The geochemistry of gem opals as evidence of their origin     

Eloïse Gaillou  Aurlien Delaunay  Benjamin Rondeau  Martine Bouhnik-le-Coz  Emmanuel Fritsch  Guy Cornen  Christophe Monnier 《Ore Geology Reviews》2008,34(1-2):113

Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si⁴⁺ by Al³⁺ and Fe³⁺. The induced charge imbalance is compensated chiefly by Ca²⁺, Mg²⁺, Mn²⁺, Ba²⁺, K⁺, and Na⁺. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence.  相似文献   

Prediction of river water temperature: a comparison between a new family of hybrid models and statistical approaches          下载免费PDF全文

Sebastiano Piccolroaz  Elisa Calamita  Bruno Majone  Aurélien Gallice  Annunziato Siviglia  Marco Toffolon 《水文研究》2016,30(21):3901-3917

River water temperature is a key physical variable controlling several chemical, biological and ecological processes. Its reliable prediction is a main issue in many environmental applications, which however is hampered by data scarcity, when using data‐demanding deterministic models, and modelling limitations, when using simpler statistical models. In this work we test a suite of models belonging to air2stream family, which are characterized by a hybrid formulation that combines a physical derivation of the key equation with a stochastic calibration of parameters. The air2stream models rely solely on air temperature and streamflow, and are of similar complexity as standard statistical models. The performances of the different versions of air2stream in predicting river water temperature are compared with those of the most common statistical models typically used in the literature. To this aim, a dataset of 38 Swiss rivers is used, which includes rivers classified into four different categories according to their hydrological characteristics: low‐land natural rivers, lake outlets, snow‐fed rivers and regulated rivers. The results of the analysis provide practical indications regarding the type of model that is most suitable to simulate river water temperature across different time scales (from daily to seasonal) and for different hydrological regimes. A model intercomparison exercise suggests that the family of air2stream hybrid models generally outperforms statistical models, while cross‐validation conducted over a 30‐year period indicates that they can be suitably adopted for long‐term analyses. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

External controls on the distribution,fabrics and mineralization of modern microbial mats in a coastal hypersaline lagoon,Cayo Coco (Cuba)   总被引：1，自引：0，他引：1       下载免费PDF全文

Anthony Bouton  Emmanuelle Vennin  Aurélie Pace  Raphaël Bourillot  Christophe Dupraz  Christophe Thomazo  Arnaud Brayard  Guy Désaubliaux  Pieter T. Visscher 《Sedimentology》2016,63(4):972-1016

Active, carbonate‐mineralizing microbial mats flourish in a tropical, highly evaporative, marine‐fed lagoonal network to the south of Cayo Coco Island (Cuba). Hypersaline conditions support the development of a complex sedimentary microbial ecosystem with diverse morphologies, a variable intensity of mineralization and a potential for preservation. In this study, the role of intrinsic (i.e. microbial) and extrinsic (i.e. physicochemical) controls on microbial mat development, mineralization and preservation was investigated. The network consists of lagoons, forming in the interdune depressions of a Pleistocene aeolian substratum; they developed due to a progressive increase in sea‐level since the Holocene. The hydrological budget in the Cayo Coco lagoonal network changes from west to east, increasing the salinity. This change progressively excludes grazers and increases the saturation index of carbonate minerals, favouring the development and mineralization of microbial mats in the easternmost lagoons. Detailed mapping of the easternmost lagoon shows four zones with different flooding regimes. The microbial activity in the mats was recorded using light–dark shifts in conjunction with microelectrode O₂ and HS^? profiles. High rates of O₂ production and consumption, in addition to substantial amounts of exopolymeric substances, are indicative of a potentially strong intrinsic control on mineralization. Seasonal, climate‐driven water fluctuations are key for mat development, mineralization, morphology and distribution. Microbial mats show no mineralization in the permanently submersed zone, and moderate mineralization in zones with alternating immersion and exposure. It is suggested that mineralization is also driven by water‐level fluctuations and evaporation. Mineralized mats are laminated and consist of alternating trapping and binding of grains and microbially induced magnesium calcite and dolomite precipitation. The macrofabrics of the mats evolve from early colonizing Flat mats to complex Cerebroid or Terrace structures. The macrofabrics are influenced by the hydrodynamic regime: wind‐driven waves inducing relief terraces in windward areas and flat morphologies on the leeward side of the lagoon. Other external drivers include: (i) storm events that either promote (for example, by bioclasts covering) or prevent (for example, by causing erosion) microbial mat preservation; and (ii) subsurface degassing, through mangrove roots and desiccation cracks covered by Flat mats (i.e. forming Hemispheroids and Cerebroidal structures). These findings provide in‐depth insights into understanding fossil microbialite morphologies that formed in lagoonal settings.  相似文献   

