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1.
The pyroclastic flow that issued from the Arenal summit crater on 28 August 1993 came from the collapse of the crater wall of the cone and the drainage of a lava pool. The 3-km-long pyroclastic flow, 2.2ǂ.8᎒6 m3 in volume, was confined to narrow valleys (30-100 m wide). The thickness of the pyroclastic deposit ranged from 1 to 10 m, and its temperature was about 400 °C, although single bombs were up to 1,000 °C. The deposit is clast-supported, has a bimodal grain size distribution, and consists of an intimate mixture of finely pulverized rock ash, lapilli, small blocks, and cauliflower bread-crusted bombs, in which are set meter-size lava fragments and juvenile and non-juvenile angular blocks, and bombs up to 7 m in diameter. Large faceted blocks make up 50% of the total volume of the deposit. The cauliflower bombs have deep and intricate bread-crust texture and post-depositional vesiculation. It is proposed that the juvenile material was produced entirely from a lava pool, whereas faceted non-juvenile blocks come from the crater-wall collapse. The concentration and maximum diameter of cauliflower bread-crusted bombs increases significantly from the base (rockslide + pyroclastic flow) to the top (the pyroclastic flow) of the deposit. An ash cloud deposited accretionary lapilli in the proximal region (outside of the pyroclastic flow deposit), and very fine ash fell in the distal region (between 5 and 30 km). The accretionary lapilli deposit is derived from the fine, elutriated products of the flow as it moved. A turbulent overriding surge blew down the surrounding shrubbery in the flow direction. The pyroclastic flow from August 1993, similar to the flows of June 1975, May 1998, August 2000, and March 2001, slid and rolled rather than being buoyed up by gas. They grooved, scratched, and polished the surfaces over which they swept, similar to a Merapi-type pyroclastic flow. However, the mechanism of the outpouring of a lava pool and the resulting flows composed of high- to moderate-vesiculated, cauliflower bread-crusted bombs and juvenile blocks have not been described before. High-frequency earthquake swarms, followed by an increase in low-frequency volcanic events, preceded the 1975, 1993, and 2000 eruptions 2-4 months before. These pyroclastic flow events, therefore, may be triggered by internal expansion of the unstable cone in the upper part because of a slight change in the pressure of the magma column (gas content and/or effusive rate). This phenomenon has important short-term, volcanic hazard implications for touristic development of some parts on the flanks of the volcano.  相似文献   
2.
 Acid mine drainage (AMD) occurs when sulfide minerals are exposed to an oxidizing environment. Most of the methods for preventing AMD are either short-term or high cost solutions. Coating with iron phosphate is a new technology for the abatement of AMD. It involves treating the sulfide with a coating solution composed of H2O2, KH2PO4, and sodium acetate as a buffer agent. The H2O2 oxidizes the sulfide surface and produces Fe3+ so that iron phosphate precipitates as a coating on the sulfide surface. Experiments performed under laboratory conditions prove that an iron phosphate coating can be established on pyrrhotite surfaces with optimal concentrations of the coating solution in the range of: 0.2M/0.01M H2O2, 0.2M KH2PO4, and 0.2M sodium acetate NaAc, depending on the experimental scale. Iron phosphate coating may be a long-term solution to the problem of AMD. The method would be easy to implement; the reagent cost, however, is not low enough, although it is lower than the conventional treatment with lime. Received: 30 March 1995 · Accepted: 6 September 1995  相似文献   
3.
A model to simulate 137Cs profiles in soils during the time in which they are being eroded is proposed. The model uses one parameter to characterize the cesium transference in the soil and another to express the erosion rate. To test the model, 137Cs profiles of stable and eroded soils were collected at sampling sites located on semi-arid and temperate slopes in the Central Ebro basin, Spain. The 137Cs profiles, corresponding to uncultivated soils with natural vegetation cover, were simulated using this model. The 137Cs inventories and profiles calculated with the model are very similar to those measured experimentally, and thus it is possible to calculate soil erosion rates in physiographically diverse Mediterranean environments.  相似文献   
4.
An analysis of Anisotropy of Magnetic Susceptibility was done on Aptian–Albian sediments from the Basque–Cantabrian basin. Samples were collected from 39 sites in the halokinetic sequences of the Bakio, Bermeo, Guernica and Mungia diapirs; 28 sites were sampled close to diapirs, and 11 sites were far from the diapir edges. The magnetic foliation is parallel to bedding, suggesting it reflects depositional and compaction processes, whereas the orientation of magnetic lineation varies. Far from the diapir edges, the magnetic lineation is interpreted as being related to the regional Pyrenean compression. Close to diapir edges, the observed behaviour shows that diapirs, predominantly formed by rigid ophites, have acted as buttresses, with shadow areas at their northern faces being protected from the Pyrenean compression. The high sensitivity of AMS makes it a very useful tool to distinguish deformation in halokinetic sequences related to diapir growth from that related to subsequent compression.  相似文献   
5.
