高效液相色谱-电感耦合等离子体质谱联用检测土壤中的无机硒形态   总被引：3，自引：3，他引：0  

秦冲  施畅  万秋月  王磊  刘爱琴  安彩秀 《岩矿测试》2018,37(6):664-670

土壤样品中亚硒酸盐Se(Ⅳ)和硒酸盐Se(Ⅵ)的形态分析中,提取剂的选择和检测方法是技术的关键。以往的提取剂容易导致硒形态发生转变或无法同时提取Se(Ⅳ)和Se(Ⅵ),常用的氢化物发生原子荧光光谱法无法直接测定Se(Ⅵ),而是通过差减法得出Se(Ⅵ)含量。本文对比了不同提取剂的提取能力,确定使用0. 1 mol/L氢氧化钠溶液作为提取剂,在55℃超声萃取土壤样品30 min,提取液经高效液相色谱分离,电感耦合等离子体质谱检测,建立了土壤中Se(Ⅳ)和Se(Ⅵ)的形态分析方法。采用Hamilton PRP X-100色谱柱,以6 mmol/L柠檬酸为流动相,pH=5. 5,在8 min内可完全分离Se(Ⅳ)和Se(Ⅵ),两者的检出限分别为0. 15μg/L、0. 16μg/L,线性相关系数(r~2)均大于0. 999。以土壤为基体进行加标回收试验,Se(Ⅳ)和Se(Ⅵ)的回收率在84. 2%～95. 8%之间,相对标准偏差为1. 4%～5. 3%(n=6)。该方法简单快速,具有良好的精密度和准确度,适用于土壤中无机硒的形态分析。  相似文献   

GNSS基本服务性能评估     

贾小林  陶清瑞  王利军  王海春  张亮 《测绘科学》2021,46(1):62-75

针对现有全球卫星导航系统性能评估无规范的评估标准问题,该文提出了以统一模型和算法为评估体系的方法,较详细的评估了全球卫星导航系统公开服务信号的基本性能,主要评估了空间信号误差、广播电离层模型改正效率及伪距单点定位精度等。结果表明:空间信号误差方面,伽利略最优、GPS和北斗三号相当;广播电离层模型方面,北斗全球广播电离层模型改正效果最优,GPSK8与NeQuick模型在低中纬度改正效果相当,北斗区域电离层模型在其服务区内具有较高改正效果;定位方面,北斗、GPS和伽利略静态伪距单点定位的三维位置均方根误差优于5m,格洛纳斯优于10 m;动态伪距单点定位方面,北斗在中国境内定位精度最高;基于统一评估体系下,可以直观对比得到目前各卫星导航系统的性能差异,同时也为后续的建设提供相应的参考。  相似文献   

Text, talk, things, and the subpolitics of performing place   总被引：1，自引：0，他引：1  

Marleen Buizer  Esther Turnhout 《Geoforum》2011,42(5):530-538

This article tells the story of how a group of Dutch and Belgian citizens organized themselves to promote an area that they valued, to put it on the map, to raise awareness about its qualities, and to protect it from urban and industrial development. Our theoretical perspective focuses on the performative and political aspects of this place-making process and the discursive and material practices involved. We connect this to Beck’s concept of subpolitics.Our findings show how the group performed this place not only through text and talk - giving the area a name, using their knowledge and expertise to raise awareness about its values, lobbying and cooperating with decision-makers -, but also through things - installing art objects and information signs that articulate certain characteristics and values of the area. Our findings demonstrate the struggles involved in these performances. The group involved multiple perspectives on what the important values and characteristics of the area are and on what strategies would work best in trying to influence decision-making and protect the area. However, the use of expertise as the main strategy to gain influence excluded the more critical and activist strategies and privileging archaeological and historical values and characteristics came at the expense of attention on agricultural and natural values.Our findings make clear that performing place cannot be taken to be homogeneous and that it inevitably involves multiple perspectives and demands. The struggles, power relations and dynamics of inclusion and exclusion that this multiplicity implicates reveal a form of sub-politics that involves both politicization and depoliticization. Also, it is a form of subpolitics that is more diverse and ambiguous than Beck’s conceptualization presupposes by its emphasis on the role of outsiders as a homogeneous group.  相似文献   

Evaluation of wave impact loads on caisson breakwaters based on joint probability of impact maxima and rise times     

