Novae as Thermonuclear Laboratories     

D.D. Clayton 《Astrophysics and Space Science》2003,285(2):353-361

Fred Hoyle undertook a study of observational consequences of the thermonuclear paradigm for the nova event in the years following his 1972 resignation from Cambridge University. The most fruitful of these have been in the areas of gamma-ray astronomy, by which one attempts to measure the level of radioactivity in the nova envelope, and of presolar grain studies in laboratories, by which one measures anomalous isotopic ratios that fingerprint condensation in the thermonuclear event. This work summarizes progress with these two astronomical measures of the novae. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Geochemistry, petrology and ages of the lunar meteorites Kalahari 008 and 009: New constraints on early lunar evolution     

A.K. Sokol  V.A. Fernandes  T. Schulz  A. Bischoff  R.N. Clayton  K. Nishiizumi  L. Schultz  K. Mezger 《Geochimica et cosmochimica acta》2008,72(19):4845-4873

Kalahari 008 and 009 are two lunar meteorites that were found close to each other in Botswana. Kalahari 008 is a typical lunar anorthositic breccia; Kalahari 009 a monomict breccia with basaltic composition and mineralogy. Based on minor and trace elements Kalahari 009 is classified as VLT (very-low-Ti) mare basalt with extremely low contents of incompatible elements, including the REE. The Lu-Hf data define an age of 4286 ± 95 Ma indicating that Kalahari 009 is one of the oldest known basalt samples from the Moon. It provides evidence for lunar basalt volcanism prior to 4.1 Ga (pre-Nectarian) and may represent the first sample from a cryptomare. The very radiogenic initial ¹⁷⁶Hf/¹⁷⁷Hf (εHf = +12.9 ± 4.6), the low REE, Th and Ti concentrations indicate that Kalahari 009 formed from re-melting of mantle material that had undergone strong incompatible trace element depletion early in lunar history. This unusually depleted composition points toward a hitherto unsampled basalt source region for the lunar interior that may represent a new depleted endmember source for low-Ti mare basalt volcanism. Apparently, the Moon became chemically very heterogeneous at an early stage in its history and different cumulate sources are responsible for the diverse mare basalt types.Evidence that Kalahari 008 and 009 may be paired includes the similar fayalite content of their olivine, the identical initial Hf isotope composition, the exceptionally low exposure ages of both rocks and the fact that they were found close to each other. Since cryptomaria are covered by highland ejecta, it is possible that these rocks are from the boundary area, where basalt deposits are covered by highland ejecta. The concentrations of cosmogenic radionuclides and trapped noble gases are unusually low in both rocks, although Kalahari 008 contains slightly higher concentrations. A likely reason for this difference is that Kalahari 008 is a polymict breccia containing a briefly exposed regolith, while Kalahari 009 is a monomict brecciated rock that may never have been at the surface of the Moon.Altogether, the compositions of Kalahari 008 and 009 permit new insight into early lunar evolution, as both meteorites sample lunar reservoirs hitherto unsampled by spacecraft missions. The very low Th and REE content of Kalahari 009 as well as the depletion in Sm and the lack of a KREEP-like signature in Kalahari 008 point to a possible source far from the influence of the Procellarum-KREEP Terrane, possibly the lunar farside.  相似文献   

Uncertainty as the overlap of alternate conditional distributions     

Olena Babak  Clayton V. Deutsch 《Computational Geosciences》2008,12(4):503-512

An important task in modern geostatistics is the assessment and quantification of resource and reserve uncertainty. This uncertainty is valuable support information for many management decisions. Uncertainty at specific locations and uncertainty in the global resource is of interest. There are many different methods to build models of uncertainty, including Kriging, Cokriging, and Inverse Distance. Each method leads to different results. A method is proposed to combine local uncertainties predicted by different models to obtain a combined measure of uncertainty that combines good features of each alternative. The new estimator is the overlap of alternate conditional distributions.  相似文献   

Aqueous alteration of the Bali CV3 chondrite: evidence from mineralogy, mineral chemistry, and oxygen isotopic compositions     

Keller LP  Thomas KL  Clayton RN  Mayeda TK  DeHart JM  McKay DS 《Geochimica et cosmochimica acta》1994,58(24):5589-5598

