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1.
In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in our area of study, were centred on variable parameters (Eh, O2(d), pH, Conductivity, T°), major elements (SO4, NO3) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological) of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of adsorption on the iron and manganese hydroxides.  相似文献   
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The Azraq basin (the Badia region in NE-Jordan) is rich in its industrial rocks and minerals. Most of the commodities are concentrated in one area, which is the Azraq depression (El-Qa’). The climatic changes (wet and dry) of Azraq closed lake contributed in the formation of industrial rocks and minerals in the El-Qa’. Basalt, pyroclastics, zeolites, diatomaceous earth, bentonite, palgorskite, porcelanite, saline brines, chalk, limestone, and gypsum are the potential industrial commodities. The basaltic rocks are of high alkalis content and good homogeneity and are of good potential use in constructions and cast basalt. The scoriaceous pyroclastic material proved to be of excellent properties for use as lightweight aggregates, cultivation purposes, and for the production of pozzolanic cement. Smectite-rich beds (bentonite) from Ein El Badia could be used as binder, absorbent, and additives for feeding farm animals. Palygorskite is potential for use in drilling mud, paint, pharmaceuticals, and as a filtering medium. The diatomaceous earth deposits are Moler type and could be used as filter aid and absorbent. Zeolites are efficient for agricultural purposes, animal waste, and wastewater treatment plants. Saline brine is exploited in the Azraq mudflat area for table salt. Porcelanite could be used as an absorbent of hazardous elements, abrasive, and filler. The softness and high purity of chalk enable its use as filler and in the lime production. The large limestone concretions are of high quality for use as a building stone. Gypsum (gypcrete) could be used after the removal of the undesired chert impurities. The Badia region is a highly potential area for future exploration and mining industry in a manner that achieves the required outcomes and minimizes impacts on ecosystems.  相似文献   
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In north-eastern Algeria, the Seybouse River is an important source of water used mainly for irrigation of large agricultural areas extending from the Guelma region to Annaba city. Industrial activities in this region contribute substantial water pollution to the river and the groundwater. Based on the different sources of pollution, mapping of areas vulnerable to groundwater pollution has been accomplished by combining land use and data on groundwater levels. The resulting maps show that the most vulnerable areas are those with large industrial activities—in Meboudja, Bouchegouf and Guelma. Infiltration and runoff contribute to pollution, and the highest infiltration rate is generally observed in areas of agricultural and industrial activities. Pollution of the aquifers in this area is of concern. Mountains, such as the Edough and Gelaat Bou Sbaa, contribute high runoff that carries pollutants towards the groundwater.  相似文献   
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We investigate the late Quaternary active deformation along the Jordan Valley segment of the left-lateral Dead Sea Fault and provide new insights on the behaviour of major continental faults. The 110-km-long fault segment shows systematic offsets of drainage systems surveyed at three sites along its southern section. The isotopic dating of six paleoclimatic events yields a precise chronology for the onset of six generations of gully incisions at 47.5 ka BP, 37.5 ka BP, 13 ka BP, 9 ka BP, 7 ka BP, and 5 ka BP. Additionally, detailed mapping and reconstructions provide cumulative displacements for 20 dated incisions along the fault trace. The individual amounts of cumulative slip consistently fall into six distinct classes. This yields: i) an average constant slip rate of 4.7 to 5.1 mm/yr for the last 47.5 kyr and ii) a variable slip rate ranging from 3.5 mm/yr to 11 mm/yr over 2-kyr- to 24-kyr-long intervals. Taking into account that the last large earthquake occurred in AD 1033, we infer 3.5 to 5 m of present-day slip deficit which corresponds to a Mw  7.4 earthquake along the Jordan Valley fault segment. The timing of cumulative offsets reveals slip rate variations critical to our understanding of the slip deficit and seismic cycle along major continental faults.  相似文献   
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The groundwater flow in a fissured chalky environment at the northern border of the Paris Basin depends on several geological and hydrogeological parameters. Although the studied sector of the basin presents a homogeneous rock type, it is affected by a fracture network. In this type of environment, in which the permeability is low, the groundwater flow displays significant disruption, which is localized in the Fruges region (northern France). The interconnection of the discontinuities (network of fault and/or joints) is reliant on the structural control of groundwater flow through increases in the hydraulic connection between the unsaturated and the saturated zone. The methodology developed herein makes use of microstructural and regional analysis of the fracture patterns, and allowed consideration of the piezometric variations of the chalk aquifer during periods of low and high groundwater levels (April and October 2001) and a diagraphic representation of the estimated physical parameters (electrical resistivity). This enabled us to construct a ‘flow structure’ conceptual model in which we identify two types of faults: tight walls and flow paths that control the piezometric heads and the flow rate. Model validation was carried out on a similar sector. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
