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Sabine Geiß Nicole Lettmann Aurélien Rey Herbert Lepper Birgit Körner Silvio Mais Theodor Prey Bettina Hilger Moana Engelke Stephan Lebertz Claudine Chatellier George Sawal Dirk Löffler Tom Schillings 《洁净——土壤、空气、水》2011,39(6):537-542
A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C10–C13 and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010. 相似文献
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Jordan G. Hamilton Jay Grosskleg David Hilger Kris Bradshaw Trevor Carlson Steven D. Siciliano Derek Peak 《Geochemical transactions》2018,19(1):1
Adsorption and precipitation reactions often dictate the availability of phosphorus in soil environments. Tripolyphosphate (TPP) is considered a form of slow release P fertilizer in P limited soils, however, investigations of the chemical fate of TPP in soils are limited. It has been proposed that TPP rapidly hydrolyzes in the soil solution before adsorbing or precipitating with soil surfaces, but in model systems, TPP also adsorbs rapidly onto mineral surfaces. To study the adsorption behavior of TPP in calcareous soils, a short-term (48 h) TPP spike was performed under laboratory conditions. To determine the fate of TPP under field conditions, two different liquid TPP amendments were applied to a P limited subsurface field site via an in-ground injection system. Phosphorus speciation was assessed using X-ray absorption spectroscopy, total and labile extractable P, and X-ray diffraction. Adsorption of TPP to soil mineral surfaces was rapid (< 48 h) and persisted without fully hydrolyzing to ortho-P. Linear combination fitting of XAS data indicated that the distribution of adsorbed P was highest (~ 30–40%) throughout the site after the first TPP amendment application (high water volume and low TPP concentrations). In contrast, lower water volumes with more concentrated TPP resulted in lower relative fractions of adsorbed P (15–25%), but a significant increase in total P concentrations (~ 3000 mg P kg soil) and adsorbed P (60%) directly adjacent to the injection system. This demonstrates that TPP application increases the adsorbed P fraction of calcareous soils through rapid adsorption reactions with soil mineral surfaces. 相似文献
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Why do people not learn from flood disasters? Evidence from Vietnam’s northwestern mountains 总被引：4，自引：2，他引：2
Iven Schad Petra Schmitter Camille Saint-Macary Andreas Neef Marc Lamers La Nguyen Thomas Hilger Volker Hoffmann 《Natural Hazards》2012,62(2):221-241
This article explores how the causes and impacts of a flood event as perceived by local people shape immediate responses and future mitigation efforts in mountainous northwest Vietnam. Local flood perception is contrasted with scientific perspectives to determine whether a singular flood event will trigger adjustments in mitigation strategies in an otherwise rarely flood-affected area. We present findings from interdisciplinary research drawing on both socioeconomic and biophysical data. Evidence suggests that individual farmers?? willingness to engage in flood mitigation is curbed by the common perception that flooding is caused by the interplay of a bundle of external factors, with climatic factors and water management failures being the most prominent ones. Most farmers did not link the severity of flooding to existing land use systems, thus underlining the lack of a sense of personal responsibility among farmers for flood mitigation measures. We conclude that local governments cannot depend on there being a sufficient degree of intrinsic motivation among farmers to make them implement soil conservation techniques to mitigate future flooding. Policy makers will need to design measures to raise farmers?? awareness of the complex interplay between land use and hydrology and to enhance collective action in soil conservation by providing appropriate incentives and implementing coherent long-term strategies. 相似文献
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Influence of glacier advance on the development of the multipart Riffeltal rock glacier,Central Austrian Alps 
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下载免费PDF全文 Jana‐Marie Dusik Matthias Leopold Tobias Heckmann Florian Haas Ludwig Hilger David Morche Fabian Neugirg Michael Becht 《地球表面变化过程与地形》2015,40(7):965-980
The multipart Riffeltal rock glacier, located in a tributary valley of the Kaunertal, Tyrol, Austria is investigated to enlarge the knowledge about spatial and temporal development of rock glaciers in and at the margins of pro‐glacial areas and to get a better understanding of glacier–rock glacier interactions. The subject of interest consists of a complex system of two adjacent rock glacier tongues and various superposed lobes with differing ages, origin and root zones, and therefore diverse development. To determine the reasons for their diverging development, the internal structure and permafrost occurrence on and in the surrounding area of the rock glacier were studied by application of geomorphological mapping, geophysical methods and measurement of the basal temperature of the winter snow cover (BTS). Permafrost modelling was performed on the basis of BTS data and land surface parameters derived from a high resolution airborne laser scanning (ALS) digital elevation model (DEM). Additionally, the ALS data were used to measure vertical and horizontal changes of the rock glacier surface between 2006 and 2012. Glacier–rock glacier interactions during and since the Little Ice Age (LIA) are evident for the development of the studied rock glacier. A geomorphic map gives important information about the connection between glacial advance or retreat and permafrost or ground ice occurrence. The combination of all information helps in the analysis of diverse kinematic action of neighbouring rock glacier tongues. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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