Stable isotope study of the Archaean rocks of the Vredefort impact structure,central Kaapvaal Craton,South Africa     

Åke Fagereng  Chris Harris  Mandy La Grange  Gary Stevens 《Contributions to Mineralogy and Petrology》2008,155(1):63-78

The Vredefort dome in the Kaapvaal Craton was formed as a result of the impact of a large meteorite at 2.02 Ga. The central core of Archaean granitic basement rocks is surrounded by a collar of uplifted and overturned strata of the Witwatersrand Supergroup, exposing a substantial depth section of the Archaean crust. Orthogneisses of the core show little variation in whole-rock δ ¹⁸O value, with the majority being between 8 and 10‰, with a mean of 9.2‰ (n = 35). Quartz and feldspar have per mil differences that are consistent with O-isotope equilibrium at high temperatures, suggesting minimal interaction with fluids during subsequent cooling. These data refute previous suggestions that the Outer Granite Gneiss (OGG) and Inlandsee Leucogranofels (ILG) of the core represent middle and lower crust, respectively. Granulite-facies greenstone remnants from the ILG have δ ¹⁸O values that are on average 1.5‰ higher than the ILG host rocks and are unlikely, therefore, to represent the residuum from the partial melting event that formed the host rock. Witwatersrand Supergroup sedimentary rocks of the collar, which were metamorphosed at greenschist-to amphibolite-facies conditions, generally have lower δ ¹⁸O values than the core rocks with a mean value for metapelites of 7.7‰ (n = 45). Overall, through an ∼20 km thick section of crust, there is a general increase in whole-rock δ ¹⁸O value with increasing depth. This is the reverse of what is normal in the crust, largely because the collar rocks have δ ¹⁸O values that are unusually low in comparison with metamorphosed sedimentary rocks worldwide. The collar rocks have δD values ranging from −35 to −115‰ (average −62‰, n = 29), which are consistent with interaction with water of meteoric origin, having a δD of about −25 to −45‰. We suggest that fluid movement through the collar rocks was enhanced by impact-induced secondary permeability in the dome structure. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

油田开发中后期岩相单元的细分研究   总被引：11，自引：0，他引：11  

撒利明  王天琦  师永民  鲁明春  杜文博 《沉积学报》2002,20(4):595-599

油田开发中后期建立在原小层对比和沉积微相基础上的储层地质模型已不能适应调整挖潜和剩余油分布研究的要求,需要在小层划分的基础上,进一步细分到岩相单元。本文以大庆长垣南部葡北油田葡I组油层为例提出岩相单元的概念,通过现代沉积研究论证岩相单元细分的可行性,结合密井网测井曲线分析旋回性、隔夹层分布的稳定性及目前经济技术和采油工艺等,探讨细分单元的基本原则。最后提出岩相单元细分的基本方法。  相似文献   

Free allocation in the 3rd EU ETS period: assessing two manufacturing sectors     

Christian Stenqvist  Max Åhman 《Climate Policy》2016,16(2):125-144

This article provides an analysis of the EU Emissions Trading Scheme (ETS) and the harmonized benchmark-based allocation procedures by comparing two energy-intensive sectors with activities in three Member States. These sectors include the cement industry (CEI) and the pulp and paper industry (PPI) in the UK, Sweden, and France. Our results show that the new procedures are better suited for the more homogeneous CEI, in which the outcome of stricter allocation of emissions allowances is consistent between Member States. For the more heterogeneous PPI – in terms of its product portfolios, technical infrastructures, and fuel mixes – the allocation procedures lead to diverse outcomes. It is the lack of product benchmark curves, and the alternative use of benchmark values that are biased towards a fossil fuel-mix and are based on specific energy use rather than emission intensity, which leads to allocations to the PPI that do not represent the average performance of the top 10% of GHG-efficient installations. Another matter is that grandfathering is still present via the historically based production volumes. How to deal with structural change and provisions regarding capacity reductions and partial cessation is an issue that is highly relevant for the PPI but less so for the CEI.

