The sandstone-hosted stratiform copper mineralization at Mwitapile and its relation to the mineralization at Lufukwe, Lufilian foreland, Democratic Republic of Congo   总被引：2，自引：0，他引：2  

Hamdy A. El Desouky  Philippe Muchez  Roger Tyler 《Ore Geology Reviews》2008,34(4):561-579

The Lufilian foreland is a triangular-shaped area located in the SE of the Democratic Republic of Congo and to the NE of the Lufilian arc, which hosts the well-known Central African Copperbelt. The Lufilian foreland recently became an interesting area with several vein-type (e.g., Dikulushi) and stratiform (e.g., Lufukwe and Mwitapile) copper occurrences. The Lufilian foreland stratiform Cu mineralization is, to date, observed in sandstone rock units belonging to the Nguba and Kundelungu Groups (Katanga Supergroup).The Mwitapile sandstone-hosted stratiform Cu prospect is located in the north eastern part of the Lufilian foreland. The host rock for the Cu mineralization is the Sonta Sandstone of the Ngule Subgroup (Kundelungu Group). A combined remote sensing, petrographic and fluid inclusion microthermometric analysis was performed at Mwitapile and compared with similar analysis previously carried out at Lufukwe to present a metallogenic model for the Mwitapile- and Lufukwe-type stratiform copper deposits. Interpretation of ETM+ satellite images for the Mwitapile prospect and the surrounding areas indicate the absence of NE–SW or ENE–WSW faults, similar to those observed controlling the mineralization at Lufukwe. Faults with these orientations are, however, present to the NW, W, SW and E of the Mwitapile prospect. At Mwitapile, the Sonta Sandstone host rock is intensely compacted, arkosic to calcareous with high silica cementation (first generation of authigenic quartz overgrowths). In the Sonta Sandstone, feldspar and calcite are present in disseminated, banded and nodular forms. Intense dissolution of these minerals caused the presence of disseminated rectangular, pipe-like and nodular dissolution cavities. Sulfide mineralization is mainly concentrated in these cavities. The hypogene sulfide minerals consist of two generations of pyrite, chalcopyrite, bornite and chalcocite, separated by a second generation of authigenic quartz overgrowth. The hypogene sulfide minerals are replaced by supergene digenite and covellite. Fluid inclusion microthermometry on the first authigenic quartz phase indicates silica precipitation from an H₂O–NaCl–CaCl₂ fluid with a minimum temperature between 111 and 182 °C and a salinity between 22.0 and 25.5 wt.% CaCl₂ equiv. Microthermometry on the second authigenic quartz overgrowths and in secondary trails related to the mineralization indicate that the mineralizing fluid is characterized by variable temperatures (Th = 120 to 280 °C) and salinities (2.4 to 19.8 wt.% NaCl equiv.) and by a general trend of increasing temperatures with increasing salinities.Comparison between Mwitapile and Lufukwe indicates that the stratiform Cu mineralization in the two deposits is controlled by similar sedimentary, diagenetic and structural factors and likely formed from a similar mineralizing fluid. A post-orogenic timing is proposed for the mineralization in both deposits. The main mineralization controlling factors are grain size, clay and pyrobitumen content, the amount and degree of feldspar and/or calcite dissolution and the presence of NE–SW to ENE–WSW faults. The data support a post-orogenic fluid-mixing model for the Mwitapile- and Lufukwe-type sandstone-hosted stratiform Cu deposits, in which the mineralization is related to the mixing between a Cu-rich hydrothermal fluid, with a temperature up to 280 °C and a maximum salinity of 19.8 wt.% NaCl equiv., with a colder low salinity reducing fluid present in the sandstone host rock. The mineralizing fluid likely migrated upwards to the sandstone source rocks along NE–SW to ENE–WSW orientated faults. At Lufukwe, the highest copper grades at surface outcrops and boreholes were found along and near to these faults. At Mwitapile, where such faults are 2 to 3 km away, the Cu grades are much lower than at Lufukwe. Copper precipitation was possibly promoted by reduction from pre-existing hydrocarbons and non-copper sulfides and by the decrease in fluid salinity and temperature during mixing. Based on this research, new Cu prospects were proposed at Lufukwe and Mwitapile and a set of recommendations for further Cu exploration in the Lufilian foreland is presented.  相似文献   

