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Janet G. Hering William G. Sunda Randolph L. Ferguson Francois M.M. Morel 《Marine Chemistry》1987,20(4)
Complexation of copper added to seawater was determined by bacterial bioassay and fixedpotential amperometry. Consistent results were obtained by these two fundamentally different methods. The results of this study support the validity of both techniques and the field applicability of fixed-potential amperometry.The intercomparison studies were performed on samples collected at the N.Y.C. sewage sludge dumpsite and in relatively unpolluted coastal waters. In this limited study, the calculated free cupric ion concentrations at ambient total copper concentrations were similar at both sites. 相似文献
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William G. Sunda 《Marine Chemistry》1984,14(4):365-378
Equilibria between Chelex 100* and manganese, zinc and cadmium ions were used to determine the complexation of these trace metals in 36‰ Gulf Stream seawater at 25°C and pH 8.2. The method utilized radiotracers (54Mn, 65Zn, and 109Cd) to quantify trace metal adsorption from trace metal-amended seawater and from seawater containing a series of ethylenediaminetetracetate (EDTA)—metal ion buffers. Results were consistent with Chelex adsorption of both trace metal ions and trace metal—EDTA chelates. Equilibrium models fitted to the data were used to establish conditional stability constants for Chelex adsorption of manganese, zinc and cadmium ions and for adsorption of EDTA-chelates. These models also yielded ratios of free metal ions to total dissolved trace metal concentrations in seawater: 10−0.1 for manganese, 10−0.2 for zinc, and 10−1.5 for cadmium. Independent measurements with a cadmium ion-selective electrode also yielded a free: total cadmium ratio of 10−1.5. 相似文献
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Saito Susumu Sunda Surendra Lee Jiyun Pullen Sam Supriadi Slamet Yoshihara Takayuki Terkildsen Michael Lecat Frédéric 《GPS Solutions》2017,21(4):1937-1947
GPS Solutions - We investigated characteristics of anomalous spatial gradients in ionospheric delay on GNSS signals in the Asia-Pacific (APAC) low-magnetic latitude region in the context of the... 相似文献
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Surendra Sunda Sneha Yadav R. Sridharan M. S. Bagiya P. V. Khekale Pan Singh S. V. Satish 《GPS Solutions》2017,21(4):1469-1478
With the increase in the use of satellite-based navigation services, the forecasting of L band scintillation has turned out to be of paramount importance as it affects their accuracy and availability. Forecasting the time of occurrence or non-occurrence, strength and probable location of scintillation enables the service providers and users to take appropriate action to mitigate the effects and optimize the services. We use the recently developed method to retrieve TEC from the ionospheric correction data transmitted by the Indian satellite-based augmentation system (SBAS)–GAGAN. By making use of the established linear relation between the dusk time TEC and the maximum probable scintillation intensity (S4max), scintillation forecast maps have been generated as early as 1930 LT. The superposition of actual S4 measurements, obtained from the GAGAN network of receivers, on the forecasted S4max map shows that the actual measurements are less than the predicted S4max except on very few occasions. The potential of the simple technique to predict the 2 D maps of maximum probable scintillation index for the whole night has been demonstrated which with more refinements could evolve into a viable forecast or forewarning system. 相似文献
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