阿拉尔河悬浮物对铀的吸附影响研究          下载免费PDF全文

钟翼  许建新  韩积斌  徐凯 《盐湖研究》2020,28(1):112-122

为了解阿拉尔河悬浮物对铀的吸附特性,通过静态吸附实验,研究了吸附时间、pH值、温度和铀初始浓度等因素对模拟含铀水中U(VI)去除率的影响,并从热力学和动力学方面对吸附过程进行了分析。结果表明,在T=25℃,溶液初始pH=7,接触时间为16 h时,悬浮物对铀的平衡吸附率最佳,为95.48%。随着铀初始浓度的增加,吸附量增加,但吸附率随之下降,升高温度有利于铀的吸附。铀在悬浮物上的吸附过程符合Langmuir等温吸附方程,说明悬浮物对铀为单分子层吸附,且化学吸附占主导地位。吸附动力学过程可用准二级吸附动力学模型描述,表明吸附主要受动力学控制,由两个以上步骤共同控制。FTIR和EDS分析结果表明,吸附过程中铀主要与悬浮物表面活性基团螯合并以表面络合吸附为主。吸附前后的能谱对比分析表明,吸附过程中存在离子交换行为。因此,悬浮物对铀的吸附机理是以表面络合吸附和离子交换为主、物理吸附为辅的混合吸附过程。  相似文献   

NURE航空计划回顾与新时代航空γ能谱勘查启示     

李敬敏  米耀辉  骆遥 《物探与化探》2021,(2):394-402

国家铀资源评价(NURE)计划实现了覆盖美国本土和阿拉斯加的1∶250000 NTMS图幅航空γ能谱测量和航磁测量,通过简要回顾该计划历程,重点针对NURE中航空地球物理勘查(航空γ能谱和航磁测量),讨论了航空地球物理勘查中测量技术、数据处理及解释方法等。NURE航空测量在铀矿勘查和辐射环境评价、洲际航空地球物理编图等领域发挥了巨大作用,产生了意义深远的影响。在总结NURE航空测量经验和做法的基础上,针对我国航空γ能谱测量勘查现状,建议从国家层面进行顶层设计,尽快实施我国陆域范围内的航空γ能谱和航磁框架性测量,实现对我国陆域航空γ能谱测量全覆盖,建设具有中国特色的航空γ能谱测量与监测体系。  相似文献   

辽东铀成矿带连山关地区韧性剪切带与铀成矿作用     

吴迪  刘永江  李伟民  常瑞虹 《岩石学报》2020,36(8):2571-2588

连山关地区位于华北克拉通北缘铀成矿省辽东铀成矿带，已知铀矿床（点）均发育在韧性剪切带附近。为了解韧性剪切带运动学、几何学构造变形机制及与铀矿的关系，本文以连山关岩体周缘韧性剪切带为研究对象，通过野外宏观调查和室内微观研究相结合的研究方法，探讨构造变形期次、韧性剪切带形成机理及其对铀成矿的控制作用。研究表明：连山关岩体周缘发育的韧性剪切带与近南北向挤压构造变形有关，其右行韧性剪切带应变类型为压扁应变，属于一般压缩-平面应变范围，Flinn指数K值在0.19~0.69之间，岩石类型属于S/SL型构造岩。研究区内铀矿体均为隐伏盲矿体，主要赋存于沿着连山关岩体和辽河群接触带右行剪切作用形成的背斜褶皱核部，和北东东向断裂关系密切。综合分析认为，连山关岩体南缘北西向韧性剪切带为一级控矿构造，是区内铀矿热液运移的通道，而剪切带边部的晚期北东东向断裂则是铀矿储存空间；铀源可能来自于太古宙古风化壳，并在大型韧性剪切活动（提供热液运移通道）和基性脉岩侵入（提供热源和还原剂）等综合因素作用下运移、富集成矿。  相似文献   

