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In this work we try to better characterise the shallow magnetic signature of hydrocarbon microseepage in oil fields from eastern and western Venezuela. To get a better insight of the processes involved, we attempt to find out the main magnetic phases responsible for the observed oil-related shallow magnetic anomalies. In this way, a new and alternative numerical approach to decompose Isothermal Remagnetization (IRM) curves is introduced. The method is based on a Direct Signal Analysis (DSA) of the IRM curve in order to identify the number and type of magnetic components. Representative wells from western (La Victoria) and eastern (San Joaquín) Venezuelan fields are studied. The DSA approach, together with rock magnetic experimental results, indicates that in the well from western Venezuela the main magnetic mineralogy associated to hydrocarbon microseepage is magnetite. Conversely, in the well from eastern Venezuela, these MS anomalies are mainly caused by the presence of Fe-sulphides (i.e. greigite). These results support the hypothesis of two different authigenic processes. For the well at the western field, we propose that a net electron transfer from the organic matter, degraded by hydrocarbon gas leakage, should occur precipitating Fe(II) magnetic minerals (e.g. magnetite). On the other hand, in the well of the eastern field, high concentrations of H2S at shallow levels, might allow the formation of secondary Fe-sulphides.  相似文献   
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Numerous studies have shown that most beaches and coastal dune systems of the world are currently eroding but very few have investigated the combined sediment budgets of subaerial and nearshore submarine systems. In the case of the dune field of the Maspalomas Natural Special Reserve (in the south of Gran Canaria), the adjacent Maspalomas and El Inglés beaches and the adjacent submarine platform, the sediment budgets have been severely affected by erosion over the past few decades. The objectives of this study were to investigate the availability of sand within the modern sedimentary system, including the coastal dunes, the beaches and the submerged shelf, but also to assess local sediment sinks. An isopach map generated on the basis of topo-bathymetric data and seismic-reflection profiles revealed that sediment thickness varies from 0–22 m in the study area. Expanses of relatively low sediment thickness were identified in the south-western sector of the coastal dune field along Maspalomas beach, and in the nearshore region to the south of this beach. These localized sediment-deficit areas earmark Maspalomas beach as the most vulnerable shore strip threatened by erosion. The shallow seismic data also revealed that the submarine platform south of Maspalomas represents a marine terrace cut into an ancient alluvial fan, thus documenting an influence of the geomorphological heritage on the present-day morphodynamics. A side-scan sonar mosaic of this nearshore platform enabled the delimitation of areas covered by rock, boulders and gravel, vegetated sand patches and a mobile sand facies, the latter including ripple and megaripple fields. The megaripple field in a valley close to the talus of the marine terrace has been identified as a major sediment sink of the Maspalomas sedimentary system. It is fed by south-westerly storm-wave events. The sediment deficit in the coastal dune field and along Maspalomas beach can therefore only be explained by a currently faster loss of sediment to an offshore sink than can be compensated by the supply of sand from outside the system.  相似文献   
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Fifty-four broadband models for computation of solar diffuse irradiation on horizontal surface were tested in Romania (South-Eastern Europe). The input data consist of surface meteorological data, column integrated data, and data derived from satellite measurements. The testing procedure is performed in 21 stages intended to provide information about the sensitivity of the models to various sets of input data. There is no model to be ranked “the best” for all sets of input data. However, some of the models performed better than others, in the sense that they were ranked among the best for most of the testing stages. The best models for solar diffuse radiation computation are, on equal footing, ASHRAE 2005 model (ASHRAE 2005) and King model (King and Buckius, Solar Energy 22:297–301, 1979). The second best model is MAC model (Davies, Bound Layer Meteor 9:33–52, 1975). Details about the performance of each model in the 21 testing stages are found in the Electronic Supplementary Material.  相似文献   
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We present two Arabic texts of historic observations of supernova SN 1006 from Yemen as reported by al‐Yamānī and Ibn al‐Daybac (14th to 16th century AD). An English translation of the report by the latter was given before (Stephenson & Green 2002), but the original Arabic text was not yet published. In addition, we present for the first time the earlier report, also from Yemen, namely by al‐Yamānī in its original Arabic and with our English translation. It is quite obvious that the report by Ibn al‐Daybac is based on the report by al‐Yamānī(or a common source), but the earlier report by al‐Yamānī is more detailed and in better (Arabic) language. We discuss in detail the dating of these observations. The most striking difference to other reports about SN 1006 is the apparent early discovery in Yemen in the evening of 15th of Rajab of the year 396h (i.e. AD 1006 April 17±2 on the Julian calendar), as reported by both al‐Yamānī and Ibn al‐Daybac, i.e. ∼1.5 weeks earlier than the otherwise earliest known reports. We also briefly discuss other information from the Yemeni reports on brightness, light curve, duration of visibility, location, stationarity, and color. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
