Kamafugitic rocks intruded the Precambrian basement and Phanerozoic sediments at the northeast border of the Paraná basin as part of the Late Cretaceous Goiás alkaline province (GAP). Plutonic complexes dominate the north of the province, whereas lavas and pyroclastic rocks prevail in the south. The central GAP is characterized by kamafugitic diatremes, which may crop out continuously for up to 850 m and consist of a central breccia body, surrounded and overlain by lava flows and crosscut by dykes. The breccias contain some special spheroidal juvenile fragments—namely, accretionary and armored lapilli, frozen droplets, spinning droplets, and wrapped fragments—whose textural and mineralogical aspects are described in detail. Irregularly shaped tuff pockets that occur within the breccias contain textures and structures similar to those of subaerial surge deposits and formed in confined, high gas to solid+liquid ratio domains in the conduit. Diatreme emplacement affected the country rock through thermal metamorphism, development of columnar jointing, and formation of peperite-like mixtures. There is no evidence of phreatomagmatic activity in the diatremes, and CO2, rather than H2O, seems to have been the major volatile component of the kamafugitic magmas. This finding implies that features such as accretionary lapilli and peperites are not exclusively associated with H2O-dominated processes. 相似文献
This paper describes the internal organisation of two diatremes (Águas Emendadas and Neuzinha) and one small breccia-filled conduit (Tigre) in the central portion of the Late Cretaceous Goiás Alkaline Province (GAP), central Brazil, and explores the criteria for facies recognition. The GAP kamafugitic diatremes are emplaced into Carboniferous sandstones of the Aquidauana Formation, at the northern margin of the Paraná Basin. They are usually elliptical structures, not longer than 900 m, filled with breccia and partially covered by thin kamafugitic to basanitic lava flows. The breccias are dominated by juvenile pyroclasts, with subordinate amounts of cognate fragments and xenoliths. In addition to variations in ash and lapilli proportions, juvenile fragment types may be used to discriminate genetic processes and the corresponding pyroclastic deposits.
An extensive field, textural and compositional dataset was analysed by multivariate statistical techniques. Combined with field observations, this allowed us to define a set of facies for kamafugitic diatremes, and, more importantly, to understand the internal structure of the studied bodies and to cross-correlate them. Seven distinct facies were recognised. The Fluidised Conduit Facies (FCF) represents high-energy, strongly fluidised but only moderately fragmented systems. It occurs in a confined environment, and is typical of deeper parts of the conduit, before the actual diatreme level is reached by the ascending fluidised magma. Large amounts of spinning droplets are formed within this region. The Fluidised Conduit–Diatreme Facies (FCDF) is characteristic of intermediate depths in the conduit, where highly fluidised and highly fragmented systems produce large amounts of ash. Spinning droplets decrease in abundance, ordinary juvenile fragments become very common, and xenoliths from the country rock in the immediate vicinity of the diatreme are present. The Fluidised Fragmented Facies (FFF) and the Magmatic Fluidised Facies (MFF) produce very heterogeneous deposits that dominate the shallower part of the system, making up most of the diatreme-filling materials. The Fluidised Fragmented Facies can be distinguished by much higher degrees of fluidisation, fragmentation and system energy. It occupies the internal part of the diatreme and is characterised by the common presence of tuff pockets, tuff fragments, and accretionary and armoured lapilli. The Magmatic Fluidised Facies typically occupies the outer portion of the diatreme and can be distinguished from the Fluidised Fragmented Facies by the dominance of lapilli over ash and by the presence of abundant wrapped fragments. The Magmatic Facies (MF) and the Coherent Magmatic Facies (CMF) are volumetrically subordinate and represent late stages, when less fluidised and less fragmented material, or even coherent magma erupts relatively passively, in the aftermath of the main explosive stage that generated the diatreme. The Border Facies is defined by the increased abundance of material from the immediate country rock. At Águas Emendadas and Neuzinha this facies is marked by the presence of fragments of peperite-like rock, formed by the interaction of the fluidised magma with friable sandstone. 相似文献
Traditional intersatellite communications for shared timing information rely on microwave transceivers such as those in Milstar, AEHF, and Iridium constellations. With extensive space heritage and well-established engineering and performance specifications, these methods have typified the field of high-performance satellite synchronization for decades, recently introduced into active GNSS satellite constellations such as BeiDou. Optical crosslinks, currently investigated as an augmentation or alternative to traditional microwave-based methods, can provide enhanced precision to intersatellite ranging and time transfer, performing beyond one-way or uplink/downlink microwave-based communications. The challenges of time transfer through optical links and crosslinks can significantly impact the systems architecture, optical terminal complexity, and agreements on international standards. Orders-of-magnitude precision enhancement can enable novel timing and ranging technologies allowing for advanced navigation capabilities. Additionally, basic scientific studies with a fleet of synchronized satellites could inform fundamental physics studies on a truly global scale. We evaluate the benefits, drawbacks, and potential applications of satellite synchronization through microwave and optical crosslinks for shared timing and ephemeris data in support of enhanced constellation state estimation and reduced range error. The risks and value associated with these technologies are also discussed with an emphasis on challenges for aerospace.