The sea-surface microlayer of puget sound: Part I. Toxic effects on fish eggs and larvae     

John Hardy  Steven Kiesser  Liam Antrim  Alan Stubin  Richard Kocan  John Strand 《Marine environmental research》1987,23(4)

The sea surface is an important habitat for the developmental stages (eggs and larvae) of many fish and invertebrates; it is also a concentration point for anthropogenic contaminants entering the sea. Studies were conducted to determine the extent to which the sea surface of Puget Sound was toxic to the early life history stages of fish. Three urban bays with suspected contamination, a rural reference bay, and a Central Sound site were compared. Surface-dwelling eggs and organisms (zooneuston) were collected with a surface-skimming neuston net and their densities enumerated. Sand sole (Psettichthys melanostictus) embryos were exposed in the field and laboratory to the sea-surface microlayer. To develop a useful year-round approach to monitoring sea-surface toxicity, larval development of anchovies, kelp bass, and sea urchins was also evaluated as an indication of sea-surface microlayer toxicity.During the spawning season (February and March), urban boys in Puget Sound had lower concentrations of sand sole eggs and neustonic organisms on the sea surface than did the rural bayor Central Sound reference sites. Compared to the reference sites, laboratory exposure to surface microlayer samples collected from urban bay sites generally resulted in more chromsomal aberrations in developing sole embryos, reduced hatching success of sole larvae, and reduced growth in trout cell cultures. In situ hatching success of sole eggs was reduced by half or more in urban bays compared to reference sites.Toxicity was associated with visible surface slicks and, in urban bays, increased with increasing surface pressure (dynes cm⁻¹). Results to be reported separately (Part II) indicate that toxicity is strongly correlated with the presence of high concentrations of polycyclic aromatic hydrocarbons and metals in the sea-surface microlayer. The toxicity of SMIC samples was similar when evaluated by sole, anchovy, kelp bass, or sea urchin tests. A sea-surface monitoring program could use sea urchin embryos to evaluate site-specific sea-surface toxicity throughout the year.  相似文献   

Contaminant concentrations and toxicity of sea-surface microlayer near Los Angeles, California     

Jeffrey N. Cross  John T. Hardy  Jo Ellen Hose  G.Patrick Hershelman  Liam D. Antrim  Richard W. Gossett  Eric A. Crecelius 《Marine environmental research》1987,23(4)

Sea-surface microlayer samples were collected from six nearshore areas receiving different amounts of anthropogenic inputs. The samples were analyzed for selected trace metals, chlorinated hydrocarbons, and polycyclic aromatic hydrocarbons. The relative toxicities of the samples were determined with fish embryo bioassays.Contaminant concentrations generally increased from offshore to the inshore stations. Contaminant concentrations were several orders of magnitude higher in microlayer samples from the highly industrialized Los Angeles and Long Beach harbors compared to samples from a site 15km offshore. Microlayer samples from the inshore stations were significantly more toxic, and induced significantly more developmental abnormalities and chromosome aberrations, than samples from the offshore stations.  相似文献   

Seasonality and selectivity in the feeding ecology and reproductive biology of deep-sea bathyal holothurians     

Ian R. Hudson  Benjamin D. Wigham  David S. M. Billett  Paul A. Tyler 《Progress in Oceanography》2003,59(4):381-407

