Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

Stream channel erosion in a rapidly urbanizing region of the US–Mexico border: documenting the importance of channel hardpoints with Structure‐from‐Motion photogrammetry          下载免费PDF全文

Kristine T. Taniguchi  Trent W. Biggs  Eddy J. Langendoen  Carlos Castillo  Napoleon Gudino‐Elizondo  Yongping Yuan  Douglas Liden 《地球表面变化过程与地形》2018,43(7):1465-1477

Urbanization can lead to accelerated stream channel erosion, especially in areas experiencing rapid population growth, unregulated urban development on erodible soils, and variable enforcement of environmental regulations. A combination of field surveys and Structure‐from‐Motion (SfM) photogrammetry techniques was used to document spatial patterns in stream channel geometry in a rapidly urbanizing watershed, Los Laureles Canyon (LLCW), in Tijuana, Mexico. Ground‐based SfM photogrammetry was used to map channel dimensions with 1 to 2 cm vertical mean error for four stream reaches (100–300 m long) that were highly variable and difficult to survey with a differential GPS. Regional channel geometry curves for LLCW had statistically larger slopes and intercepts compared with regional curves developed for comparable, undisturbed reference channels. Cross‐sectional areas of channels downstream of hardpoints, such as concrete reaches or culverts, were up to 64 times greater than reference channels, with enlargement persisting, in some cases, up to 230 m downstream. Percentage impervious cover was not a good predictor of channel enlargement. Proximity to upstream hardpoint, and lack of riparian and bank vegetation paired with highly erodible bed and bank materials may account for the instability of the highly enlarged and unstable cross‐sections. Channel erosion due to urbanization accounts for approximately 25–40% of the total sediment budget for the watershed, and channel erosion downstream of hardpoints accounts for one‐third of all channel erosion. Channels downstream of hardpoints should be stabilized to prevent increased inputs of sediment to the Tijuana Estuary and local hazards near the structures, especially in areas with urban settlements near the stream channel. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Towards new applications of underwater photogrammetry for investigating coral reef morphology and habitat complexity in the Myeik Archipelago,Myanmar     

Martina Anelli  Tommaso Julitta  Luca Fallati  Paolo Galli  Micol Rossini  Roberto Colombo 《国际地球制图》2019,34(5):459-472

Photogrammetry represents a non-destructive, cost-effective tool for coral reef monitoring, able to integrate traditional remote sensing techniques and support researchers’ work. However, its application to submerged habitats is still in early stage. We present new ways to employ Structure from Motion techniques to infer properties of reef habitats. In particular, we propose the use of Digital Surface Models and Digital Terrain Models for assessing coral colonies extension and height and discriminating between seabed and coral cover. Such information can be coupled with digital rugosity estimates to improve habitat characterization. DTM, DSM and orthophotos were derived and used to compute a series of metrics like coral morphologies, reef topography, coral cover and structural complexity. We show the potentialities offered by underwater photogrammetry and derived products to provide useful basic information for marine habitat mapping, opening the possibility to extend these methods for large-scale assessment and monitoring of coral reefs.  相似文献   

云南香格里拉市热林铅锌银矿特征及找矿标志     

赵贤  孙涛  胡成军 《云南地质》2021,(1):42-46

云南香格里拉市热林铅锌银矿,矿体呈似层状赋存于三叠系上统曲嘎寺组三段(T₃q³)之大理岩与板岩的层间构造破碎带中,矿体明显受断层构造及特定的岩性控制。该矿床属断层破碎带控制的热液型铅锌银矿床,断层破碎带和地球化学异常是直接的找矿标志,沿断层带出现的硅化、碳酸盐化、黄铁矿化和角岩化是间接的找矿标志。  相似文献   

Uncertainty in structural interpretation: Lessons to be learnt     

《Journal of Structural Geology》2015

Uncertainty in the interpretation of geological data is an inherent element of geology. Datasets from different sources: remotely sensed seismic imagery, field data and borehole data, are often combined and interpreted to create a geological model of the sub-surface. The data have limited resolution and spatial distribution that results in uncertainty in the interpretation of the data and in the subsequent geological model(s) created. Methods to determine the extent of interpretational uncertainty of a dataset, how to capture and express that uncertainty, and consideration of uncertainties in terms of risk have been investigated. Here I review the work that has taken place and discuss best practice in accounting for uncertainties in structural interpretation workflows. Barriers to best practice are reflected on, including the use of software packages for interpretation. Experimental evidence suggests that minimising interpretation error through the use of geological reasoning and rules can help decrease interpretation uncertainty; through identification of inadmissible interpretations and in highlighting areas of uncertainty. Understanding expert thought processes and reasoning, including the use of visuospatial skills, during interpretation may aid in the identification of uncertainties, and in the education of new geoscientists.  相似文献   

