Comparison of dissolved and particulate arsenic distributions in shallow aquifers of Chakdaha, India, and Araihazar, Bangladesh     

Jerome Métral  Laurent Charlet  Sara Bureau  Sukumar Basu Mallik  Sudipta Chakraborty  Kazi M Ahmed  MW Rahman  Zhongqi Cheng  Alexander van Geen 《Geochemical transactions》2008,9(1):1

Background  

The origin of the spatial variability of dissolved As concentrations in shallow aquifers of the Bengal Basin remains poorly understood. To address this, we compare here transects of simultaneously-collected groundwater and aquifer solids perpendicular to the banks of the Hooghly River in Chakdaha, India, and the Old Brahmaputra River in Araihazar, Bangladesh.  相似文献   

Calculation of Si NMR shifts of silicate complexes with carbohydrates, amino acids, and muhicarboxylic acids: potential role in biological silica utilization     

Nita Sahai 《Geochimica et cosmochimica acta》2004,68(2):227-237

The existence of ether or ester-like complexes of silicate with organic compounds has long been debated in the literature on biological utilization of silicon. Comparison of theoretically calculated ²⁹Si NMR chemical shifts for such complexes with experimentally measured values in biological systems could provide a diagnostic tool for identifying which, if any of these molecules exist under physiological conditions. Results are presented here for ab initio molecular orbital calculations of ²⁹Si NMR shifts and formation energies of silicate complexes with polyalcohols, sugar-acids, pyranose sugars, amino acids and multicarboxylic acids. The effects of functional group and molecular structure including ligand size, denticity, ring size, silicon polymerization and coordination number on calculated ²⁹Si shifts were considered. The potential role of such compounds in biological silica utilization pathways is discussed.²⁹Si NMR shifts and energies were calculated at the HF/6-311+G(2d,p)//HF/6-31G* level. The main result is that only five-membered rings containing penta- and hexa-coordinated Si can explain experimentally observed resonances at ∼ −101 and −141 ppm. Further, the heptet observed in ¹H-²⁹Si coupled spectra can only be explained by structures where Si bonds to oxygens atoms in H-C-O-Si linkages with six symmetrically equivalent H atoms.While compounds containing quadra-coordinated silicon may exist in intracellular silicon storage pools within diatoms, calculated reaction energies suggest that the organism has no thermodynamic advantage in taking up extracellular organ-silicate compounds, instead of silicic acid, from the ambient aqueous environment. Hyper-coordinated complexes are deemed unlikely for transport and storage, though they may exist as transient reactive intermediates or activated complexes during enzymatically- catalyzed silica polymerization, as known previously from sol-gel silica synthesis studies.  相似文献   

Development of a river delta: a case study of Cimanuk river mouth,Indonesia     

Nita Yuanita  Tawatchai Tingsanchali 《水文研究》2008,22(18):3785-3801

This paper describes delta development processes with particular reference to Cimanuk Delta in Indonesia. Cimanuk river delta, the most rapidly growing river delta in Indonesia, is located on the northern coast of Java Island. The delta is subject to ocean waves of less than 1 m height due to its position in the semi‐enclosed Java Sea in the Indonesian archipelago. The study has been carried out using a hydrodynamic model that accounts for sediment movement through the rivers and estuaries. As an advanced approach to management of river deltas, a numerical model, namely MIKE‐21, is used as a tool in the management of Cimanuk river delta. From calibration and verification of hydrodynamic model, it was found that the best value of bed roughness was 0·1 m. For the sediment‐transport model, the calibration parameters were adjusted to obtain the most satisfactory results of suspended sediment concentration and volume of deposition. By comparing the computed and observed data in the calibration, the best values of critical bed shear stress for deposition, critical bed shear stress for erosion and erosion coefficient were 0·05 N m^?2, 0·15 N m^?2, and 0·00001 kg m^?2 s^?1, respectively. The calibrated model was then used to analyse sensitivity of model parameters and to simulate delta development during the periods 1945–1963 and 1981–1997. It was found that the sensitive model parameters were bed shear stresses for deposition and erosion, while the important model inputs were river suspended sediment concentration, sediment characteristics and hydrodynamic. The model result showed reasonable agreement with the observed data. As evidenced by field data, the mathematical model proves that the Cimanuk river delta is a river‐dominated delta because of its protrusion pattern and very high sediment loads from the Cimanuk river. It was concluded that 86% of sediment load from the Cimanuk river was deposited in the Cimanuk delta. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Significance of co-immobilized activated carbon and Bacillus subtilis on removal of Cr(VI) from aqueous solutions     