A petrographic, geochemical, and oxygen isotopic study of the Bali CV3 carbonaceous chondrite revealed that the meteorite has undergone extensive deformation and aqueous alteration on its parent body. Deformation textures are common and include flattened chondrules, a well-developed foliation, and the presence of distinctive (100) planar defects in olivine. The occurrence of alteration products associated with the planar defects indicates that the deformation features formed prior to the episode of aqueous alteration. The secondary minerals produced during the alteration event include well-crystallized Mg-rich saponite, framboidal magnetite, and Ca-phosphates. The alteration products are not homogeneously distributed throughout the meteorite, but occur in regions adjacent to relatively unaltered material, such as veins of altered material following the foliation. The alteration assemblage formed under oxidizing conditions at relatively low temperatures (<100 degrees C). Altered regions in Bali have higher Na, Ca, and P contents than unaltered regions which suggests that the fluid phase carried significant dissolved solids. Oxygen isotopic compositions for unaltered regions in Bali fall within the field for other CV3 whole-rocks, however, the oxygen isotopic compositions of the heavily altered material lie in the region for the CM and CR chondrites. The heavy-isotope enrichment of the altered regions in Bali suggest alteration conditions similar to those for the petrographic type-2 carbonaceous chondrites.  相似文献   

Solar system isotopic anomalies: Supernova neighbor or presolar carriers?     

Donald D. Clayton 《Icarus》1977,32(3):255-269

I evaluate several nuclear and chemical problems related both to the recent scenario suggesting that the known isotopic anomalies in the solar system have resulted from a supernova near the protosolar nebula and to the model of extinct presolar carriers. Major features include: (1) Large quantities of extinct ²⁴⁸Cm and ³⁶Cl are predicted from the Cameron-Truran model of a minor injection about 10⁶ yr before condensation; (2) an extinct-carrier model of ²⁶Mg is set forth in detail with a solid chemistry picture of the early solar system; (3) a major thermonuclear supernova responsible for ²⁶Al, ²⁴⁴Pu, and ⁴⁰K would have to have occurred several million years (3 m.y.) before condensation and contributed a large fraction of the major stable chemical elements; (4) carbon isotope families are to be expected if the oxygen isotope families are due to a late injection of ¹⁶O; (5) the Earth and E meteorites may have condensed primarily in a carbon-rich nebula existing before admixtures of a major late ¹⁶O-rich mixture; (6) the extinct-presolar-carrier model is the single best explanation of all anomalies.  相似文献   

Size Scaling of Cross Correlation Between Multiple Variables     

Oz  Bora  Deutsch  Clayton V. 《Natural Resources Research》2002,11(1):1-18

Reservoir models have large uncertainty because of spatial variability and limited sample data. The ultimate aim is to use simultaneously all available data sources to reduce uncertainty and provide reliable reservoir models for resource assessment and flow simulation. Seismic impedance or some other attribute provides a key source of data for reservoir modeling. These seismic data are at a coarser scale than the hard well data and it not an exact measurement of facies proportions or porosity. A requirement for data integration is the cross-covariance between the well and seismic data.The size-scaling behavior of the cross correlation for different measurement scales was nvestigated. The size-scaling relationship is derived theoretically and validated by numerical studies (including an example with real data). The limit properties of the cross-correlation coefficient when the averaging volume becomes large is shown. After some averaging volume, the volume-dependent cross-correlation coefficient reaches a limit value. This plateau value is controlled mainly by the large-scale behavior of the cross and direct variograms.The cross correlation can increase or decrease with volume support depending on the relative importance of long- and short-scale covariance structures. If the direct and cross variograms are proportional, there is no change in the cross correlation as the averaging volume changes. Our study shows that the volume-dependent cross-correlation coefficient is sensitive to the shape of the cross variogram and differences between the direct variograms of the well data and seismic data.  相似文献   

Stepwise Conditional Transformation for Simulation of Multiple Variables   总被引：4，自引：0，他引：4  

Oy Leuangthong  Clayton V. Deutsch 《Mathematical Geology》2003,35(2):155-173

Most geostatistical studies consider multiple-related variables. These relationships often show complex features such as nonlinearity, heteroscedasticity, and mineralogical or other constraints. These features are not handled by the well-established Gaussian simulation techniques. Earth science variables are rarely Gaussian. Transformation or anamorphosis techniques make each variable univariate Gaussian, but do not enforce bivariate or higher order Gaussianity. The stepwise conditional transformation technique is proposed to transform multiple variables to be univariate Gaussian and multivariate Gaussian with no cross correlation. This makes it remarkably easy to simulate multiple variables with arbitrarily complex relationships: (1) transform the multiple variables, (2) perform independent Gaussian simulation on the transformed variables, and (3) back transform to the original variables. The back transformation enforces reproduction of the original complex features. The methodology and underlying assumptions are explained. Several petroleum and mining examples are used to show features of the transformation and implementation details.  相似文献   