台湾地形对台风Meranti(1010)经过海峡地区时迅速增强的影响研究   总被引：3，自引：1，他引：2  

薛霖  李英  许映龙  王蕾  戴高菊 《大气科学》2015,39(4):789-801

台风在趋近大陆过程中强度一般衰减, 但Meranti(1010)北上进入台湾海峡过程中却迅速加强, 且在登陆福建时达到最强。采用中国气象局台风资料、NCEP GFS 0.5°×0.5°再分析资料及台湾雷达资料, 结合中尺度数值模式WRF(The Weather Research and Forecasting Model)开展台湾地形敏感性试验, 研究Meranti进入台湾海峡过程中的结构变化及迅速加强机理。结果表明:台湾地形是Meranti迅速加强的一个重要影响因子。Meranti北上过程中, 一方面通过台湾岛地形分流作用及其背风坡效应在台湾海峡内诱生中尺度涡旋, 形成正负相间的涡度分布, 激发出与台风相关的扰动波列。地形强迫抬升及扰动波列可加强垂直运动和积云对流, 有利于台风对流发展。另一方面, 台湾地形还通过改变环境气流使台风高空辐散场加强, 环境风垂直切变减小, 形成有利于台风发展的环流背景。比较不同高度台湾地形试验中台风动能收支发现, 台湾地形激发的扰动波列和积云对流增强了次网格尺度系统与台风间能量的交换, 成为Meranti登陆前迅速加强的主要动能源。  相似文献   

东营凹陷八面河北部斜坡带构造特征及形成机制     

张蕾 《山东国土资源》2015,31(6)

研究了东营凹陷八面河北部斜坡带的断裂特征、构造演化特征及其形成机制,明确了该区的断裂展布特点和断层活动性,弄清了北部斜坡带的演化规律,同时分析该区的构造变形特征。结果表明：中生代以后,八面河地区存在2种独立的构造变形系统：一是板块边缘相互作用力;二是到后期由于板块的持续俯冲,地幔底辟作用在岩石圈底面产生的牵引力。八面河北部地区在这2种构造力的综合作用下,不同时期表现出不同的构造变形特征。  相似文献   

云南保山从干树金矿控矿条件及矿床成因讨论     

李先棋  涂向衡  杜彦强  李琼仙 《云南地质》2011,30(2):130-133,140

从干树金矿赋存于怒江构造带高黎贡山岩群变质岩系中,有两个明显的次级矿化带,具多期次成矿作用特点:前期可能为沉积变质赋矿,后期为剪切(构造热液)成矿。晚期在浅部风化淋滤富集。剪切作用形成的金矿是主体。  相似文献   

鄂尔多斯盆地旦八油田延长组长3储层研究     

许小强  赵进义  郭浩  潘翔 《云南地质》2011,30(1):115-117

三叠系延长组长3储集层灰色细粒长石砂岩储层物性差,属低孔、低渗储层.空隙以粒间孔、溶孔为主,且成岩作用控制孔隙结构.根据岩性、物性特征,把研究区储层分为四类:Ⅰ类好储集层,Ⅱ类较好储集层,Ⅲ类较差储集层,Ⅳ类非储层.  相似文献   

胶州湾营养盐浓度与结构的长期变化   总被引：15，自引：0，他引：15  

孙晓霞  孙松  赵增霞  沈志良 《海洋与湖沼》2011,42(5):662-669

依据自20世纪60年代以来胶州湾营养盐调查与研究资料,系统分析了近40余年来胶州湾营养盐浓度与结构的长期变化规律,以及2000年以后胶州湾营养盐浓度与结构的变化特征。结果表明,近几十年来胶州湾各项营养盐浓度都呈现增加趋势,但不同种类营养盐浓度变化的时期并不相同。氨氮浓度到2001年达到顶峰,随后呈现下降趋势。而亚硝酸盐...  相似文献