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1.
浮游藻类对溶解态氮的吸收同化是湖泊氮生物循环和水体富营养化发生机制探讨的关键环节。本文通过~(15)N稳定同位素添加实验以铜绿微囊藻(Microcystis aeruginosa)、海链藻(Thalassiosira sp.)、卡德藻(Tetraselmis sp.)、剧毒卡尔藻(Karlodinium veneficum)以及盐水隐藻(Rhodomonas salina)为研究对象,从浮游藻类氮素吸收时间、营养盐基质以及藻种差异三个方面研究五种藻类对铵氮(NH_4~+-N)、硝氮(NO_3~--N)、尿素氮(Urea-N)三种形态氮的吸收特征。研究发现:(1)浮游藻类对三种形态氮的吸收均在1h时吸收速率最高,其氮素吸收过程为快速吸收。(2)浮游藻类优先吸收还原态氮,其中NH_4~+-N吸收速率最高,当培养周期为1d和4d时浮游藻类对NH_4~+-N吸收速率的均值分别为4.05和4.15μmol/(L·h);浮游藻类对Urea-N吸收相对偏好系数为25.18—713.42,表现出对小分子溶解态有机氮的特定偏好性。(3)不同藻种对氮素吸收具有不同特征,其中,剧毒卡尔藻对三种形态氮的吸收速率均为最高,而铜绿微囊藻的吸收速率均为最低;不同藻种不同培养时间氮素吸收速率差异与浮游藻类生长周期等特性有关。不同浮游藻类对不同形态氮素表现出吸收特异性,对水体氮负荷和浮游藻类水华优势种形成将产生重要影响。  相似文献   
2.
In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   
3.
N(187Os)/N(188Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 1013 Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD,= 3), when taking ~ 1 g of BHVO‐2 with 76 pg g?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD,= 3) when taking ~ 1 g of BIR‐2 with 350 pg g?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD,= 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.  相似文献   
4.
本文利用喜马拉雅二期科学探测台阵的678个地震台站及26个固定台站记录到的9,641个地震共约160000条远震P波走时数据,采用基于稀疏约束的多尺度层析成像方法,获得了鄂尔多斯西缘及邻区上地幔800 km深度范围内P波速度结构.结果显示,在东经104°附近阿拉善地块与鄂尔多斯盆地间存在岩石圈深度的构造边界,这表明阿拉善地块与鄂尔多斯可能分别从属于不同的大地构造单元.以北纬38°线为界,鄂尔多斯地块西缘在岩石圈范围内南北存在明显的速度差异,鄂尔多斯南部上地幔200~300 km深度范围显示为高速异常,而鄂尔多斯北部上地幔显示大面积的低速异常.这一现象表明,鄂尔多斯地块南北两部分经历了不同的构造演化过程.根据本文的结果可以进一步推断,由于青藏高原、阿拉善地块向东北方向推挤以及岩石圈的拆离引起的上地幔扰动导致了地幔上涌,上涌的热物质改造了鄂尔多斯西北缘地区的岩石圈,并使该区的岩石圈减薄.地幔上涌也可能是东经104°边界带和北纬38°构造带形成的深部动力学因素.  相似文献   
5.
滇池沉水植物生长过程对间隙水氮、磷时空变化的影响   总被引:4,自引:0,他引:4  
2015年6-10月通过原位采集滇池沉水植物分布区和无植物对照区柱状沉积物间隙水,分析其溶解性总氮(DTN)和溶解性总磷(DTP)、溶解性无机氮(DIN)和溶解性无机磷(DIP)及溶解性有机氮(DON)和溶解性有机磷(DOP)浓度的时空变化,探讨沉水植物分布对间隙水氮、磷浓度、形态贡献及氮磷比的影响.结果表明:滇池沉水植物生长过程显著影响间隙水氮、磷浓度.与无植物对照区相比,沉水植物生长过程对间隙水氮浓度的削减主要发生在6、8月,而对间隙水磷浓度的削减主要发生在7月,反映了沉水植物对氮、磷两种元素的生物地球化学循环作用机制不同;间隙水氮形态贡献受季节性影响较大,6-7月以DON贡献为主,沉水植物分布区和无植物对照区分别达到61%和84%;而8-10月以DIN贡献为主,沉水植物分布区和无植物对照区分别为76%和75%;沉水植物分布区磷形态贡献随季节波动变化,沉水植物分布区以DOP贡献为主(63%),无植物对照区以DIP贡献为主(62%);沉水植物生长对沉积物间隙水各形态氮磷比影响显著.沉水植物生长显著增加间隙水DTN/DTP比,尤其是DIN/DIP比,相反降低DON/DOP比.沉水植物对间隙水氮、磷吸收及转化过程改变了沉积物氮、磷释放机制,从而影响上覆水氮、磷组成及氮磷比,很可能会影响到浮游植物生长及藻类水华过程,这对于湖泊水质管理具有重要意义.  相似文献   
6.
Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   
7.
近年来,海水富营养化导致近海海域大型海藻过量繁殖,成为世界性的环境问题。自2007年以来,浒苔绿潮在黄海海域连续暴发,造成巨大经济损失。为探究浒苔大规模暴发与氮磷比值(N/P)的关系,及其与其他大型绿藻在不同N/P下的竞争机制,研究了浒苔(Ulva prolifera)与石莼(Ulva lactuca)在不同N/P下单独培养和共培养时的生长情况,探究了浒苔及石莼生长的变化;结合苏北浅滩海域现场N/P的调查结果,分析了浒苔绿潮暴发的可能机制。研究结果表明:(1)浒苔单独培养时,在一定范围内高N/P能促进浒苔的生长,氮对于浒苔的影响大于磷。(2)石莼单独培养时,低N/P下石莼长势最好,但改变N/P对石莼的影响并不显著。(3)浒苔和石莼共培养时,浒苔生长受到了一定限制,低N/P下浒苔生长受限更显著。(4)苏北浅滩海域高N/P更适合浒苔的生长,可能是浒苔绿潮能够大规模暴发的原因之一。  相似文献   
8.
Stable carbon and nitrogen isotopic composition of particulate organic matter(POM) were measured for samples collected from the Bering Sea in 2010 summer. Particulate organic carbon(POC) and particulate nitrogen(PN) showed high concentrations in the shelf and slope regions and decreased with depth in the slope and basin, indicating that biological processes play an important role on POM distribution. The low C/N ratio and heavy isotopic composition of POM, compared to those from the Alaska River, suggested a predominant contribution of marine biogenic organic matter in the Bering Sea. The fact that δ13C and δ15N generally increased with depth in the Bering Sea basin demonstrated that organic components with light carbon or nitrogen were decomposed preferentially during their transport to deep water. However, the high δ13C and δ15N observed in shelf bottom water were mostly resulted from sediment resuspension.  相似文献   
9.
Due to their particular physiology and life history traits, bryophytes are critical in regulating biogeochemical cycles and functions in alpine ecosystem. Hence, it is crucial to investigate their nutrient utilization strategies in comparison with vascular plants and understand their responses to the variation of growing season caused by climate change. Firstly, this study testified whether or not bryophytes can absorb nitrogen(N) directly from soil through spiking three chemical forms of 15N stable isotope tracer. Secondly, with stronger ability of carbohydrates assimilation and photosynthesis, it is supposed that N utilization efficiency of vascular plants is significantly higher than that of bryophytes. However, the recovery of soil N by bryophytes can still compete with vascular plants due to their greater phytomass. Thirdly, resource acquisition may be varied from the change of growing season, during which N pulse can be manipulated with 15N tracer addition at different time. Both of bryophytes and vascular plants contain more N in a longer growing season, and prefer inorganic over organic N. Bryophytes assimilate more NH4+ than NO3– and amino acid, which can be indicated from the greater shoot excess 15N of bryophytes. However, vascular plants prefer to absorb NO3– for their developed root systems and vascular tissue. Concerning the uptake of three forms N by bryophytes, there is significant difference between two manipulated lengths of growing season. Furthermore, the capacity of bryophytes to tolerate N-pollution may be lower than currently appreciated, which indicates the effect of climate change on asynchronous variation of soil N pools with plant requirements.  相似文献   
10.
低序级断层在地震剖面上,通常表现为具有微小错动,同相轴扭曲,或者振幅变弱,延伸短、断距小、识别难,描述难等特征。在对采集处理过程中影响低序级断层识别的观测系统面元网格、信噪比、频率、速度误差等因素详细分析的基础上,通过建立全波场正演地质模型,借助方查体属性技术以及井资料,研究了针对性的处理技术。同时利用相干体属性、曲率属性沿层切片、方差体等技术进行有效识别低级序断层,取得了较好的效果。  相似文献   
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