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1.
A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established. 相似文献
2.
Esther Salazar Dorit Hammerling Xia Wang Bruno Sansó Andrew O. Finley Linda O. Mearns 《Climatic change》2016,138(1-2):55-69
We consider the problem of projecting future climate from ensembles of regional climate model (RCM) simulations using results from the North American Regional Climate Change Assessment Program (NARCCAP). To this end, we develop a hierarchical Bayesian space-time model that quantifies the discrepancies between different members of an ensemble of RCMs corresponding to present day conditions, and observational records. Discrepancies are then propagated into the future to obtain high resolution blended projections of 21st century climate. In addition to blended projections, the proposed method provides location-dependent comparisons between the different simulations by estimating the different modes of spatial variability, and using the climate model-specific coefficients of the spatial factors for comparisons. The approach has the flexibility to provide projections at customizable scales of potential interest to stakeholders while accounting for the uncertainties associated with projections at these scales based on a comprehensive statistical framework. We demonstrate the methodology with simulations from the Weather Research & Forecasting regional model (WRF) using three different boundary conditions. We use simulations for two time periods: current climate conditions, covering 1971 to 2000, and future climate conditions under the Special Report on Emissions Scenarios (SRES) A2 emissions scenario, covering 2041 to 2070. We investigate and project yearly mean summer and winter temperatures for a domain in the South West of the United States. 相似文献
3.
Simona Avnaim‐Katav Ahuva Almogi‐Labin Amir Sandler Dorit Sivan Naomi Porat Ari Matmon 《第四纪科学杂志》2012,27(7):675-686
The current detailed chronostratigraphic framework of the last 1 Ma of an eastern Mediterranean sequence (Haifa Bay, Israel) aims to examine the relative roles of sea‐level changes, climate and tectonics. Seven continuous marine cores, up to ～120 m long, were recovered from shallow water depths. The cores were dated by optically stimulated luminescence, 14C, magnetostratigraphy, 230Th/234U, 26Al/10Be, occurrence of index fossils and correlated to the global sea‐level curve and Marine Isotope Stages (MIS). The sedimentary sequence accumulated during the last ca. 1.0 Ma consists of 21 transgression–regression units with hiatuses between them. Five marine/terrestrial cycles, which occur in the lower part of the sequence, are attributed to the Jaramillo subchron and the Brunhes–Matuyama boundary, and correspond to MIS 29–21. The top ～50 m includes three sedimentary cycles deposited in the last ca. 400 ka. The regressive phases during this interval correspond to Glacial MIS 8, 6 and 2, while the transgressions correspond to Interglacial MIS 11, 7, 5 and 1. Thus, for the first time, this study documents the longest Quaternary succession dated so far in a key area of the Levant, sensitive to global history of sea‐level changes and glacial/interglacial fluctuations. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
4.
Acquisition and registration of terrestrial 3D laser scans is a fundamental task in mapping and modeling of cities in three dimensions. To automate this task marker-free registration methods are required. Based on the existence of skyline features, this paper proposes a novel method. The skyline features are extracted from panoramic 3D scans and encoded as strings enabling the use of string matching for merging the scans. Initial results of the proposed method in the old city center of Bremen are pre-sented. 相似文献
5.
Ines Hoog Subir K. Mitra Karoline Diehl Stephan Borrmann 《Journal of Atmospheric Chemistry》2007,57(1):73-84
In laboratory experiments the interactions of ammonia with ice crystals were studied within the temperature range between
0 and −20°C. In a first series of experiments dendritic ice crystals were grown from water vapor in presence of ammonia gas
in various concentrations between 4 and 400 ppbv. In a second series of experiments pure ice crystals were exposed to a humidified
ammonia–air mixture inside a horizontal flow tube. The influence of temperature, ammonia gas concentration (0.6, 1.5, and
10 ppmv), exposure time, and the presence of impurities such as sulfate on the ammonia uptake by the ice surface was investigated
by determining the ammonium content in the melt water of the ice crystals by ion chromatography. During the growth of ice
crystals significant amounts of ammonia (around 200 μg/l) were taken up even at small gas concentrations. In contrast, even
at high gas concentrations the uptake of ammonia by non-growing ice crystals was lower by approximately one order of magnitude.