Chlorophyll and carotenoid pigments were determined from the gut sediments of five species of bathyal holothurian in the NE Atlantic, sampled shortly after the spring/summer phytoplankton bloom in 2001 and prior to the spring bloom in 2002. Three species, Laetmogone violacea, Paroriza pallens and Bathyplotes natans, sampled within a similar depth range (900–1100 m) in the summer of 2001 showed significant differences in their chlorophyll and carotenoid pigment concentrations. This suggests they may select for slightly different components from the available food resource. Four species sampled in early spring 2002, Laetmogone violacea, Paroriza pallens, Benthogone rosea and Benthothuria funebris, also had significant differences in their pigment concentrations. These species were sampled over a wider depth range (1000–3100 m) showing a bathymetric trend in pigment concentrations. There was a distinct seasonal change in the composition and concentration of the pigments, linked to a reduction in the availability of fresh organic material during autumn and winter periods.Ovarian tissue was also examined. The carotenoid pigments found in the ovary also occurred in the OM ingested by the holothurians. The dominant gonadal carotenoid pigments were β-carotene, echinenone and zeaxanthin. The potential for using these carotenoids to gain a competitive advantage through selectivity of chlorophyll and carotenoid pigment biomarkers are discussed in relation to competition for food resources by deposit-feeders. The results were also compared with selectivity in abyssal species.  相似文献   

Aquatic surface microlayer contamination in chesapeake bay   总被引：1，自引：0，他引：1  

John T. Hardy  Eric A. Crecelius  Liam D. Antrim  Steven L. Kiesser  Virginia L. Broadhurst 《Marine Chemistry》1990,28(4)

The aquatic surface microlayer (SMIC), 50 μm thick, serves as a concentration point for metal and organic contaminants that have low water solubility or are associated with floatable particles. Also, the eggs and larvae of many fish and shellfish species float on, or come in contact with, the water surface throughout their early development. The objectives of this study were (1) to determine the present degree of aquatic surface microlayer pollution at selected sites in Chesapeake Bay, and (2) to provide a preliminary evaluation of sources contributing to any observed contamination.Twelve stations located in urban bays, major rivers, and the north central bay were sampled three times, each at 5-day intervals during May 1986. Samples of 1.4–4.1 each were collected from the upper 30–60-μm water surface (surface microlayer, SMIC) using a Teflon-coated rotating drum microlayer sampler. One sample of subsurface water was collected in the central bay.At all stations, concentrations of metals, alkanes, and aromatic hydrocarbons in the SMIC were high compared with one bulk-water sample and with typical concentrations in water of Chesapeake Bay and elsewhere. SMIC contamination varied greatly among the three sampling times, but high mean contaminant levels (total polycyclic aromatic hydrocarbons, 1.9–6.2 μg 1⁻¹; Pb, 4.9–24 μg 1⁻¹; Cu, 4–16 μg 1⁻¹; and Zn, 34–59 μg 1⁻¹) were found at the upper Potomac and northern bay sites. Three separate areas were identified on the basis of relative concentrations of different aromatic hydrocarbons in SMIC samples - the northern bay, the Potomac River, and the cleaner southern and eastern portions of the sampling area.Suspected sources of surface contamination include gasoline and diesel fuel combustion, coal combustion, and petroleum product releases. Concentrations of metals and hydrocarbons, at approximately half the stations sampled, are sufficient to pose a threat to the reproductive stages of some fish and shellfish. Sampling and analysis of the surface microlayer provides a sensitive tool for source identification and monitoring of potentially harmful aquatic pollution.  相似文献   

A wave model for the Great Barrier Reef   总被引：1，自引：0，他引：1  

Thomas A. Hardy  Luciano B. Mason  Jason D. McConochie 《Ocean Engineering》2001,28(1):1869

A new wind wave generation model, WAMGBR, is presented that has been adapted from WAM especially for use in the complex geometry of the Great Barrier Reef. A technique (reef parameterization) has been presented that incorporates sub-grid scale dissipation caused by coral reefs. Three other improvements to WAM have been proposed. An explicit/implicit finite difference scheme has been implemented that allows for more efficient modelling (longer time steps) while maintaining diffusive characteristics that are at least as good as those of WAM. An offset in discrete angles creates more uniform diffusive characteristics. And, a transformed spherical coordinate system allows for more efficient grid sizes and smaller grid dependent refraction. Comparisons between modelling techniques and between model and measured data show that WAMGBR produces very good results in the difficult challenge of modelling both non-cyclonic and tropical cyclone waves in the geographically complex environment of the Great Barrier Reef.  相似文献   

