First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

2007-2017年中国沙尘气溶胶的三维分布特征及输送过程     

贾瑞  刘玉芝  吴楚樵  祝清哲  汪兵 《中国沙漠》2019,39(6):108-117

利用最新发布的CALIPSO产品，构建了2007-2017年中国沙尘气溶胶的三维分布，并结合HYSPLIT-4模式和再分析数据，探讨了沙尘的三维输送过程。结果表明：中国的沙尘排放源区主要是塔克拉玛干沙漠和巴丹吉林沙漠，沙尘气溶胶出现频率分别为60%和35%。塔克拉玛干沙漠排放的沙尘主要（50%~70%）停留在源地0~6 000 m高度，少部分向东输送至甘肃和内蒙古；巴丹吉林沙漠排放的沙尘则主要向东输送。中国沙尘排放量在春季最大，向东输送最强；夏季，东亚夏季风限制了沙尘向东输送；秋季，沙尘排放减弱，输送强度和夏季相当；沙尘排放量在冬季最小，输送最弱。夏季，沙尘在输送过程中可被抬升至高度5 000 m以上，春季次之，秋、冬季的沙尘主要在低层大气输送。沙尘在向东输送的过程中被抬升并和当地人为污染物混合变为污染性沙尘，华北地区污染性沙尘出现频率高达30%；输送到海洋的沙尘也会与洋面上（0~3 000 m高度）的海盐气溶胶混合，出现频率约为10%。  相似文献   

Prediction of the calcium carbonate budget in a sedimentary basin: A “source-to-sink” approach applied to Great Salt Lake,Utah, USA     

Anthony Bouton  Emmanuelle Vennin  Philippe Amiotte-Suchet  Christophe Thomazo  Jean-Pierre Sizun  Aurélien Virgone  Eric C. Gaucher  Pieter T. Visscher 《Basin Research》2020,32(5):1005-1034

Most source-to-sink studies typically focus on the dynamics of clastic sediments and consider erosion, transport and deposition of sediment particles as the sole contributors. Although often neglected, dissolved solids produced by weathering processes contribute significantly in the sedimentary dynamics of basins, supporting chemical and/or biological precipitation. Calcium ions are usually a major dissolved constituent of water drained through the watershed and may facilitate the precipitation of calcium carbonate when supersaturating conditions are reached. The high mobility of Ca²⁺ ions may cause outflow from an open system and consequently loss. In contrast, in closed basins, all dissolved (i.e. non-volatile) inputs converge at the lowest point of the basin. The endoreic Great Salt Lake basin constitutes an excellent natural laboratory to study the dynamics of calcium on a basin scale, from the erosion and transport through the watershed to the sink, including sedimentation in lake's waterbody. The current investigation focused on the Holocene epoch. Despite successive lake level fluctuations (amplitude around 10 m), the average water level seems to have not been affected by any significant long-term change (i.e. no increasing or decreasing trend, but fairly stable across the Holocene). Weathering of calcium-rich minerals in the watershed mobilizes Ca²⁺ ions that are transported by surface streams and subsurface flow to the Great Salt Lake (GSL). Monitoring data of these flows was corrected for recent anthropogenic activity (river management) and combined with direct precipitation (i.e. rain and snow) and atmospheric dust income into the lake, allowing estimating the amount of calcium delivered to the GSL. These values were then extrapolated through the Holocene period and compared to the estimated amount of calcium stored in GSL water column, porewater and sediments (using hydrochemical, mapping, coring and petrophysical estimates). The similar estimate of calcium delivered (4.88 Gt) and calcium stored (3.94 Gt) is consistent with the premise of the source-to-sink approach: a mass balance between eroded and transported compounds and the sinks. The amount of calcium deposited in the basin can therefore be predicted indirectly from the different inputs, which can be assessed with more confidence. When monitoring is unavailable (e.g. in the fossil record), the geodynamic context, the average lithology of the watershed and the bioclimatic classification of an endoreic basin are alternative properties that may be used to estimate the inputs. We show that this approach is sufficiently accurate to predict the amount of calcium captured in a basin and can be extended to the whole fossil record and inform on the storage of calcium.  相似文献   

