全文获取类型
收费全文 | 66篇 |
免费 | 101篇 |
国内免费 | 25篇 |
专业分类
测绘学 | 4篇 |
大气科学 | 12篇 |
地球物理 | 8篇 |
地质学 | 50篇 |
海洋学 | 2篇 |
天文学 | 3篇 |
综合类 | 3篇 |
自然地理 | 110篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 11篇 |
2021年 | 7篇 |
2020年 | 7篇 |
2019年 | 13篇 |
2018年 | 7篇 |
2017年 | 2篇 |
2016年 | 4篇 |
2015年 | 3篇 |
2014年 | 12篇 |
2013年 | 7篇 |
2012年 | 7篇 |
2011年 | 5篇 |
2010年 | 7篇 |
2009年 | 5篇 |
2008年 | 9篇 |
2007年 | 3篇 |
2006年 | 10篇 |
2005年 | 10篇 |
2004年 | 4篇 |
2003年 | 5篇 |
2002年 | 4篇 |
2001年 | 7篇 |
2000年 | 8篇 |
1999年 | 7篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 1篇 |
1993年 | 9篇 |
1989年 | 2篇 |
排序方式: 共有192条查询结果,搜索用时 423 毫秒
1.
采用微型氢化物发生装置-冷原子吸收分光光度法测定了焊锡料及纽扣电池中的汞。在酸性介质中,用硼氢化钾将汞离子还原为汞原子,用载气将汞蒸气导入石英管,原子吸收分光光度计在波长253.7 nm处进行测定。选择了实验条件,对共存离子的干扰等进行了考察。方法的检出限为0.34 ng/mL,11次测定的相对标准偏差(RSD)小于6%,加标回收率为94.4%~104.7%。 相似文献
2.
Li-Sr-Nd isotope signatures of the plume and cratonic lithospheric mantle beneath the margin of the rifted Tanzanian craton (Labait) 总被引:3,自引:2,他引:1
Sonja Aulbach Roberta L. Rudnick William F. McDonough 《Contributions to Mineralogy and Petrology》2008,155(1):79-92
Lithium concentrations and isotopic compositions of olivine and 87Sr/86Sr and 143Nd/144Nd of coexisting clinopyroxene from peridotite xenoliths from the Quaternary Labait volcano, Tanzania, document the influence
of rift-related metasomatism on the ancient cratonic mantle. Olivines show negative correlations between Fo content and both
δ7Li and Li concentrations. Olivines in iron-rich peridotites (Fo85–87) have high Li concentrations (3.2–4.8 ppm) and heavy δ7Li (+5.2 to +6.6). In contrast, olivines in ancient, refractory peridotites have lower Li concentrations (∼2 ppm) and relatively
light δ7Li (+2.6 to +3.5). This reflects mixing between ancient, refractory cratonic lithosphere and asthenosphere-derived rift magmas.
A uniquely fertile, deformed, high-temperature garnet lherzolite, interpreted to be from the base of the lithosphere, has
a 87Sr/86Sr of 0.7029 and 143Nd/144Nd of 0.51286, similar to HIMU oceanic basalts. It provides the best estimate of the Sr–Nd isotope composition of the upwelling
mantle (i.e., plume, sensu lato) underlying this portion of the East African Rift, and is slightly less radiogenic compared
to previous estimates of the plume that were based on rift basalts. Although elevated δ7Li are not exclusive to HIMU source regions, the data collectively indicate that the plume beneath Labait has HIMU characteristics
in Sr, Nd and Li isotope composition.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
3.
D. Gournis A. Lappas M. A. Karakassides D. Többens A. Moukarika 《Physics and Chemistry of Minerals》2008,35(1):49-58
Neutron powder diffraction measurements on lithium and cesium saturated montmorillonite samples before and after heat treatment
at 300°C are studied, in order to undertake a complete refinement of crystal structure and unravel the migration mechanism
for the interlayer cations of Li or Cs. Rietveld analysis of the corresponding diffraction patterns finds that montmorillonite
crystallizes in the C2/m space group with unit cell dimensions consistent with the size of the specific interlayer cation. We show that thermal treatment
affects the two types of samples in a different way. This is with respect to their unit cell dimensions and the migration
of Li from the 2b to the 2c clay lattice site, in constrast to the Cs positioning which remains effectively unchanged. 相似文献
4.
