古盐湖卤水温度对钾盐沉积的控制作用探讨   总被引：2，自引：0，他引：2  

赵艳军  刘成林  张华  LI ZhaoQi  丁婷  汪明泉 《岩石学报》2015,31(9):2751-2756

古盐湖卤水的温度对钾盐沉积的控制作用的定量研究是钾盐成矿机理分析的重点和难点。本文分析和测试陕北盐盆奥陶系马家沟组、四川盆地三叠系嘉陵江组、云南兰坪-思茅盆地白垩系及老挝沙空那空盆地白垩系等八个含盐系的石盐岩中的流体包裹体,并利用均一温度计算了古盐湖的蒸发速率。若以老挝白垩纪时盐湖的蒸发速率为标准值100,陕北奥陶纪、四川三叠纪、云南白垩纪的蒸发速率标准值分别为54、68和90,而目前在老挝和云南白垩系都找到了一定规模的钾盐矿,因此高温(气温及水温)是盐湖成钾的有利条件,在卤水演化成钾的过程中可以起到重要的"催化"作用。  相似文献   

水中总氮的紫外分光光度分析法     

刘新 《海洋湖沼通报》1993,(3):60-66

本文采取K_2 S_2O_8氧化法,研究了氧化条件、紫外分光光度法测定总氮的最佳条件以及可能产生的干扰及消除方法。利用本法测定天然水中总氮回收率100±2％,检出限为0.010mg·dm~(-3)。方法快速准确,与Kjedahl法相比可提高工效27倍。  相似文献   

Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water     

Sun Yushan  Feng Fei  Sun Hanzhang  Peng Qiqiang  Xia Zongfeng  Wang Wei 《海洋学报(英文版)》1994,13(3):377-388

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.  相似文献   

特级钾长石产品的半工业性选矿试验简介          下载免费PDF全文

刘渝燕  刘晶  巩宝珍  张军 《山东国土资源》2004,20(4):54-56

根据山东省文登钾长石矿的矿石物质组成和工艺特性 ,经过不同选别方法、不同药剂种类、不同药剂用量的试验 ,确定了较佳选矿工艺 ,并以此为基础进行了半工业型试验。最终获得了特级钾长石产品。  相似文献   

新疆罗布泊盐湖深部钾盐找矿新进展   总被引：11，自引：0，他引：11       下载免费PDF全文

焦鹏程  刘成林  颜辉  陈永志  顾新鲁  孙小虹  宣之强  赵海彤  李文学 《地质学报》2014,88(6):1011-1024

罗布泊是世界最大干盐湖之一,罗布泊超大型钾盐矿床从1995年发现至今,经历了找钾远景预测、勘查、系统科学研究、扩大找矿及开发利用快速推进的过程,浅部(200m以浅)钾盐资源量已基本查明,但没有一个穿透第四系的较深地质科学钻井。通过区域气候条件、盐类矿物分布、碎屑岩层储卤等方面与柴达木盆地西部的对比分析以及罗布泊地堑式断陷带储卤的发现,提出罗布泊深部具有钾盐成矿远景。在罗布泊罗北凹地西北部实施盐湖深部钾盐找矿第一深井(LDK01井),首次发现钾芒硝、钾锶矾、红钾铁盐等盐类矿物;在深部地层碎屑岩层中发现钾盐矿物钾石盐、光卤石等,地层中KCl含量高达2.86%,揭示地层深部存在低品位固体钾矿,确定为一种新类型钾矿,即碎屑岩型钾矿,为罗布泊深部钾盐找矿拓展了方向和空间;深层碎屑岩地层储集卤水,卤水KCl平均品位1.50%,揭示出罗布泊盐湖深部存在富钾卤水。重力探测发现罗布泊盆地西部发育次级凹地,初步确定凹地中心第四系沉积厚度大于1200m。结合地质分析,预测库鲁克塔格山前断陷盆地和罗北盆地为进一步寻找深部隐伏钾盐矿床的重要靶区。综合遥感、物探、物性特征等资料及研究成果,估算罗北凹地深部钾盐预测资源量为1.60×108t,并提出罗北凹地西部及附近区域的深部地层中还蕴藏有丰富的钾盐资源,罗布泊深部找钾潜力巨大。该成果对深化认识罗布泊盐湖的形成演化及满足钾肥生产企业大规模开发均具有重要意义。  相似文献   

Usefulness of geological,mineralogical, chemical and chemometric analytical techniques in exploitation and profitability studies of iron mines and their associated elements     

M. Dolores Petit-Dominguez  M. Isabel Rucandio  Almudena Galan-Saulnier  Rosario Garcia-Gimenez 《Journal of Geochemical Exploration》2008

Due to the high number of variables involved in mine profitability studies, it is often very difficult to establish connections among them in order to provide a blend of market saleable quality products. In this sense, analytical chemistry together with chemometry are essential and indispensable disciplines to tackle these studies. The aim of this work was to demonstrate the utility of these disciplines to carry out optimization studies of iron mines. For this purpose, one of the most important iron mines of the Iberian Peninsula was chosen, sited in the mountain range of Sierra Menera, near the location of Ojos Negros (Teruel, Spain). Geological, mineralogical and chemical composition of 148 samples was analyzed, corresponding to different depths of three drill holes (named TE1, TE2 and TE3). In particular, aspects concerning to chemical composition are very important, since the mean contents of certain elements, such as phosphorus, sodium and potassium, should be restricted to the established limits to prevent that companies can drive back the raw material if they do not fulfil the necessary requirements. On the other hand, the large number of analysed samples drove us to use a statistical processing of the data. Among other aspects, it provides a way to find possible connections among a high number of variables and classify samples into compositional groups sharing similar composition, in order to limit the mineralised area and to obtain enough information about the amount of those chemical elements associated to iron ores. Data obtained from all these analytical techniques were in good agreement and provide a methodology that can be of wide interest applied to different geological studies.  相似文献   