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Drowned reefs, fossil reefs or paleo-reefs, are important ecologically as areas of high biodiversity, foraging, shelter environment, and as areas supporting the spawning aggregations of economically important reef fish species. This is particularly significant when the structures are situated in a wide soft-bottom continental shelf. The presence of limestone structures, fossil reefs and pinnacles dating from circa 8 to 9 ka, to the north of the Paria Peninsula in north-eastern Venezuela, has been known to local fishermen for decades. Using echograms obtained during acoustic fisheries evaluations and the scarce previously available information, an improved location map of hard-bottom structures was made. Benthic samples to study macromolluscs were taken at depths between 54 and 93 m using an unmodified 2-m beam trawl. Four trawl samples were located over fossil reef areas while another four were situated in soft-bottom valleys between limestone structures. Fossil reefs in the area showed a highly patchy distribution. A total of 91 species from 43 Bivalvia, Gastropoda and Scaphopoda families were found, Gastropoda being the dominant class with 49 species. Paleo-reef-covered areas showed higher species richness and only 21% of the species found were common to both substrates. Gastropods Tonna maculosa and Polystira albida were the most abundant species and occurred in both substrate types. Bivalve life habits, a mixture of organism–substrate relationships, shell fixation, mobility and feeding type, differed significantly according to bottom type. Six species are recorded for the first time for eastern Venezuelan waters. Bottom heterogeneity plays an important role in marine ecosystems, providing shelter to fish populations and may be significant as breeding and nursery areas. Its presence in a region with biogeographical interest, situated in the confluence of three major provinces and with oceanographic conditions varying seasonally from upwelling dominated to Orinoco River discharges, makes this the area of interest and it should be evaluated as a possible Marine Protected Area.  相似文献   
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The destabilization of kaolinite suspension by anionic flocculant addition occurs in three zones; free settling, hindered settling and compression which usually includes a final bed raking process in mineral processing practice. This paper reports changes in the kaolinite aggregate and floc structures in the different settling and raking zones by cryo-vitrification/cryo-SEM techniques with image analysis combining micro- and macro-flocs. Cryo-SEM images indicate that, even during free settling, fine clay particles are bridged predominantly in edge–edge (E–E) with some face–face (F–F) configurations forming single, small flocs and some chain structures. When these small flocs and chains settle into the hindered settling zone, the collision between flocs and chains results in “honeycomb” network structures formed with lateral chain-like extension. The settled bed consists of these honeycomb structures with both inter-aggregate and intra-aggregate trapped water and has relatively low bed density (e.g. < 12 wt.% for a 2 wt.% slurry). The effect of the raking process in dramatically improving thickener underflow solids has been extensively studied but the structural changes in flocs and aggregates in this process are less well defined. Raking the compression zone for 1 h at 3 rpm can release some of the trapped water in the “honeycomb” structure and the bed density for 2 wt.% slurry improves dramatically to more than 36 wt.%. Cryo-SEM illustrates the extensive restructuring of flocs from predominantly E–E to predominantly F–F in many areas. The STructural IMage ANalysis (STIMAN) software is used to combine a series of images at magnifications from 1000× to 8000×, including both macro- and micro-flocs. This structural analysis comparing the un-raked and raked bed samples gives increases in total particle area of 30% and in relative particle area of 6%. The relatively low energy rake action of the shear stress results in the disruption of the E–E chains and the honeycomb structure, partly releasing the trapped water and inducing some E–E to F–F aggregate restructuring are clearly illustrated in these results.  相似文献   
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Rock magnetic, petrographic and dielectric analyses were carried out, in a number of archeological ceramic potsherds, in order to characterize the different manufacturing techniques used by Prehistoric Venezuelan Amerindian potters. Samples were excavated in 7 Venezuelan islands and ascribed to distinct cultural groups on purely stylistic grounds (i.e. Valencioide, Ocumaroide, Dabajuroide and Unknown). Mean coercivity values were determined through a direct signal analyses (DSA) applied to isothermal remanent magnetization (IRM) acquisition curves. Logarithmic plots of these mean coercivities are the best quantitative means to classify diverse ceramics. The mean coercivity values seem to group the samples according to the manufacturing development. These values also seem to discriminate the samples provenance, indeed, this plot displays a good grouping of data for samples presumably manufactured by the same culture but excavated at different locations. Thermomagnetic cycles supply helpful information about original ceramic firing conditions. The irreversibility parameter (IP) for thermomagnetic curves (heating and cooling), serves as an indicator of the amount of organic matter burnt during original pottery firing. The IP for a number of pottery samples from Venezuelan islands and mainland, with ages ranging between 300 BC to 1500 AD, might suggest a possible increasing trend in time towards the complete reversibility line of IP = 0. Most samples, independently of age and cultural group, have IP values that suggest that most open fires, used by primitive Venezuelan Amerindian potters, had enough ventilation and oxidizing atmospheres. A scatter plot of maximum current depolarization temperatures versus natural remanent magnetization (NRM) suggests a complex non-linear relationship between these two parameters most likely due to the fact that both, dielectric and rock magnetic data, are linked to pore-related features.  相似文献   
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Methane-derived rocks in Monferrato and the Tertiary Piedmont Basin (NW Italy) consist of seep carbonates, formed by gas seepage at the seafloor, and macroconcretions resulting from the cementation of buried sediments crossed by gas-rich fluids. These rocks are characterized by both negative δ13C values and a marked enrichment in δ18O. Petrographic features not commonly described and that point to enigmatic depositional and diagenetic conditions have been observed in both types of rocks: inhomogeneous distribution of cements within cavities; dolomite crystals floating within cavity-filling calcite spar; non-gravitational fabrics of internal sediments plastering cavity walls; open framework within microbial crusts. These features suggest the former presence of gas hydrates in sediments. During their dissociation, new space was formed and filled with authigenic carbonates or injected sediments. Analogous mechanisms of clathrate freeze-and-thaw processes have been inferred for the genesis of zebra and stromatactis structures and particular kinds of carbonate breccias. The term melt-seal structure is proposed for this kind of diagenetic structure. The fabrics of gas hydrates and the geochemical conditions of sediments, in turn depending on the relative rates of supply of methane-rich fluids and normal seawater, conditioned the final aspect of the rocks.  相似文献   
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