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Hohl Alexander Tang Wenwu Casas Irene Shi Xun Delmelle Eric 《Journal of Geographical Systems》2022,24(3):389-417
Journal of Geographical Systems - We are able to collect vast quantities of spatiotemporal data due to recent technological advances. Exploratory space–time data analysis approaches can... 相似文献
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Mapping collective human activity in an urban environment based on mobile phone data 总被引：1，自引：0，他引：1
Identifying and characterizing variations of human activity – specifically changes in intensity and similarity – in urban environments provide insights into the social component of those eminently complex systems. Using large volumes of user-generated mobile phone data, we derive mobile communication profiles that we use as a proxy for the collective human activity. In this article, geocomputational methods and geovisual analytics such as self-organizing maps (SOM) are used to explore the variations of these profiles, and its implications for collective human activity. We evaluate the merits of SOM as a cross-dimensional clustering technique and derived temporal trajectories of variations within the mobile communication profiles. The trajectories’ characteristics such as length are discussed, suggesting spatial variations in intensity and similarity in collective human activity. Trajectories are linked back to the geographic space to map the spatial and temporal variation of trajectory characteristics. Different trajectory lengths suggest that mobile phone activity is correlated with the spatial configuration of the city, and so at different times of the day. Our approach contributes to the understanding of the space-time social dynamics within urban environments. 相似文献
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Surface area, porosity and water adsorption properties of fine volcanic ash particles 总被引：1，自引：1，他引：0
Our understanding on how ash particles in volcanic plumes react with coexisting gases and aerosols is still rudimentary, despite the importance of these reactions in influencing the chemistry and dynamics of a plume. In this study, six samples of fine ash (<100 m) from different volcanoes were measured for their specific surface area, as, porosity and water adsorption properties with the aim to provide insights into the capacity of silicate ash particles to react with gases, including water vapour. To do so, we performed high-resolution nitrogen and water vapour adsorption/desorption experiments at 77 K and 303 K, respectively. The nitrogen data indicated as values in the range 1.1–2.1 m2/g, except in one case where a as of 10 m2/g was measured. This high value is attributed to incorporation of hydrothermal phases, such as clay minerals, in the ash surface composition. The data also revealed that the ash samples are essentially non-porous, or have a porosity dominated by macropores with widths >500 Å. All the specimens had similar pore size distributions, with a small peak centered around 50 Å. These findings suggest that fine ash particles have relatively undifferentiated surface textures, irrespective of the chemical composition and eruption type. Adsorption isotherms for water vapour revealed that the capacity of the ash samples for water adsorption is systematically larger than predicted from the nitrogen adsorption as values. Enhanced reactivity of the ash surface towards water may result from (i) hydration of bulk ash constituents; (ii) hydration of surface compounds; and/or (iii) hydroxylation of the surface of the ash. The later mechanism may lead to irreversible retention of water. Based on these experiments, we predict that volcanic ash is covered by a complete monolayer of water under ambient atmospheric conditions. In addition, capillary condensation within ash pores should allow for deposition of condensed water on to ash particles before water reaches saturation in the plume. The total mass of water vapour retained by 1 g of fine ash at 0.95 relative water vapour pressure is calculated to be ~10–2 g. Some volcanic implications of this study are discussed.Editorial responsibility: J. Gilbert 相似文献
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The crater lake of Kawah Ijen volcano contains extremely low pH (<0.4) waters with high SO4 (70000 mg/kg), Cl (21000 mg/kg), F (1500 mg/kg), Al (5000 mg/kg), Fe (2000 mg/kg) and trace metal (Cu 0.5, Zn 4, Pb 3 mg/kg) contents. These brines seep outward through the western crater rim and reappear on the other side as streamlets, which form the headwaters of the Banyupahit stream. The Banyupahit first mixes with fresh rivers and thermal springs in the Ijen caldera and then irrigates a coastal agricultural plain which is 30 km from the summit crater.We discuss the downstream composition changes affecting the Banyupahit waters by using stable isotope, chemical and mineralogical data collected from sites along the stream length. The saturation of the stream waters with respect to minerals was evaluated with SOLVEQ and WATEQ4F and compared with the geochemical observations. An aluminous mineralogy (alunogen, pickeringite, tamarugite and kalinite) develops in the upper part of the Banyupahit due to concentration of the headwaters by evaporation. Downstream attenuation of dissolved element concentrations results principally from dilution and from mineral precipitation. The stream pH changes from 0 at the source to >4 close to the mouth. The δD and δ18O values and