The Late-Cretaceous Catalão I contains stockworks of thin dykes of phoscorite-series rocks, which can be subdivided into P1 (olivine-bearing, phoscorites) and P2/P3 (olivine-lacking, nelsonites). Dolomite carbonatites (DC) are intimately associated with nelsonites, as pockets and dykes. The P2 apatite nelsonite, the P3 magnetite nelsonite, and, to a lesser extent DC, host the Catalão I niobium mineralization. C–O isotopes signatures in carbonates reveal several distinct magmatic and post-magmatic processes. Limpid carbonates with stable isotopic mantle-like composition show Rayleigh fractionation and are interpreted as primary, while those with brittle-turbid aspect, and higher oxygen isotope composition, probably underwent recrystallization by interaction with H2O-rich fluids. A group of samples shows higher oxygen compositions and lower carbon values, which could be explained by degassing of carbonatite magma during cooling. A degassing pattern, parallel to magmatic degassing but at higher oxygen and lower carbon compositions, observed in carbonate veins, may indicate degassing of fracture filling fluids. Furthermore, C–O isotopes of carbonate from monazite-bearing carbonatite have a positive correlation, indicating a distinct, late-stage carbo-hydrothermal event. Though the Catalão I nelsonites and phoscorites are of igneous origin, they underwent several post-magmatic events, which sometimes overprinted partially or entirely the magmatic isotope signature. 相似文献
This petrologic analysis of the Negra Muerta Volcanic Complex (NMVC) contributes to understanding the magmatic evolution of eruptive centres associated with prominent NW-striking fault zones in the southern Central Andes. Specifically, the geochemical characteristics and magmatic evolution of the two eruptive episodes of this Complex are analysed. The first one occurred as an explosive eruption at 9 Ma and is represented by a strongly welded, fiamme-rich, andesitic to dacitic ignimbrite deposit. The second commenced with an eruption of a rhyolitic ignimbrite at 7.6 Ma followed by effusive discharge of hybrid lavas at 7.3 Ma and by emplacement of andesitic to rhyodacitic dykes and domes. Both explosive and effusive eruptions of the second episode occurred within a short time span, but geochemical interpretations permit consideration of the existence of different magmas interacting in the same magma chamber. Our model involves an andesitic recharge into a partially cooled rhyolitic magma chamber, pressurising the magmatic system and triggering explosive eruption of rhyolitic magma. Chemical or mechanical evidence for interaction between the rhyolitic and andesitic magma in the initial stages are not obvious because of their difference in composition, which could have been strong enough to inhibit the interaction between the two magmas. After the initial explosive stages of the eruption at 7.6 Ma, the magma chamber become more depressurised and the most mafic magma settled in compositional layers by fractional crystallisation. Restricted hybridisation occurred and was effective between adjacent and thermally equivalent layers close to the top of the magma chamber. At 7.3 Ma, increments of caldera formation were accompanied by effusive discharge of hybrid lavas through radially disposed dykes whereby andesitic magma gained in importance toward the end of this effusive episode in the central portion of the caldera. Assimilation during turbulent ascent (ATA) is invoked to explain a conspicuous reversed isotopic signature (87Sr/86Sr and 143Nd/144Nd) in the entire volcanic series. Therefore, the 7.6 to 7.3 Ma volcanic rocks of the NMVC resulted from synchronous and mutually interacting petrological processes such as recharge, fractional crystallization, hybridisation, and Assimilation during Turbulent Ascent (ATA).Geochemical characteristics of both volcanic episodes show diverse type and/or depth in the sources and variable influence of upper crustal processes, and indicate a recurrence in the magma-forming conditions. Similarly, other minor volcanic centres in the transversal volcanic belts of the Central Andes repeated their geochemical signatures throughout the Miocene. 相似文献
The Catalão I alkaline–carbonatite–phoscorite complex contains both fresh rock and residual (weathering-related) niobium mineralization. The fresh rock niobium deposit consists of two plug-shaped orebodies named Mine II and East Area, respectively emplaced in carbonatite and phlogopitite. Together, these orebodies contain 29 Mt at 1.22 wt.% Nb2O5 (measured and indicated). In closer detail, the orebodies consist of dike swarms of pyrochlore-bearing, olivine-free phoscorite-series rocks (nelsonite) that can be either apatite-rich (P2 unit) or magnetite-rich (P3 unit). Dolomite carbonatite (DC) is intimately related with nelsonite. Natropyrochlore and calciopyrochlore are the most abundant niobium phases in the fresh rock deposit. Pyrochlore supergroup chemistry shows a compositional trend from Ca–Na dominant pyrochlores toward Ba-enriched kenopyrochlore in fresh rock and the dominance of Ba-rich kenopyrochlore in the residual deposit. Carbonates associated with Ba-, Sr-enriched pyrochlore show higher δ18OSMOW than expected for carbonates crystallizing from mantle-derived magmas. We interpret both the δ18OSMOW and pyrochlore chemistry variations from the original composition as evidence of interaction with low-temperature fluids which, albeit not responsible for the mineralization, modified its magmatic isotopic features. The origin of the Catalão I niobium deposit is related to carbonatite magmatism but the process that generated such niobium-rich rocks is still undetermined and might be related to crystal accumulation and/or emplacement of a phosphate–iron-oxide magma. 相似文献
