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SATO HIROAKI; HOLTZ FRANCOIS; BEHRENS HARALD; BOTCHARNIKOV ROMAN; NAKADA SETSUYA 《Journal of Petrology》2005,46(2):339-354
High-temperature–pressure experiments were carried outto determine the chlorine–hydroxyl exchange partitioncoefficient between hornblende and melt in the 1992 Unzen dacite.Cl in hornblende and melt was analyzed by electron microprobe,whereas OH in hornblende and melt was calculated assuming anionstoichiometry of hornblende and utilizing the dissociation reactionconstant for H2O + O = 2(OH) in water-saturated melt, respectively.The partition coefficient strongly depends on the Mg/(Mg + Fe)ratio of hornblende, and is expressed as ln K1 = (Cl/OH)hb/(Cl/OH)melt= 2·37 – 4·6[Mg/(Mg + Fe)]hb at 2–3kbar and 800–850°C. The twofold variation in Cl contentin the oscillatory zoned cores of hornblende phenocrysts inthe 1991–1995 dacite cannot be explained by the dependenceof the Cl/OH partition coefficient on the Mg/(Mg + Fe)hb ratio,and requires c. 80% variation of the Cl/OH ratio of the coexistingmelt. Available experimental data at 200 MPa on Cl/OH fractionationbetween fluid and melt suggest that c. 1·2–1·8wt % degassing of water from the magma can explain the required80% variation in the Cl/OH ratio of the melt. The negative correlationbetween Al content and Mg/(Mg + Fe) ratio in the oscillatoryzoned cores of the hornblende phenocrysts is consistent withrepeated influx and convective degassing of the fluid phasein the magma chamber. KEY WORDS: chlorine; element partitioning; hornblende; oscillatory zoning; Unzen volcano 相似文献
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JULE XIAO YOSHIO INOUCHI HISAO KUMAI SHUSAKU YOSHIKAWA YOICHI KONDO KEIICHI TAKAHASHI 《Boreas: An International Journal of Quaternary Research》2004,33(1):74-81
The fluvial quartz flux (FQF, g cm -2 ka -1 ) to Lake Biwa of central Japan is developed as a proxy of variations in palaeoprecipitation over the lake catchment. Lake Biwa sediments spanning the last c. 145 ka are characterized by 4 main intervals when the FQF values were significantly greater than 2 g cm -2 ka -1 , and 5 main periods during which FQF values were lower. Three of the intervals with high FQF values occur from c. 128 to 78 ka BP, with peak values at c. 122, 101 and 82 ka BP; the fourth of two narrow peaks exists between c. 48 and 35 ka BP. Three main periods with lower FQF values intervene between intervals of high FQF values, and two others lie before c. 128 ka BP and after c. 35 ka BP. The data imply that palaeoprecipitation over the lake catchment increased during the intervals of high FQF values, and decreased during the periods of lower FQF values. High FQF values between c. 48 and 35 ka BP are interpreted to reflect an effective runoff of meltwater from the surrounding mountains during the interstade of the last glaciation. Relatively low FQF values during the early Holocene are interpreted to reveal a sluggish northward retreat of the polar front in the North Pacific Ocean that suppressed the northward advance of the summer monsoonal front and regional precipitation. During the last interglaciation, the increasing trend of FQF values is interpreted to indicate a progressive expansion of the Sea of Japan related to the rise in global sea level, which increased moisture advection to, and precipitation within, the Lake Biwa region. 相似文献
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云南高黎贡山典型斜长角闪岩地震波速、各向异性及其晶格优选定向的研究 总被引：1，自引：0，他引：1
斜长角闪岩和角闪岩相变质岩石是大陆中—下地、岛弧深部地壳以及俯冲大洋地壳中最重要的组成岩石之一,查明目前地壳中斜长角闪岩的体积含量、空间分布及其应变状态对于深入研究大陆地壳的形成与演化过程极其重要.笔者等实验测量了云南高黎贡韧性剪切带典型变形斜长角闪岩7个关键性方向上的地震(P和S波)波速随静水围压(0～600 MPa)的变化规律,并利用电子背散射衍射(EBSD)技术测定了主要造岩矿物角闪石、斜长石和石英的品格优选方位,查清斜长角闪岩中地震波速各向异性与剪切波分裂的成因,确定斜长角闪岩中有限应变椭球与波速椭球的对应关系,为今后利用原地地震波速的各向异性调查地壳深部区域构造应变场提供必要的实验和理论基础. 相似文献
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Experimental Petrology of the 1991-1995 Unzen Dacite, Japan. Part I: Phase Relations, Phase Composition and Pre-eruptive Conditions 总被引：2，自引：0，他引：2
HOLTZ FRANCOIS; SATO HIROAKI; LEWIS JARED; BEHRENS HARALD; NAKADA SETSUYA 《Journal of Petrology》2005,46(2):319-337
Crystallization experiments were conducted on dry glasses fromthe Unzen 1992 dacite at 100–300 MPa, 775–875°C,various water activities, and fO2 buffered by the Ni–NiObuffer. The compositions of the experimental products and naturalphases are used to constrain the temperature and water contentsof the low-temperature and high-temperature magmas prior tothe magma mixing event leading to the 1991–1995 eruption.A temperature of 1050 ± 75°C is determined for thehigh-temperature magma based on two-pyroxene thermometry. Theinvestigation of glass inclusions suggests that the water contentof the rhyolitic low-temperature magma could be as high as 8wt % H2O. The phase relations at 300 MPa and in the temperaturerange 870–900°C, which are conditions assumed to berepresentative of the main magma chamber after mixing, showthat the main phenocrysts (orthopyroxene, plagioclase, hornblende)coexist only at reduced water activity; the water content ofthe post-mixing dacitic melt is estimated to be 6 ± 1wt % H2O. Quartz and biotite, also present as phenocrysts inthe dacite, are observed only at low temperature (below 800–775°C).It is concluded that the erupted dacitic magma resulted fromthe mixing of c. 35 wt % of an almost aphyric pyroxene-bearingandesitic magma (1050 ± 75°C; 4 ± 1 wt % H2Oin the melt) with 65 wt % of a phenocryst-rich low-temperaturemagma (760–780°C) in which the melt phase was rhyolitic,containing up to 8 ± 1 wt % H2O. The proportions of rhyoliticmelt and phenocrysts in the low-temperature magma are estimatedto be 65% and 35%, respectively. It is emphasized that the strongvariations of phenocryst compositions, especially plagioclase,can be explained only if there were variations of temperatureand/or water activity (in time and/or space) in the low-temperaturemagma. KEY WORDS: Unzen volcano; magma mixing; experimental study 相似文献
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