The Fe-C system at 5 GPa and implications for Earth’s core     

Nancy L. Chabot  Andrew J. Campbell  David S. Draper  Munir Humayun  Elizabeth Cottrell 《Geochimica et cosmochimica acta》2008,72(16):4146-4158

Earth’s core may contain C, and it has been suggested that C in the core could stabilize the formation of a solid inner core composed of Fe₃C. We experimentally examined the Fe-C system at a pressure of 5 GPa and determined the Fe-C phase diagram at this pressure. In addition, we measured solid metal/liquid metal partition coefficients for 17 trace elements and examined the partitioning behavior between Fe₃C and liquid metal for 14 trace elements. Solid metal/liquid metal partition coefficients are similar to those found in one atmosphere studies, indicating that the effect of pressure to 5 GPa is negligible. All measured Fe₃C/liquid metal partition coefficients investigated are less than one, such that all trace elements prefer the C-rich liquid to Fe₃C. Fe₃C/liquid metal partition coefficients tend to decrease with decreasing atomic radii within a given period. Of particular interest, our 5 GPa Fe-C phase diagram does not show any evidence that the Fe-Fe₃C eutectic composition shifts to lower C contents with increasing pressure, which is central to the previous reasoning that the inner core may be composed of Fe₃C.  相似文献   

Stability of waterfront retaining wall subjected to pseudo-static earthquake forces     

Deepankar Choudhury  Syed Mohd. Ahmad 《Ocean Engineering》2007,34(14-15):1947-1954

Waterfront retaining walls supporting dry backfill are subjected to hydrostatic pressure on upstream face and earth pressure on the downstream face. Under seismic conditions, if such a wall retains a submerged backfill, additional hydrodynamic pressures are generated. This paper pertains to a study in which the effect of earthquakes along with the hydrodynamic pressure including inertial forces on such a retaining wall is observed. The hydrodynamic pressure is calculated using Westergaard's approach, while the earth pressure is calculated using Mononobe-Okabe's pseudo-static analysis. It is observed that when the horizontal seismic acceleration coefficient is increased from 0 to 0.2, there is a 57% decrease in the factor of safety of the retaining wall in sliding mode. For investigating the effect of different parameters, a parametric study is also done. It is observed that if φ is increased from 30° to 35°, there is an increase in the factor of safety in the sliding mode by 20.4%. Similar observations were made for other parameters as well. Comparison of results obtained from the present approach with [Ebeling, R.M., Morrison Jr, E.E., 1992. The seismic design of waterfront retaining structures. US Army Technical Report ITL-92-11. Washington DC] reveal that the factor of safety for static condition (k_h=0), calculated by both the approaches, is 1.60 while for an earthquake with k_h=0.2, they differ by 22.5% due to the consideration of wall inertia in the present study.  相似文献   

Platinum group element geochemistry of komatiites from the Alexo and Pyke Hill areas, Ontario, Canada     

Igor S. Puchtel  Munir Humayun  Rebecca A. Sproule 《Geochimica et cosmochimica acta》2004,68(6):1361-1383

Thirty-three whole-rock drill core samples and thirteen olivine, chromite, and sulfide separates from three differentiated komatiite lava flows at Alexo and Pyke Hill, Canada, were analyzed for PGEs using the Carius tube digestion ID-ICP-MS technique. The emplaced lavas are Al-undepleted komatiites with ∼27% MgO derived by ∼50% partial melting of LILE-depleted Archean mantle. Major and minor element variations during and after emplacement were controlled by 30 to 50% fractionation of olivine Fo_93-94. The emplaced lavas are characterized by (Pd/Ir)_N = 4.0 to 4.6, (Os/Ir)_N = 1.07, and Os abundances of ∼2.3 ppb. Variations in PGE abundances within individual flows indicate that Os and Ir were compatible (bulk D_Os,Ir = 2.4-7.1) and that Pt and Pd were incompatible (bulk D_Pt,Pd < 0.2) during lava differentiation, whereas bulk D_Ru was close to unity. Analyses of cumulus olivine separates indicate that PGEs were incompatible in olivine (D_PGEs^Ol-Liq = 0.04-0.7). The bulk fractionation trends cannot be accounted for by fractionation of olivine alone, and require an unidentified Os-Ir-rich phase. The composition of the mantle source (Os = 3.9 ppb, Ir = 3.6 ppb, Ru = 5.4 ppb, Pt and Pd = 5.7 ppb) was constrained empirically for Ru, Pt, and Pd; the Os/Ir ratio was taken to be identical to that in the emplaced melt, and the Ru/Ir ratio was taken to be chondritic, so that the absolute IPGE abundances of the source were determined by Ru. This is the first estimate of the PGE composition of a mantle source derived from analyses of erupted lavas. The suprachondritic Pd/Ir and Os/Ir of the inferred Abitibi komatiite mantle source are similar to those in off-craton spinel lherzolites, orogenic massif lherzolites, and enstatite chondrites, and are considered to be an intrinsic mantle feature. Bulk partition coefficients for use in komatiite melting models derived from the source and emplaced melt compositions are: D_Os,Ir = 2.3, D_Ru = 1.0, D_Pt,Pd = 0.07. Ruthenium abundances are good indicators of absolute IPGE abundances in the mantle sources of komatiite melts with 26 to 29% MgO, as Ru fractionates very little during both high degrees of partial melting and lava differentiation.  相似文献   