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Characterization of zeolitic tuff from Jabal Hannoun (HN) and Mukawir (MR) was carried out to examine the ability of using low-cost natural materials in domestic wastewater treatment. The grain size between 0.3 and 1 mm (0.3–1 mm) of the HN and MR has the highest total zeolite grade (faujasite–phillipsite and phillipsite–chabazite) and suitable cation exchange capacity. They were used as fixed-bed ion exchangers and adsorbents. The zeolitic tuff efficiently removed the organic and nitrogen compounds, Pb and Zn from the effluent. One bed volume (1 BV) of the zeolitic tuff is capable to remove up to 95 % of total organic carbon form 500 BV of the effluent. The removal percent of total nitrogen by HN and MR is close to 95 and 90 %, respectively. The zeolitic tuff has an excellent efficiency to remove Pb and Zn from the effluent. 1 BV of HN completely cleans Zn and Pb from 680 and 730 BV of the effluent, respectively, whereas 1 BV of MR is able to clean completely Zn and Pb from 500 and 685 BV of the effluent, respectively. The greater performance of the HN compared with the MR may be explained by its higher zeolites grade and presence of faujasite.  相似文献   
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Given that water resources are scarce and are strained by competing demands, it has become crucial to develop and improve techniques to observe the temporal and spatial variations in the inland water volume. Due to the lack of data and the heterogeneity of water level stations, remote sensing, and especially altimetry from space, appear as complementary techniques for water level monitoring. In addition to spatial resolution and sampling rates in space or time, one of the most relevant criteria for satellite altimetry on inland water is the accuracy of the elevation data. Here, the accuracy of ICESat LIDAR altimetry product is assessed over the Great Lakes in North America. The accuracy assessment method used in this paper emphasizes on autocorrelation in high temporal frequency ICESat measurements. It also considers uncertainties resulting from both in situ lake level reference data. A probabilistic upscaling process was developed. This process is based on several successive ICESat shots averaged in a spatial transect accounting for autocorrelation between successive shots. The method also applies pre-processing of the ICESat data with saturation correction of ICESat waveforms, spatial filtering to avoid measurement disturbance from the land–water transition effects on waveform saturation and data selection to avoid trends in water elevations across space. Initially this paper analyzes 237 collected ICESat transects, consistent with the available hydrometric ground stations for four of the Great Lakes. By adapting a geostatistical framework, a high frequency autocorrelation between successive shot elevation values was observed and then modeled for 45% of the 237 transects. The modeled autocorrelation was therefore used to estimate water elevations at the transect scale and the resulting uncertainty for the 117 transects without trend. This uncertainty was 8 times greater than the usual computed uncertainty, when no temporal correlation is taken into account. This temporal correlation, corresponding to approximately 11 consecutive ICESat shots, could be linked to low transmitted ICESat GLAS energy and to poor weather conditions. Assuming Gaussian uncertainties for both reference data and ICESat data upscaled at the transect scale, we derived GLAS deviations statistics by averaging the results at station and lake scales. An overall bias of −4.6 cm (underestimation) and an overall standard deviation of 11.6 cm were computed for all lakes. Results demonstrated the relevance of taking autocorrelation into account in satellite data uncertainty assesment.  相似文献   
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The continuous increase of industrial activities in the area of Berrahal (northeast of Algeria) resulted in an increase of waste disposal, inducing environmental pollution and contamination of groundwater. Available data on groundwater contamination were used to develop a statistical study for contaminated regions and to identify exposure scenarios of pollution. Chemical analysis of the samples shows that water of most wells and drillings is in bad quality or not drinkable, whereas statistical processing of these data by principal component analysis and discriminant factorial analysis suggests that wastewater coming from companies of the industrial park of Berrahal is very rich in organic pollutants (high percentages of BOD5 and NO2 ?) and has high mineralization (has strong concentration in major elements and high electric conductivity); these constitute the main factors of the deterioration of the quality of this water. The considered exposure pathways were drinking water exploited from wells and drillings implanted in this area and its contact with soil (ingestion and dermal contact) that could threaten either humans or wildlife, on site or off site. In addition, groundwater was considered to be a potential risk pathway, especially for the ecosystem of Lake Fetzara and for the aquiferous system.  相似文献   
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