Policy relevance

After an unprecedented amount of consultation with industrial associations and other stakeholders, a harmonized benchmark-based allocation methodology was introduced in the third trading period of the EU ETS. Establishing a reliable and robust benchmark methodology for free allocation that shields against high direct carbon costs, is perceived as fair and politically acceptable, and still incentivizes firms to take action, is a significant challenge. This article contributes to a deeper understanding of the challenges in effectively applying harmonized rules in industrial sectors that are heterogeneous. This is essential for the debate on structural reformation of the EU ETS, and for sharing experiences with other emerging emissions trading systems in the world that also consider benchmark methodologies.  相似文献   

International and national climate policies for aviation: a review     

Jörgen Larsson  Anna Elofsson  Thomas Sterner  Jonas Åkerman 《Climate Policy》2019,19(6):787-799

Aviation constitutes about 2.5% of all energy-related CO₂ emissions and in addition there are non-CO₂ effects. In 2016, the ICAO decided to implement a Carbon Offsetting and Reduction Scheme for International Aviation (CORSIA) and in 2017 the EU decided on faster emission reductions in its Emissions Trading System (EU ETS), which since 2012 includes the aviation sector. The effects of these policies on the expected development of air travel emissions from 2017 to 2030 have been analyzed. For the sample country Sweden, the analysis shows that when emissions reductions in other sectors are attributed to the aviation sector as a result of the EU ETS and CORSIA, carbon emissions are expected to reduce by ?0.8% per year (however if non-CO₂ emissions are included in the analysis, then emissions will increase). This is much less than what is needed to achieve the 2°C target. Our analysis of potential national aviation policy instruments shows that there are legally feasible options that could mitigate emissions in addition to the EU ETS and CORSIA. Distance-based air passenger taxes are common among EU Member States and through increased ticket prices these taxes can reduce demand for air travel and thus reduce emissions. Tax on jet fuel is an option for domestic aviation and for international aviation if bilateral agreements are concluded. A quota obligation for biofuels is a third option.

Key policy insights

• Existing international climate policies for aviation will not deliver any major emission reductions.

• Policymakers who want to significantly push the aviation sector to contribute to meeting the 2°C target need to work towards putting in place tougher international policy instruments in the long term, and simultaneously implement temporary national policy instruments in the near-term.

• Distance-based air passenger taxes, carbon taxes on jet fuel and quota obligations for biofuels are available national policy options; if they are gradually increased, and harmonized with other countries, they can help to significantly reduce emissions.

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Terrestrial discharge influences microbioerosion and microbioeroder community structure in coral reefs     

SA Mwachireya  M Carreiro-Silva  BE Hartwick  TR McClanahan 《African Journal of Marine Science》2018,40(1):25-42

Microbioerosion rates and microbioeroder community structure were studied in four Kenyan protected coral-reef lagoons using shell fragments of Tridacna giant clams to determine their response to the influence of terrestrial run-off. Fourteen different microbioeroder traces from seven cyanobacteria, three green algae and four fungi species were identified. The river discharge-impacted reef and ‘pristine’ reef showed similar composition but higher microbioeroder abundance and total cyanobacteria- and chlorophyte-bioeroded areas when compared with the other study reefs. Cyanobacteria dominated during the north-east monsoon (NEM) relative to the south-east monsoon (SEM) season, with algae and cyanobacteria being major microbioeroders in the river-impacted and pristine reefs. The rate of microbioerosion varied between 4.3 g CaCO3 m^?2 y^?1 (SEM) and 134.7 g CaCO₃ m^?2 y^?1 (NEM), and was highest in the river-impacted reef (127.6 g CaCO₃ m^?2 y^?1), which was almost double that in the pristine reef (69.5 g CaCO₃ m^?2 y^?1) and the mangrove-fringed reef (56.2 g CaCO₃ m^?2 y^?1). The microbioerosion rates measured in this study may not be high enough to cause concern with regard to the health and net carbonate production of Kenya’s coral reefs. Nevertheless, predicted increases in the frequency and severity of stresses related to global climate change (e.g. increased sea surface temperature, acidification), as well as interactions with local disturbances and their influence on bioerosion, may be increasingly important in the future.  相似文献   

A Late Younger Dryas–Early Holocene tephrostratigraphy for Fosen,Central Norway     

EWA M. LIND  STEFAN WASTEGÅRD  JEPPE J. LARSEN 《第四纪科学杂志》2013,28(8):803-811

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A case study to verify methods for estimating transmissivity distributions along boreholes     

Åsa Fransson 《Hydrogeology Journal》2007,15(2):307-313

Two methods, both using data from fixed-interval-length hydraulic tests and geological mapping on different scales, have been utilised to estimate transmissivity distributions of individual fractures. Individual fracture properties are of importance in estimating transport of water and solutes; they influence the spreading of grout when sealing tunnels. One of the methods is non-parametric, while the other is based on combinatorics and the multiplication principle. The study verified the usefulness of both methods for estimating the probability of conductive and non-conductive fractures, and the transmissivity distributions. Data for estimating transmissivity distributions originate from flow logging of a borehole in Sweden. Fracture frequency data are from core logging and images using a borehole image processing system (BIPS). Estimated transmissivity distributions, based on flow log data from 3-m sections (test scale length, L: 3 m, and step length, dL: 3 m), were compared with transmissivities obtained directly from detailed, overlapping flow logging which identify individual conductive fractures (test scale, L: 0.5 m, step length, dL: 0.1 m). The latter data are considered to be an acceptable approximation of the individual fracture transmissivities; the agreement, compared with the calculated transmissivity distributions based on 3-m section data, is good for both methods.

