的低高度、大比例尺的航空地球物理勘探飞行器的选型原则及飞行方法。通过甘肃某测区的实际测量飞行验证了该原则和方法的可行性。分析结果显示,AS350B3型直升机在中高山地区作业时表现出的实际飞行性能满足在该类型区域低高度、大比例尺的航空地球物理勘探的要求。  相似文献   

基于自适应时序剖分与KNN的短时交通流量预测     

祁朵  毛政元 《地球信息科学学报》2022,24(2):339-351

在智能交通系统中,准确和高效的短时交通流量预测是交通诱导、管理和控制的前提。由于交通流量动态变化中表现出的时变性和非平稳性特征,其预测难度较大,是交通领域中亟待解决的难题。为提高短时交通流量的预测精度,本文设计与实现了基于自适应时序剖分与KNN（A-TS-KNN）的短时交通流量预测算法。① 基于动态时间规整（Dynamic Time Warping,DTW）动态剖分单日时序为不同的交通模式;② 在不同交通模式,采用互信息法求解每个预测时刻时间延迟的最大阈值,构造不同时间延迟的状态向量,生成交通流量历史数据库;③ 采用十次十折交叉验证的方法求解每个时刻不同时间延迟与不同K值的正交误差结果分布,提取误差最小的正交结果,得到自适应时间延迟与K值的参数组合;④ 采用K个最相似的近邻的距离倒数加权值作为预测结果。对比K近邻（K-nearest neighbors, KNN）、支持向量回归（Support vector regression,SVR）、长短期记忆神经网络（Long-short term memory neural network,LSTM）以及门控递归单元神经网络（Gate recurrent unit neural network,GRU）共4种主流预测模型,A-TS-KNN算法预测精度显著提升;将A-TS-KNN算法用于福州市城市路网中其他交叉路口的短时交通流量预测,结果表现出良好的泛化能力。  相似文献   

Record Arctic Ozone Loss in Spring 2020 is Likely Caused by North Pacific Warm Sea Surface Temperature Anomalies     

Yan XIA  Yongyun HU  Jiankai ZHANG  Fei XIE  Wenshou TIAN 《大气科学进展》2021,38(10):1723-1736

Record ozone loss was observed in the Arctic stratosphere in spring 2020. This study aims to determine what caused the extreme Arctic ozone loss. Observations and simulation results are examined in order to show that the extreme Arctic ozone loss was likely caused by record-high sea surface temperatures(SSTs) in the North Pacific. It is found that the record Arctic ozone loss was associated with the extremely cold and persistent stratospheric polar vortex over February–April, and the extremely cold vortex was a result of anomalously weak planetary wave activity. Further analysis reveals that the weak wave activity can be traced to anomalously warm SSTs in the North Pacific. Both observations and simulations show that warm SST anomalies in the North Pacific could have caused the weakening of wavenumber-1 wave activity, colder Arctic vortex, and lower Arctic ozone. These results suggest that for the present-day level of ozone-depleting substances, severe Arctic ozone loss could form again, as long as certain dynamic conditions are satisfied.  相似文献