Highly siderophile element geochemistry of Os-enriched 2.8 Ga Kostomuksha komatiites, Baltic Shield     

Igor S. Puchtel  Munir Humayun 《Geochimica et cosmochimica acta》2005,69(6):1607-1618

New analyses of highly siderophile elements (HSE; Re, Os, Ir, Ru, Pt, and Pd) obtained by Carius tube digestion isotope dilution inductively coupled plasma mass-spectrometry (ID-ICPMS) technique are reported for ¹⁸⁷Os-enriched 2.8 Ga komatiites from the Kostomuksha greenstone belt. As a result of a significant improvement in the yield over our previous digestions by the NiS fire-assay technique, these komatiites have now been shown to contain 22 to 25% more Os, Ir, and Pt and 34% more Ru. The emplaced komatiite lavas at Kostomuksha thus had siderophile element abundances comparable to those of the Abitibi belt. The discrepancies observed between the two techniques are interpreted to be the result of incomplete digestion of HSE carriers (particularly chromite) during the NiS fire-assay procedure. Our results for UB-N peridotite reference material agree well with those obtained by the high-pressure ashing digestion ID-ICPMS technique reported in the literature. Two types of komatiite lavas have been distinguished in this study based on the IPGE (Os, Ir, and Ru) behavior during lava differentiation. The Kostomuksha type is unique and is characterized by an incompatible behavior of IPGEs, with bulk solid-liquid partition coefficients for IPGEs being close to those for olivine. Cumulate zones in this type of komatiite lava occupy <20% of the total thickness of the flows. The Munro type exhibits a compatible behavior of IPGEs during lava differentiation. The cumulate zone in this type of komatiite occupies >20% of the total thickness of the flows. The calculated bulk partition coefficients indicate that, as with the other Munro-type komatiite lavas, the bulk cumulate contained an IPGE-rich minor phase(s) in addition to olivine. The non-CI chondritic HSE pattern for the source of the Kostomuksha komatiites calculated here is similar to that of Abitibi komatiites and to average depleted spinel lherzolite (ADSL) and supports the hypothesis of a non-CI chondritic HSE composition of the Earth’s mantle. The absolute HSE abundances in the source of the Kostomuksha komatiite have been demonstrated to be comparable to those of the source of Abitibi komatiites, even though the two komatiites contrast in their Os isotopic compositions. This supports the earlier hypothesis that if core-mantle interaction produced the ¹⁸⁷Os/¹⁸⁸Os radiogenic signature in the Kostomuksha source, it must have occurred in the form of isotope exchange at the core-mantle boundary. Other explanations of the radiogenic Os signature are similarly constrained to conserve the elemental abundance pattern in the mantle source of Kostomuksha komatiites.  相似文献   

Compositions of group IVB iron meteorites and their parent melt     

Andrew J. Campbell  Munir Humayun 《Geochimica et cosmochimica acta》2005,69(19):4733-4744

The concentrations of P, V, Cr, Fe, Co, Ni, Cu, Ga, Ge, As, Mo, Ru, Rh, Pd, W, Re, Os, Ir, Pt, and Au in the group IVB iron meteorites Cape of Good Hope, Hoba, Skookum, Santa Clara, Tawallah Valley, Tlacotepec, and Warburton Range have been measured by laser ablation inductively coupled plasma mass spectrometry. The data were fitted to a model of fractional crystallization of the IVB parent body core, from which the composition of the parent melt and metal/melt distribution coefficients for each element in the system were determined, for a chosen value of D(Ni). Relative to Ni and chondritic abundances, the parent melt was enriched in refractory siderophiles, with greatest enrichment of 5× chondritic in the most refractory elements, and was strongly volatile-depleted, down to 0.00014× chondritic in Ge. Comparison to an equilibrium condensation sequence from a gas of solar composition indicates that no single temperature satisfactorily explains the volatility trend in the IVB parent melt; a small (<1%) complement of ultrarefractory components added to metal that is volatile-depleted but otherwise has nearly chondritic abundances (for Fe, Co and Ni) best explains the volatility trend. In addition to this volatility processing, which probably occurred in a nebular setting, there was substantial oxidation of the metal in the IVB parent body, leading to loss of Fe and other moderately siderophile elements such as Cr, Ga, and W, and producing the high Ni contents that are observed in the IVB irons. By assuming that the entire IVB parent body underwent a similar chemical history as its core, the composition of the silicate that is complementary to the IVB parent melt was also estimated, and appears to be similar to that of the angrite parent.  相似文献   

An analytical solution for deforming twin‐parallel tunnels in an elastic half plane          下载免费PDF全文