C. Sukumar  G. Gowthami  R. Nitya  V. Janaki  Seralathan Kamala-Kannan  K. Shanthi 《Environmental Earth Sciences》2014,72(3):839-847

Batch sorption system using co-immobilized (activated carbon and Bacillus subtilis) beads as adsorbent was investigated to remove Cr(VI) from aqueous solution. Fourier transform infrared spectroscopy analysis showed the functional groups of both bacteria and activated carbon in co-immobilized beads. Experiments were carried out as a function of contact time (5–300 min), initial metal concentration (50–200 mg L^?1), pH (2–8), and adsorbent dose (0.2–1 g L^?1). The maximum percentage of removal was found to be 99 %. Langmuir model showed satisfactory fit to the equilibrium adsorption data of co-immobilized beads. The kinetics of the adsorption followed pseudo-second-order rate expression, which demonstrates that chemisorption plays a significant role in the adsorption mechanism. The significant shift in the Fourier transform infrared spectroscopy peaks and a Cr peak in the scanning electron microscope–energy dispersive spectroscopy spectra further confirmed the adsorption. The results indicate that co-immobilized beads can be used as an effective adsorbent for the removal of Cr(VI) from the aqueous solution.  相似文献   

Ionospheric refraction effects on radio interferometer phase     

S. Sukumar 《Journal of Astrophysics and Astronomy》1987,8(4):281-294

The refraction of radio waves as they traverse through the terrestrial ionosphere and troposphere introduces a differential phase path which results for a radio interferometer in variations of the visibility phase. Though refraction due to troposphere is significant for synthesis radio telescopes operating at 1.0 GHz and above, ionospheric refraction is dominant at lower frequencies. This problem is important in the case of Ooty Synthesis Radio Telescope (OSRT) operating at 326.5 MHz, due to its proximity to the magnetic equator. This paper deals with the nature of phase variations suffered by OSRT due to refraction and explains the methodology evolved to alleviate them.  相似文献   

<Emphasis Type="Bold">Petrology of Mafic-Ultramafic Rocks Along North Purulia Shear Zone,West Bengal</Emphasis> by Aditi Mandal and Arijit Ray. Jour. Geol. Soc. India,v.74, July, 2009; pp.108–118.     

A. Sukumar 《Journal of the Geological Society of India》2009,74(4):533-534

Discussion

Petrology of Mafic-Ultramafic Rocks Along North Purulia Shear Zone, West Bengal by Aditi Mandal and Arijit Ray. Jour. Geol. Soc. India, v.74, July, 2009; pp.108–118.  相似文献   