The Taconite Inlet Lakes Project: a systems approach to paleoclimatic reconstruction     

R. S. Bradley  M. J. Retelle  S. D. Ludlam  D. R. Hardy  B. Zolitschka  S. F. Lamoureux  M. S. V. Douglas 《Journal of Paleolimnology》1996,16(2):97-110

A comprehensive study of meteorological, hydrological, limnological and sedimentological conditions in the watersheds of density-stratified (meromictic) lakes around Taconite Inlet, Northern Ellesmere Island, N.W.T., Canada was carried out from 1990–1992. Lakes C1 and C2 contain seawater trapped by isostatic uplift as the former embayments became isolated from the sea. These lakes, and Lake C3, contain varved sediments which provide an annually resolvable paleoclimatic record. By studing the major systems influencing sedimentation in one of these lakes (Lake C2) a better understanding of the climatic controls on varve formation, and hence on the paleoclimatic signal in the varved sediment record, was obtained. The varves of Lake C2 provide a proxy record of summer temperature for the region.This is the first in a series of papers published in this issue on the Taconite Inlet Lakes Project. These papers were collected by Dr R. S. Bradley.  相似文献   

Machine Learning for Improving Surface-Layer-Flux Estimates     

McCandless  Tyler  Gagne  David John  Kosović  Branko  Haupt  Sue Ellen  Yang  Bai  Becker  Charlie  Schreck  John 《Boundary-Layer Meteorology》2022,185(2):199-228

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Mars surface properties observed by earth-based radar at 70-, 12.5-, and 3.8-cm wavelengths     

Richard A. Simpson  G.Leonard Tyler  Belinda J. Lipa 《Icarus》1977,32(2):147-167

A review of Mars radar data obtained through the 1973 opposition confirms that the surface of the planet has many diverse characteristics. Analysis of the quasi-specular echo component shows changes in apparent reflectivity of at least 5 to 1. If attributed entirely to variations in surface material, these correspond to dielectric constants between 1.6 and 4.0. Values of rms surface slope on 1- to 100-m scales range from as low as 0.5° in tablelands near Vlles Marineris to more than 3.0° (the upper limit for which these analysis techniques are appropriate) in certain other areas such as inside Coprates Chasma itself. There is weak correlation between the small-scale surface characteristics inferred from radar and those inferred from Mariner 9 images, geologic maps derived from those images, and other remote sensing data sets. Topography, a large-scale surface characteristic for which good correlation exists between radar and other data sets, was not considered in this study. A search for guidelines which would allow extrapolation of radar properties to new areas on the basis of those studied has been singularly unsuccessful. Data obtained during the 1973 opposition at Arecibo, Goldstone, and Haystack Observatories indicate that the scattering behavior of Mars varies little over the 70- to 3.8-cm wavelength range. Comparison of 1971 and 1973 Goldstone results shows no detectable variation with time.  相似文献   

Discrete element modelling of the influence of cover strength on basement-involved fault-propagation folding   总被引：2，自引：0，他引：2  

Stuart Hardy  Emma Finch   《Tectonophysics》2006,415(1-4):225-238

A discrete element model is used to investigate the influence of sedimentary cover strength on the development of basement-involved fault-propagation folds. We find that uniformly weak cover best promotes the development of classical, trishear-like fault-related folds showing marked anticlinal thinning and synclinal thickening, with cover dips increasing downwards towards the fault tip. Uniformly strong cover results in more rounded fold forms with only minor hinge thickening/thinning and significant basement fault-propagation into the sedimentary cover. Heterogeneous, layered, cover sequences with marked differences in strength promote the development of more complex and variable fold forms, with a close juxtaposition of brittle and macroscopically ductile features, which diverge from the predictions of simple kinematic models. In these structures the upper layers are often poor indicators of deeper structure. In addition, we find that in layered cover sequences fault-propagation into the cover is a complex process and is strongly buffered by the weaker cover units.  相似文献