During an international workshop at the Institute for Experimental Physics of the University of Vienna, Austria, which was coordinated within the Committee on Nucleation and Atmospheric Aerosols (IAMAS-IUGG), 10 instruments for aerosol number concentration measurement were studied, covering a wide range of methods based on various different measuring principles. In order to investigate the detection limits of the instruments considered with respect to particle size, simultaneous number concentration measurements were performed for monodispersed aerosols with particle sizes ranging from 1.5 to 50 nm diameter and various compositions.The instruments considered show quite different response characteristics, apparently related to the different vapors used in the various counters to enlarge the particles to an optically detectable size. A strong dependence of the 50% cutoff diameter on the particle composition in correlation with the type of vapor used in the specific instrument was found. An enhanced detection efficiency for ultrafine hygroscopic sodium chloride aerosols was observed with water operated systems, an analogous trend was found for n-butanol operated systems with nonhygroscopic silver and tungsten oxide particles. 相似文献
Recognising the importance of understanding sediment dynamics to evaluate the status of a coastal lagoon environment, this work has been focused on the investigation of the hydrodynamic and sediment transport processes occurring in such basins. In order to describe the lagoon system, a modelling approach combining hydrodynamics, waves and sediment dynamics has been developed. The framework of the numerical model consists of a finite element hydrodynamic model, a third generation finite element spectral wave model and a sediment transport and morphodynamic model for both cohesive and non-cohesive sediments. The model adopts the finite element technique for spatial integration, which has the advantage to describe more accurately complicated bathymetry and irregular boundaries for shallow water areas. The developed model has been applied to test cases and to a very shallow tidal lagoon, the Venice Lagoon, Italy. Numerical results show good agreement with water level, waves and turbidity measurements collected in several monitoring stations inside the Lagoon of Venice. Such a model represents an indispensable tool in analysing coastal problems and assessing morphological impacts of human interference. 相似文献
Heterogeneous nucleation of supersaturated n-nonane vapour on seed particles of different size and composition has been investigated using a fast expansion chamber. Monodisperse seed particle sizes were ranging from about 4 nm up to about 24 nm in diameter. By using different types of particle generators WOx, Ag and (NH4)2SO4 particles were generated. For direct comparison between different particle compositions overlapping sizes have been generated for WOx and Ag at about 7 nm particle diameter as well as for Ag and (NH4)2SO4 at about 15 nm. Nucleation temperature was kept constant at about 278 K. Experimental data were compared to Kelvin equation and Fletcher theory including the effect of line tension. It was found that heterogeneous nucleation of n-nonane seems to be independent of seed particle composition and starts well below the Kelvin curve. Good agreement was achieved with Fletcher theory including the effect of line tension. 相似文献
The karsted limestone valleys of central Pennsylvania contain two populations of sinkholes. Solution sinkholes occur in the
Champlainian limestone units along the margins of the valleys. Solution sinkholes are permanent parts of the landscape and,
although a nuisance to construction, do not present other problems. The second population is the suffosional or soil-piping
sinkholes These occur on all carbonate rock units including the Beekmantown and Gatesburg dolomites that comprise the two
principal carbonate aquifers in the valley. Suffosional sinkholes are the principal land-use hazard.
Suffosional sinkholes are transient phonomena. They occur naturally but are exacerbated by runoff modifications that accompany
urbanization Suffosional sinkholes are typically 1.5–2.5 m in diameter depending on soil thickness and soil type. The vertical
transport of soil to form the void space and soil arch that are the precursors to sinkhole collapse is through solutionally
widened fractures and cross-joints and less often through large vertical openings in the bedrock. The limited solution development
on the dolomite bedrock combined with soil thickness, seldom greater than 2 m, limits the size of the sinkholes. All aspects
of suffosional sinkhole development are shallow processes: transport, piping, void and arch formation, and subsequent collapse
take place usually less than 10 m below the land surface
Factors exacerbating sinkhole development include pavement, street, and roof runoff which accelerates soil transport Such
seemingly minor activities as replacing high grass and brush with mowed grass is observed to accelerate sinkhole development.
Dewatering of the aquifer is not a major factor in this region 相似文献
Two water samples from the Great Dismal Swamp National Wildlife Refuge with high dissolved organic matter (DOM) concentrations (51 and 121 mg C L?1) were subjected to ultraviolet (UV) light for up to 110 days. During the course of the irradiations, 74–88 % of the original dissolved organic carbon was lost along with 95–99 % of the absorption at 300 nm. Based on changes observed during light exposure, three pools of DOM were identified: photo-labile, photo-refractory, and photo-produced compounds. Solid-state 13C nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FTIR) spectroscopy were used to determine structural moieties characteristic to each of these pools. These analyses showed aromatic carbons were preferentially removed while carbohydrate-like and amide/peptide-like carbons were preserved during UV exposure. An increase in carbon normalized 13C NMR signal in the 0–50 ppm region suggests that alkyl moieties were produced, while FTIR signal at 1,745 cm?1 and two-dimensional 1H–13C NMR results confirmed the photochemical production of acetate. Several properties typically used to trace terrigenous DOM in ocean margin and marine environments were significantly altered. Optical properties, including absorption spectral slopes and fluorescence indices, as well as carbon-normalized lignin yields shifted from terrestrial values towards those more typical of coastal or open ocean samples. The loss of terrestrial signatures during irradiation highlights the difficulty faced when quantifying the contribution of terrigenous DOM to aquatic carbon pools. 相似文献
With sea levels projected to rise as a result of climate change, it is imperative to understand not only long-term average trends, but also the spatial and temporal patterns of extreme sea level. In this study, we use a comprehensive set of 30 tide gauges spanning 1954–2014 to characterize the spatial and temporal variations of extreme sea level around the low-lying and densely populated margins of the South China Sea. We also explore the long-term evolution of extreme sea level by applying a dynamic linear model for the generalized extreme value distribution (DLM-GEV), which can be used for assessing the changes in extreme sea levels with time. Our results show that the sea-level maxima distributions range from ~?90 to 400 cm and occur seasonally across the South China Sea. In general, the sea-level maxima at northern tide gauges are approximately 25–30% higher than those in the south and are highest in summer as tropical cyclone-induced surges dominate the northern signal. In contrast, the smaller signal in the south is dominated by monsoonal winds in the winter. The trends of extreme high percentiles of sea-level values are broadly consistent with the changes in mean sea level. The DLM-GEV model characterizes the interannual variability of extreme sea level, and hence, the 50-year return levels at most tide gauges. We find small but statistically significant correlations between extreme sea level and both the Pacific Decadal Oscillation and El Niño/Southern Oscillation. Our study provides new insight into the dynamic relationships between extreme sea level, mean sea level and the tidal cycle in the South China Sea, which can contribute to preparing for coastal risks at multi-decadal timescales.