Spatial and Temporal Distribution of Dust‐Bound Trace Metal Elements around Kuhdasht Watershed Area in Iran     

Hamid Alipour  Ahmad Jalalian  Naser Honarjoo  Norair Tommanian  Fereidoon Sarmadian 《洁净——土壤、空气、水》2019,47(10)

Dust, as a source of trace metal elements, affects the health of society. The spatial and temporal concentrations of dust‐bound trace metals (Cd, Pb, Ni, Zn, Cu, and Mn) in Kuhdasht watershed (456 km²), Lorestan Province, Iran, is investigated. Dust is collected using glass traps placed in ten research stations in the region. The spatial and temporal distribution of dust trace metals are plotted using ARC‐GIS. The highest and the lowest concentrations of Zn (9751150 mg kg^?1), Pb (46.352.9 mg kg^?1), and Cd (2.443.30 mg kg^?1) are obtained in winter, of Ni (98110 mg kg^?1) and Cu in autumn (16.053.5 mg kg^?1), and of Mn in summer (385505 mg kg^?1). The spatial concentrations of dust‐bound trace metals indicate all, except Cu, show a decreasing trend from the mountains toward the plains, similar to that of soil and of dust, except for Zn, which shows higher concentrations in dust than in soil. The potential sources of dust‐bound trace metals and their rate of contamination are also investigated using the enrichment and contamination factors. The major sources of Cd and Zn in the dust of watershed are due to anthropogenic activities or from activities outside the borders.  相似文献   

An Amended Chemical Mass Balance Model for Source Apportionment of PM2.5 in Typical Chinese Eastern Coastal Cities     

Qiaoli Wang  Nana Cheng  Sujing Li  Minli Dong  Xiangqian Wang  Linlin Ge  Tianjiao Guo  Wei Li  Xiang Gao 《洁净——土壤、空气、水》2019,47(2)

  相似文献   

论中国古代地缘战略制定中的“权衡”——以《盐铁论》为例   总被引：3，自引：1，他引：2  

王丰龙  刘云刚 《地理科学》2019,39(9):1407-1415

《盐铁论》是记录汉朝时期关于盐铁酒榷均输及对匈奴关系的辩论的一部重要著作,能够较典型地反映中国古代地缘战略制定中的“权衡”过程。构建中国古代地缘战略制定中的“权衡”理论分析框架,继而基于该分析框架对《盐铁论》中的地缘战略辩论进行详细解读。《盐铁论》中辩论双方“权衡”的要点包含匈奴对汉朝产生的威胁程度、领土扩张所带来的收益大小和相应地缘战略的合法性3个方面。从思想、方法、目的等比较中西方地缘政治研究差异,指出“权衡”思想为西方主导的地缘政治理论提供新视角。  相似文献   

车辆碾压作用下戈壁地表起尘浓度   总被引：1，自引：1，他引：0  

孟小楠  严平  王振亭  董苗  王勇 《中国沙漠》2019,39(1):80-87

通过野外观测车辆碾压作用下戈壁地表PM₁₀释放浓度，探讨其主要影响因素。针对戈壁区砾石、砂砾、砂质和砂土4种路面类型，应用TSI粉尘仪多次重复观测车辆碾压产生的PM₁₀浓度，进而阐明碾压次数、车速和地表水分等因素对起尘浓度的影响。结果表明：4种路面的平均起尘浓度依次为5.339、9.089、16.944、50.251 mg·m^-3，是自然状态下的5~50倍；起尘浓度随碾压次数增多而增大，其中砂土路情况下的增长最显著；随土层厚度的增大呈现出幂函数的增长趋势；降雨后路面起尘浓度显著减小，且降雨量会影响降雨后起尘浓度的变化趋势。最后提出了针对性的建议和措施以减弱车辆碾压导致的戈壁地表起尘。  相似文献   