The presence of sulfate on the ice surface affected an enhanced uptake of ammonia by a factor of 5–10. A model is presented
which describes the uptake of ammonia by ice considering the chemical processes occurring in the ice surface layer and simultaneous
diffusion of ammonia into bulk ice. Even the increased uptake of ammonia by growing ice is rather small compared to the uptake
by water droplets; thus, the major process for scavenging of ammonia from the atmosphere via the ice phase might not be the
direct uptake by ice crystals but the riming involving super-cooled droplets containing ammonia. 相似文献
6.
The coast at Caesarea, Israel, has been inhabited almost continuously for the last 2,400 years, and the archeological sites are today a major international tourist attraction. Because the sites straddle the shoreline, they are subject to constant damage by wave action, and must therefore be frequently restored. In this paper, local shoreline migrations over the last 200 years are investigated with the aim of distinguishing between natural and man-made coastal changes. In order to assess these changes accurately, geomorphological and sedimentological data were examined based on detailed beach profile measurements, bathymetric surveys, and grain-size analyses. In addition, series of old aerial photographs, as well as historical topographic maps and nautical charts were consulted. The results show that shoreline changes can be grouped into two main time periods. During the first period from 1862 to 1949 before the expansion of modern settlements, the position of the shoreline changed irregularly by up to 30 m. In the second period from 1949 onward, numerous coastal structures have been erected, and various coastal modifications have been carried out. The evaluation of the data suggests that human interventions have had relatively little effect on the overall position of the shoreline, as displacements ranged only from 5 to 18 m. Thus, coastal changes at Caesarea are predominantly due to natural wave action reflected in the heterogeneous geomorphological and sedimentological characteristics of the shore. This contradicts the common assumption that human activities are always mainly responsible for large-scale shoreline modifications in the region. It is concluded that, in order to implement meaningful mitigating countermeasures, coastal archeological sites need to be individually assessed with respect to the dominant factors causing local coastal change. 相似文献
7.
Nadine v. Blohn Karoline Diehl Anke Nölscher Alexander Jost Subir K. Mitra Stephan Borrmann 《Journal of Atmospheric Chemistry》2013,70(2):131-150
Laboratory experiments were carried out in the Mainz vertical wind tunnel to determine the retention of the trace gases ammonia and sulfur dioxide dissolved in supercooled cloud droplets during riming. The conditions during riming were similar to the ones in atmospheric mixed phase clouds: temperatures from ?18 °C to ?5 °C, liquid water contents between 1 and 1.5 g m?3, liquid drop radii between 10 and 20 μm, liquid phase concentrations from 1 to 22 mg/l. As collectors, floating ice particles and snow flakes with diameters between 6 mm and 1.5 cm were used. After riming the retention coefficients, i.e. the fractions of the species which remained in the ice phase after freezing were determined. Retention coefficients lying between 0.1 and 1.0 were measured depending on the solubility and dissociation of the trace gas, liquid phase concentration, ambient air temperature, and shape of rimed collector. This can be explained from the chemists’ point of view by the effective Henry’s law constant of the species and physically with the rate of latent heat removal from the rimed collector during freezing. Parameterizations derived from the different experimental cases describe the retention coefficients as a function of temperature. In general, an average retention of ammonia of 92?±?21 % was determined independently of liquid phase concentration while mean values for sulfur dioxide were 53?±?10 % at low liquid phase concentrations and 29?±?7 % at high liquid phase concentrations. 相似文献
8.