Peak Frequency Dynamics in Solar Microwave Bursts     

V. F. Melnikov  Dale E. Gary  Gelu M. Nita 《Solar physics》2008,253(1-2):43-73

We analyze the dynamics of the broadband frequency spectrum of 338 microwave bursts observed in the years 2001?–?2002 with the Owens Valley Solar Array. A subset of 38 strong microwave bursts that show a single spectral maximum are studied in detail. Our main goal is to study changes in spectral peak frequency ν _pk with time. We show that, for a majority of these simple bursts, the peak frequency shows a high positive correlation with flux density – it increases on the rise phase in ≈83% of 24 bursts where it could be cleanly measured, and decreases immediately after the peak time in ≈62% of 34 bursts. This behavior is in qualitative agreement with theoretical expectations based on gyrosynchrotron self-absorption. However, for a significant number of events (≈30?–?36%) the peak frequency variation is much smaller than expected from self-absorption, or may be entirely absent. The observed temporal behavior of ν _pk is compared with a simple model of gyrosynchrotron radio emission. We show that the anomalous behavior is well accounted for by the effects of Razin suppression, and further show how an analysis of the temporal evolution of ν _pk can be used to uniquely determine the relative importance of self-absorption and Razin suppression in a given burst. The analysis technique provides a new, quantitative diagnostic for the gyrosynchrotron component of solar microwave bursts. Applying this analysis technique to our sample of bursts, we find that in most of the bursts (60%) the spectral dynamics of ν _pk around the time of peak flux density is caused by self-absorption. On the other hand, for a significant number of events (≈70%), the Razin effect may play the dominant role in defining the spectral peak and dynamics of ν _pk, especially on the early rise phase and late decay phase of the bursts.  相似文献   

Reply to the comment on “Mobility of arsenic in West Bengal aquifers conducting low and high groundwater arsenic. Part I: Comparative hydrochemical and hydrogeological characteristics” by Subhrangsu K. Acharyya     

Bibhash Nath  Doris Stüben  Sukumar Basu Mallik  Debashis Chatterjee  Laurent Charlet 《Applied Geochemistry》2009

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Multiple Regressive Pattern Recognition Technique: An Adapted Approach for Improved Georesource Estimation     

Thomas?Oommen  Debasmita?MisraEmail author  Anupma?Prakash  Sukumar?Bandopadhyay  Sathy?Naidu  John?J.?Kelley 《Natural Resources Research》2011,20(1):11-24

Multiple Regressive Pattern Recognition Technique (MRPRT) is an adapted approach for improved geologic resource estimation. We developed and tested this approach for the Platinum (Pt) bearing region near Goodnews Bay, Alaska, which presents an example of a complex depositional environment. We applied geospatial and pattern recognition methods to assess the spatial distribution of offshore Pt in the Goodnews Bay area from point data collected by various agencies. We used the coefficient of correlation (r) and the Nash–Sutcliffe efficiency (E) to quantitatively assess the degree of accuracy of the estimated Pt distribution. We split the study area, based on trend analysis, into two regions: inside the Bay and outside the Bay. We could not obtain appreciable estimates from the geospatial and pattern recognition methods. Using MRPRT, we were able to improve r from 0.57 to 0.93 and the E from 28.31 to 92.91 inside the Bay. We achieved improvement in r from 0.55 to 0.61 and E from 28.46 to 34.52 outside the Bay. The reasons for a non-significant improvement outside the Bay have been discussed. The results indicate that the proposed MRPRT has wide application potential in georesource estimation where input data is often scarce.  相似文献   

Mobility of arsenic in West Bengal aquifers conducting low and high groundwater arsenic. Part I: Comparative hydrochemical and hydrogeological characteristics     

Bibhash Nath  Doris Stüben  Sukumar Basu Mallik  Debashis Chatterjee  Laurent Charlet 《Applied Geochemistry》2008

The present study demonstrates the importance of hydrogeochemical characteristics (groundwater flow and recharge) of an aquifer in the release of As to groundwater. The study area (∼20 km²) is located in Chakdaha block, Nadia district, West Bengal, which hosts groundwaters of variable As content. The spatial distribution pattern of As is patchy with areas containing groundwater that is high in As (>200 μg L⁻¹) found in close vicinity to low As (<50 μg L⁻¹) groundwaters (within 100 m). The concentration of groundwater As is found to decrease with depth. In addition, the data shows that there is no conspicuous relationship between high groundwater As concentration and high groundwater abstraction, although the central cone of depression has enlarged over 2 a and is extending towards the SE of the study area. The river Hooghly, which forms the NW boundary of the study site, shows dual behaviour (effluent and influent during pre- and post-monsoon periods, respectively), complicating the site hydrogeology. The observed groundwater flow lines tend to be deflected away from the high As portion of the aquifer, indicating that groundwater movement is very sluggish in the As-rich area. This leads to a high residence time for this groundwater package, prolonging sediment–water interaction, and hence facilitating groundwater As release.  相似文献