高分异花岗岩浆可能是华南花岗岩型铀矿床主要铀源——来自诸广山南体花岗岩锆石铀含量的证据     

伍皓  夏彧  周恳恳  张建军 《岩石学报》2020,36(2):589-600

锆石的U-Pb测年、Hf和O同位素及稀土、微量元素的研究与应用已获得诸多进展,但锆石中铀含量所蕴藏的地质意义却较少被关注。华南花岗岩型铀矿床的铀源一直存在争议,不同观点认为其分别来自早期已固结地质体、分异岩浆、地幔柱或热点以及U、Th、K富集圈。为尝试利用锆石中的铀含量来追索铀源,本文通过搜集诸广山南体花岗岩锆石U-Pb同位素测年文献,掌握了该花岗岩中14个岩体、37件样品、3种岩性,共467个锆石定年数据。通过数据分析发现印支期(253Ma、244Ma)和燕山期(139Ma、124Ma)具高分异特征的4件酸性岩脉(小岩体)样品中锆石的铀含量明显高于同期岩体。依据铀矿床中高分异酸性岩脉(小岩体)侵位期、基性岩脉侵位期、铀成矿早期(140~90Ma)三者的良好对应关系,结合这一锆石铀含量指示,初步认为华南花岗岩型铀矿床中铀可能主要来自高分异花岗岩浆;推测花岗岩型铀成矿可能属壳幔混合作用结果,即铀源来自地壳分异岩浆,成矿流体和矿化剂主要来自地幔,而成矿空间受断裂系统控制。岩体锆石铀含量或可在铀源丰度、矿床品位判别等方面发挥积极作用。  相似文献   

富二价铁岩石信息提取及在铀矿勘查中的应用     

杨燕杰  赵英俊  刘德长  张万良 《测绘科学》2011,36(5):77-78

本文利用航空高光谱CASI数据和岩石的光谱特征,提出一种快速提取富含Fe2+岩石信息的算法,并由此获取辉绿岩脉信息。经过实地验证,数据处理结果的精度较高,处理结果中辉绿岩脉规模及其走向等特征清晰。将提取的结果与铀矿异常信息对比分析,发现富含Fe2+的辉绿岩脉与铀异常具有很强的相关性。通过利用这种方法,在研究区南部又新发现了两条辉绿岩脉构造。  相似文献   

Apatite Fission Track Thermochronology of Granite from the Xiazhuang Uranium Ore Field, South China: Implications for Exhumation History and Ore Preservation     

SUN Yue  CHEN Zhengle  PAN Jiayong  HUO Hailong  LI Haidong  SUN Junjie  XU Guangchun 《《地质学报》英文版》2024,98(2):430-440

Xiazhuang uranium ore field, located in the southern part of the Nanling Metallogenic Belt, is considered one of the largest granite-related U regions in South China. In this paper, we contribute new apatite fission track data and thermal history modeling to constrain the exhumation history and evaluate preservation potential of the Xiazhuang Uranium ore field. Nine Triassic outcrop granite samples collected from different locations of Xiazhuang Uranium ore field yield AFT ages ranging from 43 to 24 Ma with similar mean confined fission track lengths ranging from 11.8 ± 2.0 to 12.9 ± 1.9 μm and Dpar values between 1.01 and 1.51 μm. The robustness time-temperature reconstructions of samples from the hanging wall of Huangpi fault show that the Xiazhuang Uranium ore field experienced a time of monotonous and slow cooling starting from middle Paleocene to middle Miocene (~60–10 Ma), followed by relatively rapid exhumation in the late Miocene (~10–5 Ma) and nearly thermal stability in the Pliocene–Quaternary (~5–0 Ma). The amount of exhumation after U mineralization since the Middle Paleogene was estimated as ~4.3 ± 1.8 km according to the integrated thermal history model. Previous studies indicate that the ore-forming ages of U deposits in the Xiazhuang ore field are mainly before Middle Paleocene and the mineralization depths are more than 4.4 ± 1.2 km. Therefore, the exhumation history since middle Paleocene plays important roles in the preservation of the Xiazhuang Uranium ore field.  相似文献   