Metal loads were determined from water samples collected under different streamflow conditions (baseflow and storm events) in a rural catchment (NW Spain) during 4 years. A study at annual, seasonal and storm‐event scales was carried out. In all analysed scales, the export order was Fe > Al > Mn > Zn > Cu. A high inter‐annual, seasonal and storm‐event scale variability of metal load was observed. The total metal loads in stream were higher during baseflow conditions than during storm events, which only represented 4% of the duration of the study period and 25% of streamflow. During storm events, both Al and Fe loads accounted 45% of the total load of the study period, whereas Mn, Cu and Zn loads represented 42%, 33% and 24%, respectively. This highlights the role of high flows on metal export. Only four big events exported around 30% of load of each metal transported in events. At all time scales, a prevalence of export of particulate metals over dissolved metals was observed, more pronounced for Al, Fe and Mn than for Cu and Zn. The export of metals in the Corbeira catchment is influenced by runoff and, to a lesser extent, by the rainfall amount. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
6.
In this work we analyse and check the results of anisotropy of magnetic susceptibility (AMS) by means of a comparison with palaeostress orientations obtained from the analysis of brittle mesostructures in the Cabuérniga Cretaceous basin, located in the western end of the Basque–Cantabrian basin, North Spain. The AMS data refer to 23 sites including Triassic red beds, Jurassic and Lower Cretaceous limestones, sandstones and shales. These deposits are weakly deformed, and represent the syn-rift sequence linked to basins formed during the Mesozoic and later inverted during the Pyrenean compression. The observed magnetic fabrics are typical of early stages of deformation, and show oblate, triaxial and prolate magnetic ellipsoids. The magnetic fabric seems to be related to a tectonic overprint of an original, compaction, sedimentary fabric. Most sites display a NE–SW magnetic lineation that is interpreted to represent the stretching direction of the Early Cretaceous extensional stage of the basin, without recording of the Tertiary compressional events, except for sites with compression-related cleavage.Brittle mesostructures include normal faults, calcite and quartz tension gashes and joints, related to the extensional stage. The results obtained from joints and tension gashes show a dominant N–S to NE–SW, and secondary NW–SE, extension direction. Paleostresses obtained from fault analysis (Right Dihedra and stress inversion methods) indicate NW–SE to E–W, and N–S extension direction. The results obtained from brittle mesostructures show a complex pattern resulting from the superposition of several tectonic processes during the Mesozoic, linked to the tectonic activity related to the opening of the Bay of Biscay during the Early Cretaceous. This work shows the potential in using AMS analysis in inverted basins to unravel its previous extensional history when the magnetic fabric is not expected to be modified by subsequent deformational events. Brittle mesostructure analysis seems to be more sensitive to far-field stress conditions and record longer time spans, whereas AMS records deformation on the near distance, during shorter intervals of time.  相似文献   
7.
The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm3 molecule−1 s−1). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO3, O3 and Cl have been calculated.  相似文献   
8.
Nonlinear finite element (FE) modeling has been widely used to investigate the effects of seismic isolation on the response of bridges to earthquakes. However, most FE models of seismic isolated bridges (SIB) have used seismic isolator models calibrated from component test data, while the prediction accuracy of nonlinear FE models of SIB is rarely addressed by using data recorded from instrumented bridges. In this paper, the accuracy of a state‐of‐the‐art FE model is studied through nonlinear FE model updating (FEMU) of an existing instrumented SIB, the Marga‐Marga Bridge located in Viña del Mar, Chile. The seismic isolator models are updated in 2 phases: component‐wise and system‐wise FEMU. The isolator model parameters obtained from 23 isolator component tests show large scatter, and poor goodness of fit of the FE‐predicted bridge response to the 2010 Mw 8.8 Maule, Chile Earthquake is obtained when most of those parameter sets are used for the isolator elements of the bridge model. In contrast, good agreement is obtained between the FE‐predicted and measured bridge response when the isolator model parameters are calibrated using the bridge response data recorded during the mega‐earthquake. Nonlinear FEMU is conducted by solving single‐ and multiobjective optimization problems using high‐throughput cloud computing. The updated FE model is then used to reconstruct response quantities not recorded during the earthquake, gaining more insight into the effects of seismic isolation on the response of the bridge during the strong earthquake.  相似文献   
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