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Resumen Se han utilizado dos métodos, ambos procesando datos de pruebas hidráulicas de longitud e intervalo fijo y mapas geológicos en distintas escalas, para estimar las distribuciones de transmisividad de fracturas individuales. Las propiedades de fracturas individuales son de importancia para estimar el transporte de agua y solutos; las propiedades influyen en la propagación de lechada al sellar túneles. Uno de los métodos es no paramétrico mientras que el otro se basa en el principio de multiplicación y combinatorio. El estudio verifica la utilidad de ambos métodos para estimar la probabilidad de fracturas conductivas y no conductivas y las distribuciones de transmisividad. Los datos para estimar las distribuciones de transmisividad se originan del registro de flujo de un pozo en Suecia. Los datos de frecuencia de fracturas provienen de registros de núcleo e imágenes usando un Sistema de Procesamiento de Imágenes de Pozo (BIPS). Se compararon las distribuciones estimadas de transmisividad basadas en datos del registro de flujo en secciones de 3 m (longitud de escala de la prueba L: 3 m, y escalón de longitud dL: 3 m), con transmisividades obtenidas directamente de registros detallados de flujo superpuesto el cual identifica fracturas conductivas individuales (escala de la prueba, L: 0.5 m, escalón de longitud, dL: 0.1 m). Los últimos datos se consideran una aproximación aceptable de las transmisividades de fracturas individuales; la consistencia, comparada con las distribuciones de transmisividad calculada basadas en datos de sección de 3 m, es buena para ambos métodos.

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Résumé Deux méthodes ont été testées afin d’estimer la distribution des transmissivités de fractures unitaires; toutes deux utilisent des données issues de tests hydrauliques effectués à intervalles réguliers et de cartographies géologiques à plusieurs échelles. La connaissance des propriétés des fractures unitaires est importante pour estimer le transport d’eau et de solutés; elles influencent en outre l’étalement du coulis lors du scellement des tunnels. La première méthode est non-paramétrique, et la seconde repose sur l’analyse combinatoire et le principe de multiplication. Cette étude a vérifié l’utilité des deux méthodes pour estimer la probabilité d’occurrence de fractures conductrices et non-conductrices, et la distribution des transmissivités. Les distributions des transmissivités ont été estimées à partir de diagraphies effectuées sur un forage situé en Suède. Les densités de fracturation proviennent de carottages et d’imagerie BIPS (Borehole Image Processing System). Les distributions estimées des transmissivités, basées sur des diagraphies de flux effectuées sur des sections de 3 m (échelle du test L:3 m; pas dL:3 m), ont été comparées aux transmissivités obtenues sur des diagraphies de flux détaillées et se chevauchant, identifiant les fractures conductrices unitaires (échelle du test L: 0.5 m ; pas dL: 0.1 m). Il est admis que ces dernières données représentent une approximation satisfaisante des transmissivités des fractures unitaires; les deux méthodes sont en accord avec les distributions des transmissivités calculées à partir des données acquises sur des sections de 3 m.

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Downscaling a twentieth century global climate simulation to the North Sea   总被引：2，自引：1，他引：2  

Bjørn Ådlandsvik  Mats Bentsen 《Ocean Dynamics》2007,57(4-5):453-466

The regional ocean model system (ROMS) is used to downscale a 26-year period of the twentieth century 20C3M experiment from the global coupled Bergen climate model (BCM) for the North Sea. Compared to an observational-based climatology, BCM have good results on the mean temperature, except for too low winter temperature. This is connected to a too weak inflow of Atlantic water. The downscaling gives added value to the BCM results by providing regional details, doubling the Atlantic inflow, and improving the mean winter temperature. For mean salinity, BCM has values very close to the climatology, whereas the downscaling becomes too fresh. The downscaling, however, improves the sea surface salinity, the vertical structure, and the Norwegian Coastal Current. It is concluded that the downscaling procedure as presented here is a suitable tool for assessing the future Atlantic inflow and sea temperature in the North Sea based on a global climate projection.  相似文献   

