We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
As well known, the methods of remote sensing and Bowen Ratio for retrieving surface flux are based on energy balance closure; however, in most cases, surface energy observed in experiment is lack of closure. There are two main causes for this: one is from the errors of the observation devices and the differences of their observational scale; the other lies in the effect of horizontal advection on the surface flux measurement. Therefore, it is very important to estimate the effects of horizontal advection quantitatively. Based on the local advection theory and the surface experiment, a model has been proposed for correcting the effect of horizontal advection on surface flux measurement, in which the relationship between the fetch of the measurement and pixel size for remote sensed data was considered. By means of numerical simulations, the sensitivities of the main parameters in the model and the scaling problems of horizontal advection were analyzed. At last, by using the observational data acquired in agricultural field with relatively homogeneous surface, the model was validated.
Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades
in autumn as thermocline declines. TF intensity ⋎ST⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution
in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results
are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming
and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the
TF.
Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No.
49736190). 相似文献
In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series. 相似文献
Based on the MASNUM wave-tide-circulation coupled numerical model, the temperature structure along 35°N in the Yellow Sea
was simulated and compared with the observations. One of the notable features of the temperature structure along 35°N section
is the double cold cores phenomena during spring and summer. The double cold cores refer to the two cold water centers located
near 122°E and 125°E from the depth of 30m to bottom. The formation, maintenance and disappearance of the double cold cores
are discussed. At least two reasons make the temperature in the center (near 123°E) of the section higher than that near the
west and east shores in winter. One reason is that the water there is deeper than the west and east sides so its heat content
is higher. The other is invasion of the warm water brought by the Yellow Sea Warm Current (YSWC) during winter. This temperature
pattern of the lower layer (from 30m to bottom) is maintained through spring and summer when the upper layer (0 to 30m) is
heated and strong thermocline is formed. Large zonal span of the 35°N section (about 600 km) makes the cold cores have more
opportunity to survive. The double cold cores phenomena disappears in early autumn when the west cold core vanishes first
with the dropping of the thermocline position.
Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No.
49736190). 相似文献
We discuss the determination of membership of 42 open clusters. Our analysis shows that Vasilevskis' mathematical model can be reasonably applied to this case. Our improved version of Sanders' method and our definition of cluster member based on the principles of discriminatory analysis effectively exclude stars of low probabilities. It is important in the study of open cluster to use only those with high probabilities. The effectiveness of the statistical method is closely related to the velocity distributions of the member and field stars. For fields where the error rate is high, it is better to combine other data than proper motion in determining membership. 相似文献
In this paper the tidal phenomena on the Earth are concisely specified, including solid tides, ocean tides and atmospheric tides due to the luni-solar tide-generating force, and the Earth pole tide due to the motion of the Earth's rotation axis (polar motion); as well as their effects on the Earth rotation. The outcomes of scientific researches of Chinese astronomers on these topics are described in some detail. These researches deal with the mechanisms responsible for tidal effects on the earth rotation, and on the measurements of the Earth rotation parameters. Finally, the effects discovered by Chinese researchers on the measurements of the period and change in period of pulsars are discussed. These effects are very small in magnitude but not negligible. 相似文献