Giovanni Cuomo  Rodolfo Piscopia  William Allsop 《Coastal Engineering》2011

When waves break against seawalls, vertical breakwaters, piers or jetties, they abruptly transfer their momentum into the structure. This energy transfer is always spectacular and perpetually unrepeatable but can also be very violent and affect the stability and the integrity of coastal structures. Over the last 15 years, increasing awareness of wave-impact induced structural failures of maritime structures has emphasised the need for a more complete approach to dynamic responses, including effects of impulsive loads. At the same time, movement of design standards toward probabilistic approaches requires new statistical tools able to account for uncertainties in the variability of wave loading processes. This paper presents a new approach to the definition of loads for use in performance design of vertical coastal structures subject to breaking wave impacts.  相似文献   

Intra-plant differences in seaweed nutritional quality and chemical defenses: Importance for the feeding behavior of the intertidal amphipod Orchestoidea tuberculata     

Cristian Duarte  Karin Acuña  Jorge M. Navarro  Iván Gómez 《Journal of Sea Research》2011,66(3):215-221

As a result of their morphological complexity, large macroalgae show intra-thallus variations in their nutritional composition and secondary metabolite content, which influences the trophic ecology of herbivorous invertebrates, and ultimately their fitness. In this study, we evaluated for the first time the variability in nutritional quality (protein content, carbohydrates, lipids, and total organic matter), secondary metabolites (phlorotannins), and structure (shape and toughness) between blades and stipes of the macroalgae Durvillaea Antarctica. Specifically, we looked at their effect on feeding preference, rate of consumption, absorption efficiency, and growth rate of the amphipod Orchestoidea tuberculata, one of the most abundant organisms on Chilean sandy beaches. Proteins, carbohydrates, total organic matter and phlorotannin contents were significantly higher in blades than in stipes. Preference experiments revealed that the amphipods preferred blades when fresh pieces of blades and stipes were offered at the same time. Similar results were found when artificial food (in which structures of both parts of the alga were standardized) was offered, suggesting that shape and toughness of the two different parts of the alga did not influence preference patterns of O. tuberculata. Absorption efficiency of O. tuberculata was higher on blades compared to stipes. When the amphipods were kept with each of the algal parts separately (i.e. no choice), they consumed a significantly higher amount of stipe, which suggests that O. tuberculata used food quantity to compensate for the lower nutritional quality of stipes. The higher nutritional values of blades compared to stipes appears to explain observed preference patterns by O. tuberculata. Phlorotannin content did not appear to inhibit blade consumption, suggesting that the nutritional quality of the food could be more important than chemical defense in determining food choice in O. tuberculata. Growth did not differ between the amphipods maintained with either blades or stipes (i.e. no choice), which is consistent with the hypothesis of compensatory feeding. To conclude, O. tuberculata can actively select specific parts of an alga and this selection appears to be based on nutritional quality. The capacity for using different feeding strategies allow O. tuberculata, in some cases, to successfully exploit food types with different nutritional qualities.  相似文献   

A global map to aid the identification and screening of critical habitat for marine industries     

《Marine Policy》2015

Marine industries face a number of risks that necessitate careful analysis prior to making decisions on the siting of operations and facilities. An important emerging regulatory framework on environmental sustainability for business operations is the International Finance Corporation’s Performance Standard 6 (IFC PS6). Within PS6, identification of biodiversity significance is articulated through the concept of “Critical Habitat”, a definition developed by the IFC and detailed through criteria aligned with those that support internationally accepted biodiversity designations. No publicly available tools have been developed in either the marine or terrestrial realm to assess the likelihood of sites or operations being located within PS6-defined Critical Habitat. This paper presents a starting point towards filling this gap in the form of a preliminary global map that classifies more than 13 million km² of marine and coastal areas of importance for biodiversity (protected areas, Key Biodiversity Areas [KBA], sea turtle nesting sites, cold- and warm-water corals, seamounts, seagrass beds, mangroves, saltmarshes, hydrothermal vents and cold seeps) based on their overlap with Critical Habitat criteria, as defined by IFC. In total, 5798×10³ km² (1.6%) of the analysis area (global ocean plus coastal land strip) were classed as Likely Critical Habitat, and 7526×10³ km² (2.1%) as Potential Critical Habitat; the remainder (96.3%) were Unclassified. The latter was primarily due to the paucity of biodiversity data in marine areas beyond national jurisdiction and/or in deep waters, and the comparatively fewer protected areas and KBAs in these regions. Globally, protected areas constituted 65.9% of the combined Likely and Potential Critical Habitat extent, and KBAs 29.3%, not accounting for the overlap between these two features. Relative Critical Habitat extent in Exclusive Economic Zones varied dramatically between countries. This work is likely to be of particular use for industries operating in the marine and coastal realms as an early screening aid prior to in situ Critical Habitat assessment; to financial institutions making investment decisions; and to those wishing to implement good practice policies relevant to biodiversity management. Supplementary material (available online) includes other global datasets considered, documentation and justification of biodiversity feature classification, detail of IFC PS6 criteria/scenarios, and coverage calculations.  相似文献   