Jinyang Fu  Junsheng Yang  Li Yan  Syed Muntazir Abbas 《国际地质力学数值与分析法杂志》2015,39(5):524-538

The interaction between twin‐parallel tunnels affects the tunnelling‐induced ground deformation, which may endanger the nearby structures. In this paper, an analytical solution is presented for problems in determining displacements and stresses around deforming twin‐parallel tunnels in an elastic half plane, on the basis of complex variable theory. As an example, a uniform radial displacement was assumed as the boundary condition for each of the two tunnels. Special attention was paid to the effects of tunnel depth and spacing between the two tunnels on the surface movement to gain deep insight into the effect of the interaction between twin‐parallel tunnels using the proposed analytical approach. It is revealed that the influence of twin tunnel interaction on surface movements diminishes with both the increase of the tunnel depth and the spacing between the two tunnels. The presented analytical solution manifests that, similar to most of the existing numerical results, the principle of superposition can be applied to determine ground deformation of twin‐parallel tunnels with a certain large depth and spacing; otherwise, the interaction effect between the two tunnels should be taken into account for predicting reliable ground movement. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Diversity patterns of free‐living marine nematodes in the southwest continental shelf off Bay of Bengal and their link to abiotic variables          下载免费PDF全文

Kapuli Gani Mohamed Thameemul Ansari  Somasundharanair Lyla  Syed Ajmal Khan  Punyasloke Bhadury 《Marine Ecology》2016,37(3):631-644

Marine sediments in continental shelf ecosystems harbor a rich biodiversity of benthic communities. In this study, the spatial and temporal diversity and community assemblages of free‐living marine nematodes were studied by sampling at six depths and over 3 years from the southwest continental shelf off Bay of Bengal, one of the least explored tropical shelf ecosystems. The dominant marine nematode species were related with abiotic variables as part of this study. The effects of sediment granulometry generally decreased with increasing depth and the highest nematode density and species diversity were recorded on coarse sand (shallower depths). Multivariate analysis of the nematode community data showed that community structure differed significantly among depths as well as among years. Statistical analyses showed significant correlations between the nematode community and abiotic variables. Sediment texture, organic matter, water pressure and depth profile were crucial factors for determining diversity, vertical profile and feeding types of the nematode community. Other environmental factors, including anthropogenic pressure, did not have an effect on nematode diversity except for the presence of some tolerant species (Metachromadora spp., Sabatieria spp. and Siplophorella sp.). This study represents a baseline of knowledge of free‐living marine nematode communities that can be used in the future to compare nematode assemblages from temperate shelf ecosystems.  相似文献   

Hydrogeochemical characterization and quality assessment of groundwater in parts of Southern Gangetic Plain     

Satya N. Sethy  Tajdarul H. Syed  Alok Kumar  Debanjan Sinha 《Environmental Earth Sciences》2016,75(3):232

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Contamination of soil and carrots irrigated with different sources of water in Punjab,Pakistan     

Kafeel Ahmad  Zafar Iqbal Khan  Sumaira Yasmin  Asma Ashfaq  Ijaz Rasool Noorka  Nudrat Aisha Akram  Hazoor Ahmad Shad  Abrar Hussain  Fahim Arshad  Muhammad Sher  Hafiz Muhammad Tahir  Humayun Bashir  Asma Zafar 《Environmental Earth Sciences》2016,75(5):426

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The Red Sea depositional architecture: insights from 3D modeling     

Khalid A. Almalki  Syed A. Mahmud  Hisham I. Hashem  Oumar A. Loni 《Arabian Journal of Geosciences》2018,11(11):277

More than half a century of geological and exploration studies have taken place in the Red Sea area, and still very limited information is available to the geological community in regard to the lithological distribution and the stratigraphic architecture. In this study, extensive well data was used to build the first lithologic and stratigraphic 3D models of the entire Red Sea to better understand the lithological distribution. The potential models have been constrained by bathymetric and geophysical data. Studied data demonstrate that up to 5 km of sediments were deposited in the Red Sea. It is mainly comprised of limestones, evaporites, and shales. Our models show that the evaporite body represents more than 70% of the Red Sea succession. In particular, the evaporite succession seems to be well developed in the southern region. Salt dome features are present and developed close to the margins. The models suggest that domal formation did not enable thick carbonate accumulation in some parts of the basin but the carbonate generally follows the evaporite trend. The models help to identify the main controls leading to salt diapir by highlighting the distribution of this body and the geometry of geological structures. Syn-rift faulting and rifting has been one of the most prominent structural features. Complex interplay of tectono-stratigraphic events played a significant role in shaping the stratigraphic evolution of the Red Sea basin with multiple evolution phases of paleoenvironment and paleogeographic were recognized based on the models. Our synthesis and interpretation support that moderately deep marine conditions dominated in the Miocene, whereas shallow seas dominated the whole basin during the Plio-Pleistocene period as a result of episodic marine invasion. However, lacustrine environment may have prevailed at the Oligocene time in isolated half grabens.  相似文献