the relative SO4–Cl–F contents of the Banyupahit waters indicate that the tributaries are mostly meteoric. Dissolved SO4 in the acidic stream come only from the crater lake seepages and are not involved later in microbially mediated reactions, as shown by their δ34S and δ18O values. Re-equilibration of the stream SO4 oxygen-isotope composition with H2O from tributaries does not occur.Calcium, SiO2, Al, Fe, K and SO4 behave non-conservatively in the stream waters. Gypsum, silica (amorphous or poorly ordered), a basic aluminum hydroxysulfate (basaluminite?), K-jarosite and amorphous ferric hydroxide may exert a solubility control on these elements along the entire stream length, or in certain stream sections, consistent with the thermochemical model results. Downstream concentration trends and mineral saturation levels suggest that precipitation of Sr-, Pb-rich barite and celestite consume Ba, Sr and Pb, whereas dissolved Cu, Pb and Zn may adsorb onto solid particles, especially after the junctions of the acidic stream with non-acidic rivers. We calculated that significant fluxes of SO4, F, Cl, Al, SiO2, Ti, Mn and Cu may reach the irrigation system, possibly causing serious environmental impacts such as soil acidification and induration. 相似文献
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The crater lake water from Maly Semiachik volcano in Kamchatka was used for the international analytical laboratory comparison of major and minor elements, and hydrogen, sulfur, and oxygen isotope data. Eight institutions participated in this program, giving analytical results of 9 major and 20 minor elements mainly by using ICP-AES for cations and IC for anions. Among the major elements, Na, Mg and Si showed coefficients of variation (CV) of 10% or more, whereas B, Al, Fe, Mn had coefficients less than 7%. The CV% of the minor elements Co, Cu, P, Cr, Pb was much greater (>30%) while the V analyses agreed well (<10%). Ti, Sr, Zn, and F were intermediate (between 10 and 20 CV%). The errors observed for these constituents are inherent to the methods applied: large dilutions and spectrometric interferences. Even the major anions such as Cl (>2000 ppm) and SO4 (>5000 ppm) gave considerable ranges (5.1 and 8.8 CV%, respectively) as did the obtained pH values (22 CV%). The measured δ18O of the water samples and δ34S of sulfate are in excellent agreement but the δD values had CV% of 8. Technical recommendations are presented to improve the analytical results for these elements with significant deviations from the mean values. 相似文献
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Eric Delmelle Michael R. Desjardins Jing Deng 《International journal of geographical information science》2017,31(12):2505-2523
Natural habitats continue to dwindle due to a variety of natural and human-induced stressors. In response, sufficient land must be set aside for conservation to preserve long-term biodiversity. In this paper, we propose a bi-objective optimization model to form spatially cohesive nature reserves by minimizing the distance from habitat patches to the center of their reserve, while simultaneously maximizing the ecological condition of the patches set aside for preservation. Our model can accommodate multiple reserves which, combined with a minimum separation distance requirement, enforces backup coverage to mitigate the possible effects of natural and anthropogenic stressors. The model fully capitalizes on GIS functionalities to extract information on spatial relationships and visualize optimization results. Given the complexity of the separation constraint, we propose a genetic algorithm (GA) and a two-phase heuristic where the GA solves the selection of the reserves, while a solver attempts to optimize the allocation of patches to the selected reserves. The behavior of our model and its sensitivity to the parameters are illustrated on a simulated data set, while its real-world problem-solving capabilities are demonstrated on a case study in New Hampshire. Our model provides an alternative modeling tool for conservation planning, particularly when backup reserves are desired. 相似文献
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In this article, we investigate the factors that lead to changes in the socioeconomic complexion of urban neighborhoods along four critical dimensions: crime, youth social distress, home ownership, and economic conditions. We argue that the dynamics of these dimensions are better apprehended simultaneously considering their potential mutual relationships and we propose a cross-lagged panel model approach within a structural equation modeling framework. Neighborhoods in Charlotte, North Carolina, are used as a case study, and change is modeled at several time lags throughout the 2000–2010 decade. Findings indicate that the model performs well and that it offers a very promising avenue for modeling the socioeconomic changes of neighborhoods that accounts for complex longitudinal effects as well as spatial dependencies. Specifically, it shows that lower human capital manifested by a decline in youth indicators is significant in explaining subsequent increases in crime and declines in economic indicators. Also, the predominance of housing stock constructed in the 1950s and 1960s is a significant trigger of declines across all neighborhood indicators. Finally, spatial spillover effects between neighborhoods are found to be short-lived and dissipate after a few years. 相似文献
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