Oxygen and organic carbon fluxes in sediments of the Bay of Biscay     

Aurélia Mouret  Pierre Anschutz  Bruno Deflandre  Gwénaëlle Chaillou  Christelle Hyacinthe  Jonathan Deborde  Henri Etcheber  Jean-Marie Jouanneau  Antoine Grémare  Pascal Lecroart 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(4):528-540

The relationship between particulate organic carbon (POC) concentrations measured in modern sediment and fluxes of exported POC to the sediment surface needs to be understood in order to use POC content as a proxy of paleo-environmental conditions. The objective of our study was to compare POC concentrations, POC mineralization rates calculated from O₂ consumption and POC burial rates. Benthic O₂ distributions were determined in 58 fine-grained sediment cores collected at different periods at 14 stations in the southeastern part of the Bay of Biscay with depths ranging from 140 to 2800 m. Depth-dependent volume-specific oxygen consumption rates were used to assess rates of aerobic oxidation of organic matter (OM), assuming that O₂ consumption solely was related to heterotrophic activity at the sediment–water interface. Heterogeneity of benthic O₂ fluxes denoted changes in time and space of fresh organic material sedimentation. The most labile fraction of exported POC engendered a steep decrease in concentration in the upper 5 mm of vertical O₂ profiles. The rupture in the gradient of O₂ microprofile may be related to the bioturbation-induced mixing depth of fast-decaying carbon. Average diffusive O₂ fluxes showed that this fast-decaying OM flux was much higher than buried POC, although diffusive O₂ fluxes underestimated the total sediment oxygen demand, and thus the fast-decaying OM flux to the sediment surface. Sedimentary POC burial was calculated from sediment mass accumulation rate and the organic carbon content measured at the top of the sediment. The proportion of buried POC relative to total exported POC ranged at the most between 50% and 10%, depending on station location. Therefore, for a narrow geographic area like the Bay of Biscay, burial efficiency of POC was variable. A fraction of buried POC consisted of slow-decaying OM that was mineralized within the upper decimetres of sediment through oxic and anoxic processes. This fraction was deduced from the decrease with depth in POC concentration. At sites located below 500 m water depth, where the fast-decaying carbon did not reach the anoxic sediment, the slow-decaying pool may control the O₂ penetration depth. Only refractory organic material was fossilized in sedimentary records at locations where labile OM did not reach the anoxic portion of the sediment.  相似文献   

Accumulation,solid partitioning and remobilisation of 99Tc in subtidal and intertidal sediments in the Irish Sea     

Paul Finegan  Luis León Vintró  Peter I. Mitchell  Dominique Boust  Aurélien Gouzy  Peter J. Kershaw  Julie A. Lucey 《Continental Shelf Research》2009,29(16):1995-2010

Recent studies have shown that accumulation of ⁹⁹Tc in seabed sediments labelled by authorised radioactive liquid discharges into the NE Irish Sea from the Sellafield reprocessing complex is greater than previously thought. In this paper, new data on ⁹⁹Tc concentration profiles in subtidal and intertidal sediments from the eastern and western Irish Sea are provided with a view to elucidating the processes responsible for the incorporation and retention of ⁹⁹Tc in the seabed. The data show that substantial amounts of ⁹⁹Tc have accumulated in the fine-grained subtidal sediments off the Cumbrian coast, particularly after increased releases from Sellafield following the commissioning of the Enhanced Actinide Removal Plant (EARP) in 1994. In all the cores taken in this area, ⁹⁹Tc has been found to be present to depths in excess of 30 cm. Analysis of ¹³⁷Cs and ²⁴¹Am profiles, together with other supporting geochemical data, show a high degree of homogenisation of the sediments down to these depths as a result of physical and biological processes, and confirm that incorporation of ⁹⁹Tc into the sediment compartment is actually the result of mixing and reworking, rather than active sediment accumulation. In contrast, active deposition of material transported from this mixed pool of sediment appears to be the dominant mechanism controlling ⁹⁹Tc profiles in intertidal areas close to the Sellafield discharge outfall.Data obtained from the analysis of subtidal sediment cores from the western Irish Sea mud basin suggest that similar mixing processes to those occurring in the subtidal sediments of the eastern Irish Sea are also active in this area. Time-series data on ⁹⁹Tc concentrations in surficial sediments from this basin, gathered in the period 1988–2004, inclusive, show a clear increase in concentrations, by a factor of ～2, between samples collected pre-EARP and post-EARP. The constancy of ⁹⁹Tc concentrations in surface sediments throughout the 1980s and the early-1990s suggests that little redissolution and export of ⁹⁹Tc occurred over this extended period. A similar observation applies to the post-EARP period, when concentrations remained relatively constant despite the reported steady decrease in ⁹⁹Tc concentrations in the overlying waters.This apparent lack of remobilisation is consistent with data from sequential extraction analyses, which indicate that the bulk of the ⁹⁹Tc is strongly bound to non-labile geochemical phases, with only a small proportion associated with exchangeable and acido-soluble phases. Further, these analyses show that ⁹⁹Tc is not associated with oxygen-sensitive and highly-reactive acid-volatile sulphides (AVS) to any significant extent.  相似文献   