Mobility of Al, Co, Cr, Cu, Fe, Mn, Ni and V in sulphide-bearing fine-grained sediments exposed to atmospheric O2: an experimental study   总被引：1，自引：0，他引：1  

Mats Åström 《Environmental Geology》1998,36(3-4):219-226

 The major aim was to increase our knowledge on the behaviour of Al, Co, Cr, Cu, Fe, Mn, Ni and V in sulphide-bearing fine-grained sediments exposed to atmospheric oxygen. Samples of this type of sediment collected in a previous investigation at eight sites in western Finland were digested in HClO₄-HNO₃-HCl-HF at 200  °C and in HCl:HNO₃:H₂O at 95  °C (aqua regia), and subjected to extractions with ammonium acetate and hydrogen peroxide. Metals and S in the leachates were determined with ICP-AES. The results of the chemical analyses are compared with previously reported experimental data. The concentrations of Al and Fe in the sulphide-bearing fine-grained sediments are about 7% and 5%, respectively. Of the trace metals studied, Mn is most abundant followed in decreasing order by V>Cr>Ni>Cu>Co. On oxidation of the sediments, high proportions of Co, Mn and Ni, intermediate proportions of Cu but low proportions of Fe, Al, Cr and V are released. The extent of the release of a metal on oxidation is controlled either by (1) the level to which the pH of the sediments drops on oxidation (Al, Cu, Cr, V), (2) the amount of the metal associated with easily reduced phases (metal sulphides) in the sediments (Ni, Co) or (3) the sum of the amount associated with reduced phases and adsorbed on soil compounds (Mn). No control of the release of Fe on oxidation of the sediments was identified. Based on the results of the study it is argued that artificial drainage and the subsequent oxidation of sulphide-bearing sediments will result in extensive leaching of Co, Mn and Ni, moderate leaching of Cu and limited leaching of Cr and V into drainages. The major elements, Fe and Al, have the potential to be mobilised and leached in large amounts, though the proportions mobilised/leached will remain low. It is suggested that the identification of sulphide-bearing sediments with a high potential of metal release should be based on determination of metals in easily mobilised reduced compounds (dissolved e.g. in H₂O₂) and of the level to which the pH of the sediments drops on oxidation. Received: 16 October 1997 · Accepted: 9 March 1998  相似文献   

Sampling and Characterizing Rare Earth Elements in Groundwater in Deep-Lying Fractures in Granitoids Under In Situ High-Pressure and Low-Redox Conditions     

Linda J. Alakangas  Frédéric A. Mathurin  Mikko Faarinen  Bill Wallin  Mats E. Åström 《Aquatic Geochemistry》2014,20(4):405-418

Several countries are preparing to dispose of radioactive nuclear waste deep underground in crystalline rock. This type of bedrock is commonly extensively fractured and consequently carries groundwater that serves as a medium for transporting metals and radionuclides. A group of metals of particular interest in this context is the rare earth elements (REEs), because they are analogues of actinides contained within radioactive waste and are tracers of hydrological pathways and geochemical processes. Concentrations of REEs are commonly low in these groundwaters, leading to values below detection limits of standard monitoring methods, particularly for the heavy REEs. We present a new technical set-up for monitoring REEs (and other trace metals) in groundwater in fractured crystalline rock. The technique consists of passing the fracture groundwater, commonly under high pressure and containing reduced chemical species, through a device that maintains the physicochemical character of the groundwater. Within the device, diffusive gradient in thin-film (DGT) discs are installed in triplicate. With this set-up, we studied REEs in groundwater in fractures at depths of approximately ?144, ?280, and ?450 m in granitoids in the Äspö Hard Rock Laboratory in southern Sweden. The entire REE suite was detected (concentrations down to 0.1 ng L^?1) and was differently fractionated among the groundwaters. The shallowest groundwater, composed of dilute modern Baltic Sea water, was enriched in the heavy REEs, whereas the deeper groundwaters, dominated by old saline water, were depleted in the heavy REEs. Deployment periods varying from 1 to 4 weeks delivered similar REE concentrations, indicating stability and reproducibility of the experimental set-up. The study finds that 1 week of deployment may be enough. However, if the overall setting and construction allow for longer deployment times, 2–3 weeks will be optimal in terms of reaching reliable REE concentrations well above the detection limit while maintaining the performance of the DGT samplers.  相似文献