长江流域河水和悬浮物的锂同位素地球化学研究 总被引:9,自引:1,他引:8
深入理解流域侵蚀过程中的锂同位素分馏对于运用锂同位素来示踪化学循环和气候变化是十分必要的。研究集中在长江干流和主要支流的水体和悬浮物的锂及锂同位素组成。长江流域水体的锂及锂同位素组成(δ7Li)分别为150~4 570 nmol/L和+7.6‰~+28.1‰,两者沿上游至下游的变化趋势相反。悬浮物锂同位素组成(δ7Li)变化比较稳定,分别为41~92 μg/g和-4.7‰~+0.7‰,而且总是低于相应水体的锂同位素组成。悬浮物和流体之间的锂同位素分馏系数在0.977和0.992之间,与悬浮物的量及组成存在明显相关性,反映了粘土矿物的吸附和化学风化的程度。锂含量与锂同位素组成之间良好的负相关性表明流域水体的锂来自2个端元混合:其一可能是蒸发盐岩,并伴有深部热泉水;其二可能是硅酸岩。 相似文献
5.
A. Ankilov A. Baklanov M. Colhoun K. -H. Enderle J. Gras Yu. Julanov D. Kaller A. Lindner A. A. Lushnikov R. Mavliev F. McGovern T. C. O'Connor J. Podzimek O. Preining G. P. Reischl R. Rudolf G. J. Sem W. W. Szymanski A. E. Vrtala P. E. Wagner W. Winklmayr V. Zagaynov 《Atmospheric Research》2002,62(3-4)
During an international workshop at the Institute for Experimental Physics of the University of Vienna, Austria, which was coordinated within the Committee on Nucleation and Atmospheric Aerosols (IAMAS-IUGG), 10 instruments for aerosol number concentration measurement were studied, covering a wide range of methods based on various different measuring principles. In order to investigate the detection limits of the instruments considered with respect to particle size, simultaneous number concentration measurements were performed for monodispersed aerosols with particle sizes ranging from 1.5 to 50 nm diameter and various compositions.The instruments considered show quite different response characteristics, apparently related to the different vapors used in the various counters to enlarge the particles to an optically detectable size. A strong dependence of the 50% cutoff diameter on the particle composition in correlation with the type of vapor used in the specific instrument was found. An enhanced detection efficiency for ultrafine hygroscopic sodium chloride aerosols was observed with water operated systems, an analogous trend was found for n-butanol operated systems with nonhygroscopic silver and tungsten oxide particles. 相似文献
6.
7.
本文介绍了碱金属硼酸盐的一些基本知识,主要回顾了其中Li2O—B2O3体系的研究历史,讨论了该体系结构与性质的关系并总结了Li2O-B2O3晶态及非晶态物质作为新型功能材料的研究进展。 相似文献
8.
9.
锂是银白色的、自然界最轻的金属,广泛应用于纺织、陶瓷、冶金、核能、新能源等领域,有“高能金属”、“21世纪的能源金属”之称。锂矿床按成因类型可分为内生和外生两种类型,内生型可具体分为花岗伟晶岩型、花岗岩型、云英岩型和岩浆热液型,外生型则包括盐湖型及地下卤水型(赵一鸣等,2004)。伟晶岩型锂矿主要开采锂辉石、透锂云母、锂云母、磷铝锂石等,是锂矿资源的重要来源。 相似文献
10.
锂离子电池作为现代文明中重要的能量载体被广泛且大量地使用。浅层钻探是一种重要的浅表层调查取样手段,将锂离子电池储能技术应用于便携式钻机的研发,可解决山区、林草区等特殊地貌区防火期内调查取样的难题,实现浅钻调查零碳排,助力绿色勘查发展;本文重点介绍了锂电池电动钻机的技术参数、特点及试验情况,该机型具有体积小、质量轻、无噪音、无污染,主要钻进参数可显示、可调控,钻进数据可采集、可存储等特点,锂离子电池储能技术在便携式钻机中的应用为浅钻装备数字化、信息化和智能化发展奠定了基础。 相似文献