2018年秦皇岛风暴潮前后岸基站及浮标主要水质参数变化分析     

马方方  王刚  毕玉明  周秋伶  桓清柳 《海洋技术学报》2019,38(6):68-74

对2018年8月秦皇岛风暴潮期间3个入海口岸基站及邻近海域浮标的监测数据进行分析,结果显示:风暴潮导致入海口水体中COD、总磷、总氮和氨氮含量均明显升高;风暴潮2 d之后,3个入海口邻近海域均发生赤潮,此次赤潮的发生与风暴潮导致陆源入海污染物骤然大幅升高有关。此次风暴潮导致秦皇岛人造河口、大蒲河口和七里海3个岸基监测站的COD监测日均值最高分别达到15.83 mg/L、8.70 mg/L和7.92 mg/L,约升高至前期的2倍、1.5倍和2倍;人造河口总氮变化不大,大蒲河口和七里海总氮升高30%左右;大蒲河口总磷变化不大,人造河口总磷为前期的3.5倍,升高幅度最大,七里海总磷为风暴潮之前两日的2倍,但未超过前一周的最高浓度;风暴潮当天及第二天,人造河口、大蒲河口、七里海氨氮日均值陆续达到最高,分别为2.34 mg/L、1.11 mg/L和0.12 mg/L,分别为风暴潮前两日的7倍、3.5倍和10倍。风暴潮过后,入海口临近海域发生赤潮,浮标监测到叶绿素a最高值为76.4μg/L,pH和溶解氧也大幅升高。分析表明,此次风暴潮导致的入海口污染物突然大幅升高为风暴潮之后的赤潮发生提供了充足的营养基础。  相似文献   

南海风暴潮对风场和外围海水敏感性研究     

李健  刘清容  阮成卿  訚忠辉  冀承振 《海洋科学》2018,42(2):99-107

为探索来自西北太平洋台风风暴潮与南海局地生成台风风暴潮不同,本研究在假设两种台风气象条件相同情况下,研究随台风而来外围海水所形成增水对南海沿岸的影响。以0814"黑格比"强台风风暴潮为基础,使用ROMS(regional ocean modeling system)模式进行数值模拟并通过设计对比试验方法进行研究,研究发现在台风登陆时引起的增水最大,最大增水出现在台风路径右侧,其中在沿岸区域,外围海水形成增水约占总增水10%,且大约3 h后出现增水回震现象。同时,设计对比试验,研究来自西北太平洋台风风暴潮对台风路径、台风强度、台风移动速度和流入角等气象条件敏感性,并获得与前人一致的结果。  相似文献   

艾比湖原核微生物菌群结构演变与环境因子关系分析          下载免费PDF全文

马雪莉  吕杰  马媛  吕光辉 《盐湖研究》2020,28(4):79-90

用非培养法获得新疆维吾尔自治区艾比湖湖底沉积物原核微生物菌群组成,并与已有盐湖原核微生物菌群数据进行比对,分析湖泊由淡水湖向盐湖演替过程中原核微生物群落结构变化规律。实验获得艾比湖原核微生物16S rRNA基因序列,并从NCBI数据库下载赛里木湖、柴窝堡湖和顿巴斯他乌盐湖3个湖泊的非培养原核微生物16S rRNA基因序列数据。用不同盐湖细菌和古菌16S rRNA序列信息构建系统发育树并与其理化指标进行典型性相关分析。同源比对及聚类结果显示,艾比湖湖底沉积物中细菌包括4个门,拟杆菌门(Bacteroidetes)占克隆文库的64%,变形菌门(Proteobacteria)占9.4%,厚壁菌门(Firmicutes)占3.4%,放线菌门(Actinobacteria)占2.6%,此外含有未分类类群20.6%。古菌含有两个门,广古菌门(Euryarchaeota,98.3%)和盐纳古菌门(Nanohaloarchaeota,1.7%)。不同盐湖系统发育树结果显示,随盐度增加,盐湖细菌从变形菌门向拟杆菌门演替；古菌从奇古菌门和泉古菌门向广古菌门和盐纳古菌门演替。RDA结果显示,Na⁺、Cl-、SO₄2-和矿化度对盐湖原核微生物多样性结构起到决定性的作用,K⁺、Mg²⁺和Ca²⁺对艾比湖菌群结构影响作用最为显著。原核微生物群落会随着湖水盐浓度的增加和盐湖化学成分的不同而发生演替。  相似文献