The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification     

Kaizad F. Patel  Ivan J. Fernandez  Sarah J. Nelson  Stephen A. Norton  Cheryl J. Spencer 《水文研究》2021,35(5):e14147

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.  相似文献   

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药     

时磊  孙艳艳  沈小明  吕爱娟  蔡小虎  刘娇  沈加林 《岩矿测试》2020,39(6):856-865

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。  相似文献   

Hypo‐elastic and hyper‐elastic equations of soils          下载免费PDF全文

Koichi Hashiguchi 《国际地质力学数值与分析法杂志》2018,42(13):1554-1564

  相似文献   

Coupling numerical simulation with remotely sensed information for the study of frozen soil dynamics     

HuiRan Gao  WanChang Zhang 《寒旱区科学》2020,12(6):404-417

The acquisition of spatial-temporal information of frozen soil is fundamental for the study of frozen soil dynamics and its feedback to climate change in cold regions. With advancement of remote sensing and better understanding of frozen soil dynamics, discrimination of freeze and thaw status of surface soil based on passive microwave remote sensing and numerical simulation of frozen soil processes under water and heat transfer principles provides valuable means for regional and global frozen soil dynamic monitoring and systematic spatial-temporal responses to global change. However, as an important data source of frozen soil processes, remotely sensed information has not yet been fully utilized in the numerical simulation of frozen soil processes. Although great progress has been made in remote sensing and frozen soil physics, yet few frozen soil research has been done on the application of remotely sensed information in association with the numerical model for frozen soil process studies. In the present study, a distributed numerical model for frozen soil dynamic studies based on coupled water-heat transferring theory in association with remotely sensed frozen soil datasets was developed. In order to reduce the uncertainty of the simulation, the remotely sensed frozen soil information was used to monitor and modify relevant parameters in the process of model simulation. The remotely sensed information and numerically simulated spatial-temporal frozen soil processes were validated by in-situ field observations in cold regions near the town of Naqu on the East-Central Tibetan Plateau. The results suggest that the overall accuracy of the algorithm for discriminating freeze and thaw status of surface soil based on passive microwave remote sensing was more than 95%. These results provided an accurate initial freeze and thaw status of surface soil for coupling and calibrating the numerical model of this study. The numerically simulated frozen soil processes demonstrated good performance of the distributed numerical model based on the coupled water-heat transferring theory. The relatively larger uncertainties of the numerical model were found in alternating periods between freezing and thawing of surface soil. The average accuracy increased by about 5% after integrating remotely sensed information on the surface soil. The simulation accuracy was significantly improved, especially in transition periods between freezing and thawing of the surface soil.  相似文献   

新疆伊犁地区季节冻土沿海拔的分布规律及其影响因素     

郝建盛  张飞云  黄法融  李兰海 《冰川冻土》2020,42(4):1179-1185

基于2000 - 2014年新疆伊犁地区不同海拔区域观测的冻融期内的冻土、 积雪和气象数据， 应用相关性分析和回归分析方法， 分析该地区季节冻土沿海拔的分布规律， 以及气温、 积雪对季节冻土特征的影响。结果表明： 伊犁地区表层土壤存在着每年11月份开始结冻， 于次年4月份完全融化的周期性变化。每个周期内土壤冻结时长随海拔以4 d·（100m）^-1的趋势增加， 土壤最大冻结深度随海拔以3.9 cm·（100m）^-1的趋势增加。土壤冻结时长与冻结期的平均气温具有显著负相关关系， 相关系数为-0.98（P<0.05）。土壤冻结日数与积雪覆盖历时呈正相关关系， 土壤的最大冻结深度与最大雪深呈负相关关系。随着海拔升高， 温度递减， 导致伊犁地区土壤最大冻结深度和土壤冻结日数整体呈现增加趋势。但在海拔相对较高的地区， 由于相对较厚积雪的影响， 出现土壤最大冻结深度随海拔升高而减小的反常现象。研究结果可为新疆伊犁地区季节冻土的分布对气候变化的响应研究提供支持， 帮助研究区域生态规划和水资源管理， 为农业发展制定适应气候变化对策。  相似文献   

非饱和土中剪切S波的传播特性分析          下载免费PDF全文

柳鸿博  周凤玺 《地震工程学报》2020,42(4):960-966

基于对非饱和多孔介质的研究成果,考虑孔隙中的液相和气相的相互影响,研究非饱和土地基中剪切S波的传播特性。通过非饱和土中固相、液相和气相的质量平衡方程、动量平衡方程和非饱和土有效应力原理,建立问题的弹性波动方程,经过理论推导给出非饱和土中剪切S波的弥散特征方程。通过数值算例分析剪切S波的波速和衰减系数随饱和度、频率和固有渗透系数等因素的变化规律。结果表明,剪切S波的波速几乎不受饱和度的影响,但其随着频率的增大而减小,随着固有渗透系数的增大先不变后增大;剪切S波的衰减系数随着饱和度和频率的增加均增大,而随着固有渗透系数的增大先不变后增大最后减小。  相似文献   

Effects of antecedent moisture and macroporosity on infiltration and water flow in frozen soil     