Envisat and SARAL/AltiKa Observations of the Antarctic Ice Sheet: A Comparison Between the Ku-band and Ka-band     

Frédérique Rémy  Thomas Flament  Aurélie Michel  Denis Blumstein 《Marine Geodesy》2015,38(3):510-521

The AltiKa altimeter onboard SARAL is a joint CNES/ISRO mission launched in February 2013 that has the same 35 days repeat orbit of the previous European altimeters, Envisat, and ERS-1/2. SARAL/AltiKa is thus a unique opportunity to extend the repeat observations of this orbit that have been surveyed since 1991. However, the altimeter operates in Ka-band, which is higher than the previous frequencies, and offers new paths of investigation. The penetration depth is theoretically reduced from around 10 m in Ku-band to less than 1 m in Ka-band, such that the volume echo originates from the near subsurface. Second, the sharper antenna aperture leads to a narrower leading edge that reduces the impact of the ratio between surface and volume echoes of the height retrieval. Indeed, the spatial and temporal observations of AltiKa at cross-over points and along-track indicate that the impact of backscatter changes on the height decreasesfrom 0.3 m/dB for the Ku-band to only 0.05 m/dB for the Ka-band. Therefore, the height measurement is stable over time. Moreover, the volume echo in the Ka-band results from the near subsurface layer and is mostly controlled by ice grain size, unlike the Ku-band.  相似文献   

Fundamental physics and absolute positioning metrology with the MAGIA lunar orbiter     

Simone Dell��Agnello  Caterina Lops  Giovanni O. Delle Monache  Douglas G. Currie  Manuele Martini  Roberto Vittori  Angioletta Coradini  Cesare Dionisio  Marco Garattini  Alessandro Boni  Claudio Cantone  Riccardo March  Giovanni Bellettini  Roberto Tauraso  Mauro Maiello  Luca Porcelli  Simone Berardi  Nicola Intaglietta 《Experimental Astronomy》2011,32(1):19-35

MAGIA is a mission approved by the Italian Space Agency (ASI) for Phase A study. Using a single large-diameter laser retroreflector, a large laser retroreflector array and an atomic clock onboard MAGIA we propose to perform several fundamental physics and absolute positioning metrology experiments: VESPUCCI, an improved test of the gravitational redshift in the Earth?CMoon system predicted by General Relativity; MoonLIGHT-P, a precursor test of a second generation Lunar Laser Ranging (LLR) payload for precision gravity and lunar science measurements under development for NASA, ASI and robotic missions of the proposed International Lunar Network (ILN); Selenocenter (the center of mass of the Moon), the determination of the position of the Moon center of mass with respect to the International Terrestrial Reference Frame/System (ITRF/ITRS); this will be compared to the one from Apollo and Lunokhod retroreflectors on the surface; MapRef, the absolute referencing of MAGIA??s lunar altimetry, gravity and geochemical maps with respect to the ITRF/ITRS. The absolute positioning of MAGIA will be achieved thanks to: (1) the laboratory characterization of the retroreflector performance at INFN-LNF; (2) the precision tracking by the International Laser Ranging Service (ILRS), which gives two fundamental contributions to the ITRF/ITRS, i.e. the metrological definition of the geocenter (the Earth center of mass) and of the scale of length; (3) the radio science and accelerometer payloads; (4) support by the ASI Space Geodesy Center in Matera, Italy. Future ILN geodetic nodes equipped with MoonLIGHT and the Apollo/Lunokhod retroreflectors will become the first realization of the International Moon Reference Frame (IMRF), the lunar analog of the ITRF.  相似文献   

Report of the IAU Working Group on Cartographic Coordinates and Rotational Elements: 2009   总被引：5，自引：0，他引：5  