W. Wobrock D. Schell R. Maser W. Jaeschke H. -W. Georgii W. Wieprecht B. G. Arends J. J. Mols G. P. A. Kos S. Fuzzi M. C. Facchini G. Orsi A. Berner I. Solly C. Kruisz I. B. Svenningsson A. Wiedensohler H. -C. Hansson J. A. Ogren K. J. Noone A. Hallberg S. Pahl T. Schneider P. Winkler W. Winiwarter R. N. Colvile T. W. Choularton A. I. Flossmann S. Borrmann 《Journal of Atmospheric Chemistry》1994,19(1-2):3-35
9.
Frank Drewnick Johannes Schneider Silke S. Hings Nele Hock Kevin Noone Admir Targino Silke Weimer Stephan Borrmann 《Journal of Atmospheric Chemistry》2007,56(1):1-20
The Aerodyne aerosol mass spectrometer (Q-AMS) was coupled with a counterflow virtual impactor (CVI) for the first time to measure cloud droplet residuals of warm tropospheric clouds on Mt. Åreskutan in central Sweden in July 2003. Operating the CVI in different operational modes generated mass concentration and species-resolved mass distribution data for non-refractory species of the ambient, interstitial, and residual aerosol. The ambient aerosol measurements revealed that the aerosol at the site was mainly influenced by long-range transport and regional photochemical generation of nitrate and organic aerosol components. Four different major air masses were identified for the time interval of the experiment. While two air masses that approached the site from northeastern Europe via Finland showed very similar aerosol composition, the other two air masses from polar regions and the British Islands had a significantly different composition. During cloud events the larger aerosol particles were found to be activated into cloud droplets. On a mass basis the activation cut-off diameter was approximately 150 nm for nitrate and organics dominated particles and 200 nm for sulfate dominated particles. Generally nitrate and organics were found to be activated into cloud droplets with higher efficiency than sulfate. While a significant fraction of the nitrate in ambient particles was organic nitrates or nitrogen-containing organic species, the nitrate found in the cloud droplet residuals was mainly ammonium nitrate. After passage of clouds the ambient aerosol size distribution had shifted to smaller particle sizes due to the predominantly activation of larger aerosol particles without a significant change in the relative composition of the ambient aerosol. 相似文献
10.
L. Stefanutti A. R. MacKenzie V. Santacesaria A. Adriani Stefano Balestri S. Borrmann V. Khattatov P. Mazzinghi V. Mitev V. Rudakov C. Schiller G. Toci C. M. Volk V. Yushkov H. Flentje C. Kiemle G. Redaelli K. S. Carslaw K. Noone Th. Peter 《Journal of Atmospheric Chemistry》2004,48(1):1-33
The APE-THESEO campaign was held from 15 February to 15 March 1999 from the Seychelles in the western Indian Ocean. APE-THESEO stands for Airborne Platform for Earth observation — (contribution to) the Third European Stratospheric Experiment on Ozone. The campaign aimed to study processes controlling the low water content of the stratosphere, including the mechanisms of cloud formation in the tropical tropopause region, and transport processes, studied using measurements of long-lived trace gases and ozone.Two aircraft were used: the high-altitude research aircraft, M-55 Geophysica, which can fly up to 21 km, and the Falcon of the Deutsches Zentrum für Luft- und Raumfahrt, a tropospheric aircraft. Seven flights were performed, including the first simultaneous in situ and remote sensing of sub-visible cirrus clouds, the first interception of sub-visible cirrus using in-flight guidance from a path-finding aircraft, and guided descent of a high-altitude research aircraft into the anvil cloud at the top of a tropical cyclone. In this paper we describe the payload used, the objectives for each flight, and the meteorological conditions encountered. First results show that a new type of cloud, which we have dubbed ultra-thin tropical tropopause cloud (UTTC), has been observed frequently, and observed to cover areas of 105 km2. The frequent coincidence of the tropopause and hygropause implies that the western Indian Ocean played an important role in the dehydration of the lower tropical stratosphere during the season of the mission. UTTCs, sub-visible cirrus, and visible cirrus, have all been implicated in the observed dehydration. Tracer measurements indicate little mixing of stratospheric air into the upper tropical troposphere. 相似文献