Oxygen isotope salt effects at high pressure and high temperature and the calibration of oxygen isotope geothermometers     

Guixing Hu  Robert N. Clayton 《Geochimica et cosmochimica acta》2003,67(17):3227-3246

The influence of NaCl, CaCl₂, and dissolved minerals on the oxygen isotope fractionation in mineral-water systems at high pressure and high temperature was studied experimentally. The salt effects of NaCl (up to 37 molal) and 5-molal CaCl₂ on the oxygen isotope fractionation between quartz and water and between calcite and water were measured at 5 and 15 kbar at temperatures from 300 to 750°C. CaCl₂ has a larger influence than NaCl on the isotopic fractionation between quartz and water. Although NaCl systematically changes the isotopic fractionation between quartz and water, it has no influence on the isotopic fractionation between calcite and water. This difference in the apparent oxygen isotope salt effects of NaCl must relate to the use of different minerals as reference phases. The term oxygen isotope salt effect is expanded here to encompass the effects of dissolved minerals on the fractionations between minerals and aqueous fluids. The oxygen isotope salt effects of dissolved quartz, calcite, and phlogopite at 15 kbar and 750°C were measured in the three-phase systems quartz-calcite-water and phlogopite-calcite-water. Under these conditions, the oxygen isotope salt effects of the three dissolved minerals range from ∼0.7 to 2.1‰. In both three-phase hydrothermal systems, the equilibrium fractionation factors between the pairs of minerals are the same as those obtained by anhydrous direct exchange between each pair of minerals, proving that the use of carbonate as exchange medium provides correct isotopic fractionations for a mineral pair.When the oxygen isotope salt effects of two minerals are different, the use of water as an indirect exchange medium will give erroneous fractionations between the two minerals. The isotope salt effect of a dissolved mineral is also the main reason for the observation that the experimentally calibrated oxygen isotope fractionations between a mineral and water are systematically 1.5 to 2‰ more positive than the results of theoretical calculations. Dissolved minerals greatly affect the isotopic fractionation in mineral-water systems at high pressure and high temperature. If the presence of a solute changes the solubility of a mineral, the real oxygen isotope salt effect of the solute at high pressure and high temperature cannot be correctly derived by using the mineral as reference phase.  相似文献   

Indicator Simulation Accounting for Multiple-Point Statistics   总被引：7，自引：0，他引：7  

Julián M. Ortiz  Clayton V. Deutsch 《Mathematical Geology》2004,36(5):545-565

Geostatistical simulation aims at reproducing the variability of the real underlying phenomena. When nonlinear features or large-range connectivity is present, the traditional variogram-based simulation approaches do not provide good reproduction of those features. Connectivity of high and low values is often critical for grades in a mineral deposit. Multiple-point statistics can help to characterize these features. The use of multiple-point statistics in geostatistical simulation was proposed more than 10 years ago, on the basis of the use of training images to extract the statistics. This paper proposes the use of multiple-point statistics extracted from actual data. A method is developed to simulate continuous variables. The indicator kriging probabilities used in sequential indicator simulation are modified by probabilities extracted from multiple-point configurations. The correction is done under the assumption of conditional independence. The practical implementation of the method is illustrated with data from a porphyry copper mine.  相似文献   

Transformation of Residuals to Avoid Artifacts in Geostatistical Modelling with a Trend   总被引：1，自引：0，他引：1  

Oy Leuangthong  Clayton V. Deutsch 《Mathematical Geology》2004,36(3):287-305

Trend modelling is an important part of natural resource characterization. A common approach to account for a variable with a trend is to decompose it into a relatively smoothly varying trend and a more variable residual component. Then, the residuals are stochastically modelled independent of the trend. This decomposition can result in values outside the plausible range of variability, such as grades below zero or ratios that exceed 1.0. We transform the residuals conditional to the trend component to explicitly remove these complex features prior to geostatistical modelling. Back transformation of the modelled residual values allows the complex relations to be reproduced. A petroleum-related application shows the robustness of the proposed transformation. Furthermore, a mining application shows that when this conditional transformation is applied to the original variable, instead of the residual, simulated values are assured to be nonnegative.  相似文献