B. A. Archinal  M. F. A��Hearn  E. Bowell  A. Conrad  G. J. Consolmagno  R. Courtin  T. Fukushima  D. Hestroffer  J. L. Hilton  G. A. Krasinsky  G. Neumann  J. Oberst  P. K. Seidelmann  P. Stooke  D. J. Tholen  P. C. Thomas  I. P. Williams 《Celestial Mechanics and Dynamical Astronomy》2011,109(2):101-135

Every three years the IAU Working Group on Cartographic Coordinates and Rotational Elements revises tables giving the directions of the poles of rotation and the prime meridians of the planets, satellites, minor planets, and comets. This report takes into account the IAU Working Group for Planetary System Nomenclature (WGPSN) and the IAU Committee on Small Body Nomenclature (CSBN) definition of dwarf planets, introduces improved values for the pole and rotation rate of Mercury, returns the rotation rate of Jupiter to a previous value, introduces improved values for the rotation of five satellites of Saturn, and adds the equatorial radius of the Sun for comparison. It also adds or updates size and shape information for the Earth, Mars?? satellites Deimos and Phobos, the four Galilean satellites of Jupiter, and 22 satellites of Saturn. Pole, rotation, and size information has been added for the asteroids (21) Lutetia, (511) Davida, and (2867) ?teins. Pole and rotation information has been added for (2) Pallas and (21) Lutetia. Pole and rotation and mean radius information has been added for (1) Ceres. Pole information has been updated for (4) Vesta. The high precision realization for the pole and rotation rate of the Moon is updated. Alternative orientation models for Mars, Jupiter, and Saturn are noted. The Working Group also reaffirms that once an observable feature at a defined longitude is chosen, a longitude definition origin should not change except under unusual circumstances. It is also noted that alternative coordinate systems may exist for various (e.g. dynamical) purposes, but specific cartographic coordinate system information continues to be recommended for each body. The Working Group elaborates on its purpose, and also announces its plans to occasionally provide limited updates to its recommendations via its website, in order to address community needs for some updates more often than every 3 years. Brief recommendations are also made to the general planetary community regarding the need for controlled products, and improved or consensus rotation models for Mars, Jupiter, and Saturn.  相似文献   

Angular momentum exchange during secular migration of two-planet systems     

Adri��n Rodr��guez  Tatiana A. Michtchenko  Octavio Miloni 《Celestial Mechanics and Dynamical Astronomy》2011,111(1-2):161-178

We investigate the secular dynamics of two-planet coplanar systems evolving under mutual gravitational interactions and dissipative forces. We consider two mechanisms responsible for the planetary migration: star-planet (or planet-satellite) tidal interactions and interactions of a planet with a gaseous disc. We show that each migration mechanism is characterized by a specific law of orbital angular momentum exchange. Calculating stationary solutions of the conservative secular problem and taking into account the orbital angular momentum leakage, we trace the evolutionary routes followed by the planet pairs during the migration process. This procedure allows us to recover the dynamical history of two-planet systems and constrain parameters of the involved physical processes.  相似文献   

Erratum to: Reports of the IAU Working Group on Cartographic Coordinates and Rotational Elements: 2006 & 2009     

B. A. Archinal  M. F. A��Hearn  A. Conrad  G. J. Consolmagno  R. Courtin  T. Fukushima  D. Hestroffer  J. L. Hilton  G. A. Krasinsky  G. Neumann  J. Oberst  P. K. Seidelmann  P. Stooke  D. J. Tholen  P. C. Thomas  I. P. Williams 《Celestial Mechanics and Dynamical Astronomy》2011,110(4):401-403

The primary poles for (243) Ida and (134340) Pluto and its satellite (134340) Pluto : I Charon were redefined in the IAU Working Group on Cartographic Coordinates and Rotational Elements (WGCCRE) 2006 report (Seidelmann et al. in Celest Mech Dyn Astr 98:155, 2007), and 2009 report (Archinal et al. in Celest Mech Dyn Astr 109:101, 2011), respectively, to be consistent with the primary poles of similar Solar System bodies. However, the WGCCRE failed to take into account the effect of the redefinition of the poles on the values of the rotation angle W at J2000.0. The revised relationships in Table 3 of Archinal et al. 2011) are $$\begin{array}{llll} W & = & 274^{\circ}.05 +1864^{\circ}.6280070\, d\;{\rm for\; (243)\,Ida} \\ W & = & 302^{\circ} .695 + 56^{\circ} .3625225\, d\;{\rm for\; (134340)\,Pluto,\; and}\\ W & = & 122^{\circ} .695 + 56^{\circ} .3625225\, d\;{\rm for\; (134340)\,Pluto : I \,Charon}\end{array}$$ where d is the time in TDB days from J2000.0 (JD2451545.0).  相似文献