Freda Pittman  Aaron Mohammed  Edwin Cey 《水文研究》2020,34(3):795-809

Infiltration into frozen soil plays an important role in soil freeze–thaw and snowmelt-driven hydrological processes. To better understand the complex thermal energy and water transport mechanisms involved, the influence of antecedent moisture content and macroporosity on infiltration into frozen soil was investigated. Ponded infiltration experiments on frozen macroporous and non-macroporous soil columns revealed that dry macroporous soil produced infiltration rates reaching 10³ to 10⁴ mm day⁻¹, two to three orders of magnitude larger than dry non-macroporous soil. Results suggest that rapid infiltration and drainage were a result of preferential flow through initially air-filled macropores. Using recorded flow rates and measured macropore characteristics, calculations indicated that a combination of both saturated flow and unsaturated film flow likely occurred within macropores. Under wet conditions, regardless of the presence of macropores, infiltration was restricted by the slow thawing rate of pore ice, producing infiltration rates of 2.8 to 5.0 mm day⁻¹. Reduced preferential flow under wet conditions was attributed to a combination of soil swelling, due to smectite-rich clay (that reduced macropore volume), and pore ice blockage within macropores. In comparison, dry soil column experiments demonstrated that macropores provided conduits for water and thermal energy to bypass the frozen matrix during infiltration, reducing thaw rates compared with non-macroporous soils. Overall, results showed the dominant control of antecedent moisture content on the initiation, timing, and magnitude of infiltration and flow in frozen macroporous soils, as well as the important role of macropore connectivity. The study provides an important data set that can aid the development of hydrological models that consider the interacting effects of soil freeze–thaw and preferential flow on snowmelt partitioning in cold regions.  相似文献   

Fully coupled elastoplastic hydro-mechanical analysis of unsaturated porous media using a meshfree method     

Omid Ghaffaripour  Golnaz A. Esgandani  Arman Khoshghalb  Babak Shahbodaghkhan 《国际地质力学数值与分析法杂志》2019,43(11):1919-1955

This paper presents the first application of an advanced meshfree method, ie, the edge-based smoothed point interpolation method (ESPIM), in simulation of the coupled hydro-mechanical behaviour of unsaturated porous media. In the proposed technique, the problem domain is spatially discretised using a triangular background mesh, and the polynomial point interpolation method combined with a simple node selection scheme is adopted for creating nodal shape functions. Smoothing domains are formed on top of the background mesh, and a constant smoothed strain, created by applying the smoothing operation over the smoothing domains, is assigned to each smoothing domain. The deformation and flow models are developed based on the equilibrium equation of the mixture, and linear momentum and mass balance equations of the fluid phases, respectively. The effective stress approach is followed to account for the coupling between the flow and deformation models. Further coupling among the phases is captured through a hysteretic soil water retention model that evolves with changes in void ratio. An advanced elastoplastic constitutive model within the context of the bounding surface plasticity theory is employed for predicting the nonlinear behaviour of soil skeleton. Time discretisation is performed by adopting a three-point discretisation method with growing time steps to avoid temporal instabilities. A modified Newton-Raphson framework is designed for dealing with nonlinearities of the discretised system of equations. The performance of the numerical model is examined through a number of numerical examples. The state-of-the-art computational scheme developed is useful for simulation of geotechnical engineering problems involving unsaturated soils.  相似文献   

离子类土壤固化剂对高温冻土工程性质改良试验研究   总被引：2，自引：1，他引：1  

张致龙  张建明  张虎  柴明堂 《冰川冻土》2019,41(1):140-146

为了研究离子类土壤固化剂对青藏高原高温冻土工程性质的改良效果，分别选用酸性和碱性离子类土壤固化剂对冻结青藏粉质黏土进行了改良测试。塑性指数测试表明，两种固化剂的最优含量为0.2%。固化剂含量小于0.3%时，冻结温度相对原状土样没有明显的下降。对不同含量碱性和酸性固化土力学性质进行了测试，无侧限单轴抗压强度相对原状土样整体增大，碱性和酸性固化土抗压强度最大分别提高了78.7%和46.6%，最优配比（0.2%）的碱性和酸性固化土体积压缩系数随养护龄期增大而减小，两种固化土的体积压缩系数相对原状土样最大分别下降了80.0%和38.5%，固化效果明显。碱性固化土力学性质变化更显著，说明其更适合对青藏黏土进行改良。  相似文献   

深厚软土场地基岩地震动反演——以天津波为例          下载免费PDF全文

梁建文  张萍  何颖 《世界地震工程》2020,(3):001-11

根据天津波地表加速度记录和相应实测场地钻孔资料，采用等效线性化方法模拟土体非线性，进行了深厚软土场地基岩地震动反演，研究了频率截断对深厚软土场地基岩地震动反演的影响，为天津波地表加速度记录提供了相应的基岩地震动输入。研究表明:不同截断频率情况下，反演得到的基岩地震动峰值和反应谱曲线形状均相差悬殊，但反演后再正演所得到的地面运动与原地表记录相比，加速度时程曲线形状和峰值大小、反应谱曲线形状和峰值大小均非常接近；可根据工程需要对地表加速度记录进行不同频率的截断，反演得到所需强度的基岩地震动。  相似文献