Microbial release of potassium from K-bearing minerals by thermophilic fungus Aspergillus fumigatus     

Bin Lian  Bin Wang  Mu Pan  H. Henry Teng 《Geochimica et cosmochimica acta》2008,72(1):87-98

A strain of thermophilic fungus Aspergillus fumigatus was cultured with K-bearing minerals to determine if microbe-mineral interactions enhance the release of mineralic potassium. Experiments were carried out in two settings, one with the mineral grains and the fungal cells in direct contact, and the other employing a membrane (pore size 0.22 μm) to separate the two. Measurements over a period of 30 days showed that, irrespective of the experimental setup, the concentration of free K in the culture was drastically higher than those in any of the control experiments where no living organism was present. Moreover, the occurrence of mineral-cell physical contact enhanced potassium release by an additional factor of 3 to 4 in comparison to the separation experiments. For contact experiments, Electron Probe Microanalysis revealed the formation of mycelium-mineral aggregates, and Atomic Force Microscopy imaging further indicated the possible ingestion of mineral particles by the fungus cells. Contrasting to what was observed and expected in control experiments, the potassium solubilization rate showed a positive dependence upon pH when fungi and minerals were mixed directly, and exhibited no correlations with solution acidity if cell-rock contact was restrained. These results appear to suggest that A. fumigatus promoted potassium release by means of at least three likely routes, one through the complexation of soluble organic ligands, another appealing to the immobile biopolymers such as the insoluble components of secretion, and the third related to the mechanical forces in association with the direct physical contact between cells and mineral particles.  相似文献   

西台吉乃尔盐湖原卤水历年来钾硼锂镁等元素品位变化及未来变化趋势预测          下载免费PDF全文

余明祥  李陇岗  陈元军  秦佳政  刘贺 《盐湖研究》2021,29(3):98-103

研究统计了西台吉乃尔盐湖(以下简称西台)自开发以来原卤水中钾硼锂镁各元素品位变化,利用K~+,Na~+,Mg~(2+)/Cl~-,SO_4~(2-)-H_2O五元体系298K介稳相图研究了主要元素之间相对含量的变化关系。根据西台开发现状建立数学模型,预测了未来10年钾硼锂元素品位变化趋势,为西台盐湖钾硼锂镁等资源的开发和综合利用提供依据。  相似文献   

我国积极破解钾盐矿资源短缺迷局   总被引：2，自引：0，他引：2       下载免费PDF全文

庾莉萍 《盐湖研究》2007,15(4):49-55

介绍了钾肥的应用范围,阐述了我国钾盐的生产情况、需求空间和对进口的依赖程度,重点介绍了我国主要的钾盐资源和泰国、老挝、俄罗斯等周边国家的钾盐资源。最后提出了要充分利用国内外"两种资源、两个市场",建立起我国强有力的钾肥资源保障体系,保障我国农村的可持续发展。  相似文献   

Effect of water quality on the leaching of potassium from sandy soil   总被引：1，自引：0，他引：1  

Z. Kolahchi  M. Jalali   《Journal of Arid Environments》2007,68(4):624-639

When potassium (K⁺) fertilizers are applied to soil, K⁺ is subject to displacement through the soil profile. More generally, the application of K⁺ fertilizers to sandy soils with low clay content and small buffer capacity, in which K⁺ does not interact strongly with the soil matrix, results in localized increases in K⁺ concentration in the soil solution. Losses of K⁺ depend on the concentration of calcium (Ca²⁺) as a competing ion in the leaching water and the amount of water that passes through the soil. In this study, we examined the adsorption and movement of applied K⁺ in columns of sandy soil. Glass tubes, 4.8 cm in diameter and 40 cm in length, were packed with either native soil or Ca²⁺-saturated soil. The resulting 10-cm-long column of soil had a bulk density of 1.65 g cm⁻³. Native soil was leached with distilled water and CaCl₂ solutions of various concentrations. In the Ca²⁺-saturated soil, a pulse of K⁺ was leached with CaCl₂ solutions of various concentrations or distilled water. Increasing the CaCl₂ concentration from 3 to 15 mm resulted in earlier breakthrough, a higher peak concentration of K⁺, and greater amounts of leached K⁺. The breakthrough curve for K⁺, when leached with distilled water, showed very low concentrations and was more delayed than the other treatments. In Ca²⁺-saturated soil, the amount of K⁺ leached increased as Ca²⁺ concentration increased, with up to 54% of the added pulse K⁺ being removed from 10 pore volumes (Pv) (387 mm) of 15 mm CaCl₂. The presence of Ca²⁺ in irrigation water and soil minerals able to release Ca²⁺ is important in determining the amount of K⁺ leached from soils. Large amounts of K⁺ are leached from soils in areas where crops are irrigated with water that contains significant concentrations of Ca²⁺ and other cations.  相似文献