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1.
Lithium concentrations and isotopic compositions of olivine and 87Sr/86Sr and 143Nd/144Nd of coexisting clinopyroxene from peridotite xenoliths from the Quaternary Labait volcano, Tanzania, document the influence of rift-related metasomatism on the ancient cratonic mantle. Olivines show negative correlations between Fo content and both δ7Li and Li concentrations. Olivines in iron-rich peridotites (Fo85–87) have high Li concentrations (3.2–4.8 ppm) and heavy δ7Li (+5.2 to +6.6). In contrast, olivines in ancient, refractory peridotites have lower Li concentrations (∼2 ppm) and relatively light δ7Li (+2.6 to +3.5). This reflects mixing between ancient, refractory cratonic lithosphere and asthenosphere-derived rift magmas. A uniquely fertile, deformed, high-temperature garnet lherzolite, interpreted to be from the base of the lithosphere, has a 87Sr/86Sr of 0.7029 and 143Nd/144Nd of 0.51286, similar to HIMU oceanic basalts. It provides the best estimate of the Sr–Nd isotope composition of the upwelling mantle (i.e., plume, sensu lato) underlying this portion of the East African Rift, and is slightly less radiogenic compared to previous estimates of the plume that were based on rift basalts. Although elevated δ7Li are not exclusive to HIMU source regions, the data collectively indicate that the plume beneath Labait has HIMU characteristics in Sr, Nd and Li isotope composition. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
2.
The architecture of macrofaunal burrows and the total area of the sediment-water interface created by biogenic structure were investigated in the Donggeomdo tidal flat on the west coast of Korea. Resin casting methods were applied to recover burrows of four dominant species, Macrophthalmus japonicus, Cleistostoma dilatatum, Perinereis aibuhitensis, and Periserrula leucophryna, and whole burrows within the casting area at three sites in different tidal levels.P. leucophryna excavated the largest burrow in terms of a surface area among them. In the case of whole burrow casting, the space occupied by the biogenic structure was extended into deeper and expanded more greatly at the higher tidal level. In the uppermost flat, the burrow wall surface area within sediment was more extensive than the sediment surface area. Increased oxygen supply through the extended interface could enhance the degradation rates of organic carbon and also change the pathways of degradation. Quantifying the relationship between the extended interface and mineralization rate and pathway requires more extensive study.  相似文献   
3.
A study was conducted to determine polycyclic aromatic hydrocarbons (PAHs) distribution and microbial population changes in brackish sediments from an Italian lagoon included in the Ramsar List of Wetlands of International Importance. The presence and level of PAH-degrading bacteria were estimated by the most probable number (MPN) enumeration technique, whereas degradation capability towards target compounds was checked against loss of spiked PAHs (Phenanthrene, Anthracene and Fluoranthene) in MPN tubes after incubation in optimal conditions. Chemical analyses and microbiological counts suggested a potential for PAHs biodegradation by natural occurring populations of sediment microorganisms, thus indicating an "optimal range" in sediment PAHs concentrations, outside of which the natural selection of the indigenous microflora did not occur. The MPN procedure here described, provided an effective and reliable way to simultaneously determine microbial population densities and subsequent confirmation of the biodegradation capability of sediment indigenous microflora when exposed to laboratory and environmental concentrations of PAHs.  相似文献   
4.
Pristane (2,6,10,14 -tetramethylpentadecane) occurs ubiquitously in the marine environment. This hydrocarbon may be of biogenic or petrogenic origin.1 Recently it has been shown that residual amounts of this branched alkane increased in marine organisms after an oil spill.2,3 The lack of data on the fate of pristane in fish, added with the fact that this compound was considered by some authors as a non-metabolisable substance in vertebrates, including man,4 led us to investigate the capability of fish to metabolise pristane. In this study, urinary and fecal excretion, tissue distribution and metabolism of 3H-pristane were analysed in Salmo gairdneri R. after a single intragastric dose. In addition to unchanged hydrocarbon, various labelled compounds have been isolated and identified in liver, bile, faeces, urine and surrounding water, demonstrating that pristane was first oxidised to alcohols (pristanol and pristane-diol) and to acid (pristanic acid). The elimination of these compounds occurred in the form of conjugated products (primarily glucuronides) as well as free metabolites.  相似文献   
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Quantitative Evaluation of Water Deposited By Dew on Monuments   总被引:1,自引:0,他引:1  
Samples of White and Green Carrara marble, and three types oflimestone and brick exposed in the field vertically and horizontally were used to evaluate condensationon monuments during clear sky nights. Experiments in a simulation chamber under controlledconditions led to a general equation for the actual amount of water deposited on a surface by dew.This is determined by: How much and for how long the surface temperature falls below the dew point,the moisture content in the air and the ventilation. On clear nights, the condensation on buildingstructures facing the sky may reach some 0.2 kg m-2 (or 0.2 mm), whereas condensation on verticalsurfaces is very small. Computation of the seasonal trend of night-time condensationshowed that the maximum amount of water condensed per night occurs in the autumn, with the moreabundant concentration of moisture in the air. The total amount of water condensed per month isfound to be a maximum in the summer-autumn period. Morning condensationfor the thermal inertia of monuments is also relevant, and has been calculated to reach the same order of magnitude as thenocturnal dew. A detailed analysis of the temperature and mixing ratio profiles near a condensingsurface has shown two different situations. In still air, the two profiles follow an exponentiallaw and the thermal and the concentration layers lie within a few tens of millimetres. Inthe presence of turbulence, the thickness of these two layers is dramatically reduced. In still air, infront of a vertical, chilly surface, the deposition rate of air pollutants by thermophoresis and/orStefan flow is increased by 3 or 4 times in comparison with a horizontal surface. In the presence ofturbulence, the thickness of the thermal and concentration layers was dramatically reduced, makingthese two kinds of deposition much faster.  相似文献   
7.