Selecting and assessing social objectives for Australian fisheries management     

《Marine Policy》2015

This paper details Australian research that developed tools to assist fisheries managers and government agencies in engaging with the social dimension of industry and community welfare in fisheries management. These tools are in the form of objectives and indicators. These highlight the social dimensions and the effects of management plans and policy implementation on fishing industries and associated communities, while also taking into account the primacy of ecological imperatives. The deployment of these objectives and indicators initially provides a benchmark and, over the life of a management plan, can subsequently be used to identify trends in effects on a variety of social and economic elements that may be objectives in the management of a fishery. It is acknowledged that the degree to which factors can be monitored will be dependent upon resources of management agencies, however these frameworks provide a method for effectively monitoring and measuring change in the social dimension of fisheries management.Essentially, the work discussed in this paper provides fisheries management with the means to both track and begin to understand the effects of government policy and management plans on the social dimension of the fishing industry and its associated communities. Such tools allow the consideration of these elements, within an evidence base, into policy arrangements, and consequently provide an invaluable contribution to the ability to address resilience and sustainability of fishing industries and associated communities.  相似文献   

Photographic assessment of retroreflective film properties   总被引：1，自引：0，他引：1  

G. BurgessM.R. Shortis  P. Scott 《ISPRS Journal of Photogrammetry and Remote Sensing》2011,66(5):743-750

Retroreflective film is used widely for target manufacture in close-range photogrammetry, especially where high precision is required for applications in industrial or engineering metrology. 3M Scotchlite 7610 high gain reflective sheeting is the gold standard for retroreflective targets because of the high level of response for incidence angles up to 60°. Retroreflective film is now widely used in the transport industry for signage and many other types of film have become available. This study reports on the performance of six types of retroreflective sheeting, including 7610, based on published metrics for reflectance. Measurements were made using a camera and flash, so as to be directly applicable to photogrammetry. Analysis of the results from this project and the assessment of previous research indicates that the use of standards is essential to enable a valid comparison of retroreflective performance.  相似文献   

Effect of depth of soil stratum on performance of buildings for site-specific earthquakes     

P. Kamatchi  J. Rajasankar  Nagesh R. Iyer  N. Lakshmanan  G.V. Ramana  A.K. Nagpal 《Soil Dynamics and Earthquake Engineering》2010

Towards formulating guidelines for performance evaluation of buildings to site-specific earthquakes, studies are reported in literature on the effect of various critical parameters. No study is, however, reported on the effect of depth of soil stratum. In this paper, a methodology is proposed and applied for performance evaluation of buildings for site-specific earthquakes including depth of soil stratum as a parameter. The methodology integrates independent procedures meant for performance evaluation of buildings and site-specific seismic analysis. Application of the proposed methodology enables to determine performance point of a building in terms of inelastic displacement and base shear. Numerical application of the methodology is demonstrated using the particulars of Delhi region. Two typical RC buildings (B1 and B2) with significantly different inelastic behaviour, assumed to be located on soil depths ranging from 10 to 200 m are chosen for the application study. Capacity spectra of the buildings are generated from nonlinear static analysis. Studies indicate that for building B1, with elasto-plastic behaviour, the depth of soil stratum strongly influences demand on inelastic displacement compared to that on inelastic base shear. For building B2, with continuously varying inelastic behaviour, the depth of soil stratum is observed to have significant influence on both the inelastic base shear as well as inelastic displacement. Responses of the buildings are compared with that obtained based on design spectrum of Indian seismic code. For both the cases, inelastic displacements as well as inelastic base shears are underestimated by Indian seismic code for certain depths of soil stratum. Proposed methodology enables the calculation of realistic values of inelastic base shear and corresponding displacement of a building for site-specific earthquakes by considering the actual characteristics of soil stratum.  相似文献   

Standardizing catch rates: is logbook information by itself enough?     

Bishop  J.; Venables  W. N.; Dichmont  C. M.; Sterling  D. J. 《ICES Journal of Marine Science》2008,65(2):255-266

  相似文献