Testing mathematical uranium migration models in combined ESR/U-series dating of fossil teeth from open-air sites     

《Quaternary Geochronology》2015

Several mathematical models have been suggested to describe uranium migration kinetics for ESR dating of fossil tooth. In the present study, different U-uptake models were used to calculate ages for fossil teeth from two open-air Paleolithic sites in Nihewan Basin – Donggutuo and Hougou and compared with independent age control of the sites. For Donggutuo site, the results show that the ages of three teeth calculated by EU and AU models were much younger than magnetostratigraphic age. At Hougou site, two teeth from the top of Nihewan lacustrine deposits give the consistent EU and AU ages within errors but younger than sediment OSL age. This study indicates that mathematical modeling could not always give convincing results for the open-air sites, which may experience dramatic hydrological variations and high erosion rates.  相似文献   

Fluxes and behavior of radium isotopes, barium, and uranium in seven Southeastern US rivers and estuaries     

Willard S. Moore  Timothy J. Shaw 《Marine Chemistry》2008,108(3-4):236-254

This paper demonstrates the importance of advective transport of water through permeable estuarine and salt marsh sediments. This transport delivers significant quantities of radium and barium to the coastal ocean; and, in some cases may remove significant quantities of uranium. These conclusions are based on repeated analyses of seven river–estuarine systems from North Carolina to Florida. Fluxes of radium and barium from these river systems are shown to be inadequate to balance the dissolved inventories of these elements in the South Atlantic Bight. The strong interactions that occur between surface and subsurface waters as these rivers encounter coastal marshes lead us to consider these river mouths as marsh-dominated in terms of their chemical fluxes to the ocean. Such interactions between the river and coastal marsh must be considered when estimating fluxes of material between the land and ocean.  相似文献   

CBERS-02B星数据质量评价及铀成矿要素解译应用研究   总被引：1，自引：0，他引：1  

张杰林  赵英俊  张静波  黄艳菊  宣艳秀 《国土资源遥感》2009,(1)

利用遥感影像处理技术和数理统计方法,评价了中巴地球资源卫星02B星(CBERS-02B,以下简称02B星)遥感数据的空间特性和辐射特征,并与ETM+多光谱数据主要特性参数进行了对比分析.在此基础上,以江西桃山花岗岩型铀矿田为试验区,结合航空放射性数据,开展了基于02B星遥感数据的控矿断裂带、热液蚀变带及主要成矿岩体等铀成矿要素的光谱特征识别与提取,并对该数据的地学应用潜力进行了评价.  相似文献   

青海玉树断裂带地震落石的地震地质意义     

田婷婷  吴中海  马志邦  冯卉  尼玛次仁  蒋瑶  张绪教  张铎 《地质通报》2014,33(4):567-577

2010年青海玉树Ms 7.1级大地震引发了一系列次生地质灾害,其中地震落石是除地震滑坡外沿断裂带及其邻侧最常见的现象。对玉树震区落石的调查发现,该区多处存在非常典型的多期地震落石分布现象,指示该区地震落石的发育与其他古地震现象类似,具有多期性和一定的原地复发性。实地调查表明,该区地震落石分布的主要特征为:多集中发育在活动断裂带附近的陡峭基岩斜坡下方,分布零散,且滚动较远,并常与古地震滑坡相伴生。初步获得的8个地震落石钙膜U系测年结果分布在距今6030±300a BP、4720±210a BP、3530±490~3560±280a BP、2010±160a BP、1090±70a BP、760±20a BP和230±20a BP年龄段,与该区古地震探槽和滑坡反映的地震事件比较吻合,进一步揭示玉树断裂带附近在全新世中晚期发生过多期可导致地表产生地震落石的事件。同时也说明,地震落石及其钙膜测年是特别值得进一步探索的潜在古地震研究方法或途径。  相似文献