This work deals with sedimentological, petrographic, and structural analyses of a middle Miocene late-orogenic sedimentary cycle, denoted Oued Dayr Formation, recognized in the Rifian sector of the Maghrebian Chain (Morocco). The analyzed Formation (75 m thick) starts with 15–20 m of light colored polymict conglomerates, with minor sandstone beds, lying on the Paleozoic basement and Mesozoic cover of the Ghomaride Nappe. Facies analysis indicates a fining-upward deposition in a marine environment characterized by increasing deepening, reflecting a subsidence rate that exceeds sedimentary supply. Petrographic analysis points out that sandstones are represented by litharenites originated by erosion of recycled orogen. The conglomerates pebbles and cobbles consist of Alpine low- to high-grade metamorphic rocks as metarenites, phyllites, mylonitic quartzites, micaschists, augen gneisses deriving from the exhumed deep metamorphic basement, the overlying metasedimentary of the Sebtide Nappes and of sedimentary rocks as sandstones, jaspes, limestones, and shales deriving from the Ghomaride Nappes and their sedimentary cover. Data reveal mixed provenance indicating that the Oued Dayr Formation was fed by the Internal Nappes stack of the Maghrebian Chain. Structural analysis shows that the Oued Dayr Formation accumulated in a Thrust-Top basin, during an early extension (D0 phase), recorded by synsedimentary normal faults within middle Langhian deposits on the rear of the Internal Nappes stack. Subsequent ductile and brittle compressional (D1, D2, D3) and extensional (D4) deformation phases occurred during and/or after the stacking, exhumation, and early unroofing of Sebtide Complex coeval with the opening of the western Mediterranean back-arc basins since middle Miocene time.  相似文献   
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9.
The process of combining models of the ocean circulation with large data sets is known in meteorology as model initialization and data assimilation. This process is new to oceanographers, who only now are on the verge of having available world-wide synoptic maps of dynamic variables. In this paper we carry out a series of idealized initialization/assimilation experiments with a primitive equation (PE) model, which constitute a first step in developing a realistic process model and data assimilation techniques for the Gulf Stream system. The PE model is used in a spin-down mode and initialized with an analytic jet profile with geostrophically balanced fields.Two major questions are addressed in the present study. The first concerns the initialization process of a PE model during which internal/inertial gravity wave noise is produced. We ask: are the initialization shocks equally crucial for ocean models as they have been for their atmospheric counterparts? The results of an extensive series of balanced versus unbalanced initializations indicate that, for a PE model with a rigid lid, a brutally unbalanced initialization is required to produce strong internal gravity wave shocks. A geostrophically balanced initialization is sufficient to ensure smooth jet evolutions, with no apparent gravity waves, over long time durations in the spin-down mode. No sophisticated initialization procedures seem, therefore, to be required.The second question addressed is: which component of the flow is the most important in data assimilation to drive the model response towards a baseline reference ocean? We specifically compare the knowledge of the depth-integrated flow only, corresponding to measurements of the total transport, with the knowledge of the density field only, or equivalently the velocity shear. The knowledge of the interior density field is much more effective in decreasing the root-mean-square (r.m.s.) errors relative to the reference ocean. If the baroclinic structure is known, coarse horizontal resolutions of data insertion can be reached before significantly worsening the model estimates. If only the depth-averaged flow is known, a decrease in the horizontal resolution of data assimilation has an immediate effect: the r.m.s. errors sharply increase and the assimilation run diverges from the reference ocean. In the assimilation of the barotropic flow alone, even with dense resolution, the errors in the deep layers always show an increasing trend. The relative effectiveness of baroclinic versus barotropic data insertion can be rationalized in the context of geostrophic adjustment theory.  相似文献   
10.
Conservation and management of coastal lagoons envisage direct human intervention. To prevent siltation and to preserve the hydrodynamics features of the lagoon system, the inner channels undergo regular maintenance dredging.  相似文献   
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