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Continuous field estimation of dissolved organic carbon concentration and biochemical oxygen demand using dual‐wavelength fluorescence,turbidity and temperature 
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下载免费PDF全文 Dissolved organic matter (DOM) quality and quantity is not measured routinely in‐situ limiting our ability to quantify DOM process dynamics. This is problematic given legislative obligations to determine event based variability; however, recent advances in field deployable optical sensing technology provide the opportunity to address this problem. In this paper, we outline a new approach for in‐situ quantification of DOM quantity (Dissolved Organic Carbon: DOC) and a component of quality (Biochemical Oxygen Demand: BOD) using a multi‐wavelength, through‐flow fluorescence sensor. The sensor measured tryptophan‐like (Peak T) and humic‐like (Peak C) fluorescence, alongside water temperature and turbidity. Laboratory derived coefficients were developed to compensate for thermal quenching and turbidity interference (i.e., light attenuation and scattering). Field tests were undertaken on an urban river with ageing wastewater and stormwater infrastructure (Bourn Brook; Birmingham, UK). Sensor output was validated against laboratory determinations of DOC and BOD collected by discrete grab sampling during baseflow and stormflow conditions. Data driven regression models were then compared to laboratory correction methods. A combination of temperature and turbidity compensated Peak T and Peak C was found to be a good predictor of DOC concentration (R2 = 0.92). Conversely, using temperature and turbidity correction coefficients provided low predictive power for BOD (R2 = 0.46 and R2 = 0.51, for Peak C and T, respectively). For this study system, turbidity appeared to be a reasonable proxy for BOD, R2 = 0.86. However, a linear mixed effect model with temperature compensated Peak T and turbidity provided a robust BOD prediction (R2 = 0.95). These findings indicate that with careful initial calibration, multi‐wavelength fluorescence, coupled with turbidity, and temperature provides a feasible proxy for continuous, in‐situ measurement of DOC concentration and BOD. This approach represents a cost effective monitoring solution, particularly when compared to UV – absorbance sensors and DOC analysers, and could be readily adopted for research and industrial applications. 相似文献
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Madurya Adikaram Amarasooriya Pitawala Hiroaki Ishiga Daham Jayawardhana 《Journal of the Geological Society of India》2017,89(1):71-76
Quaternary sediment deposits are well exposed along the eastern coastal margin of Sri Lanka. Systematic trace fossil studies along with sediment characteristics have been carried out for the first time to interpret the paleoenvironment that prevailed during Quaternary sedimentation in eastern Sri Lanka. The trace fossils Thalassinoides, Skolithos and Polykladichnus have been recognized about 5m above the present mean sea level. Features of the major trace fossil, Thalassinoides, indicate that it was formed by Thalassinidean shrimp Calianassa. Isolated, vertical to steeply inclined, cylindrical to sub cylindrical tubes with thin internal wall lining and inner wall striations of Skolithos and Polykladichnus show that they were formed by polychaetes. The typical characteristic of Polykladichnus isY-shaped branching with slight enlargement at junctions. Morphology and association of burrows as well as mineralogy, grain size and roundness of sediments indicate that the environment prevailed was marine soft grounds of the intertidal zone. Presence of preserved fine-scale features of burrows indicate that the bioturbated sandy tidal flat was suddenly exposed to the tropical environment due to sea level regression in Quaternary periods. Due to the microbial activities of wall linings, burrows were preserved and it was supported by other microbial activities that produced secondary iron bearing minerals that suffered subsequent oxidation. The bio-origination of red sediments of eastern coastal area of the present study can be used to interpret the debatable origin of the red beds found in northwestern and southeastern coastal areas of the island. 相似文献
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Khamis Naba Sayl Nur Shazwani Muhammad Ahmed El-Shafie 《Environmental Earth Sciences》2017,76(10):368
The major limitation in planning water harvesting is the lack of knowledge in the estimation of surface area and storage volume at any depth of dam reservoir. The area–volume–elevation (AVE) curve of a reservoir plays a key role in estimating the most suitable depth, optimum surface area and highest capacity of reservoir storage. The existing methods to estimate the AVE curve are costly and time-consuming and require laborious work. This study attempts to develop a method to optimize the AVE curve for earth dams, using the digital elevation model generated by the Shuttle Radar Topography Mission (SRTM) data, and integrate it with the geographic information system (GIS), known as the GIS–SRTM. The proposed method was tested using field data in the Western Desert of Iraq, which is an arid environment. Three constructed small earth dams were selected for this study. The AVE curves were extracted for Horan 2 (H2), Al-gara 2 (G2) and Al-gara 4 (G4) earth dams. Comprehensive analyses have been carried out to evaluate the performance of the AVE curves using the proposed GIS–SRTM method and the field data. From the comparison, the proposed GIS–SRTM method was able to produce reliable AVE curves with a relative error less than 20%. Additionally, the proposed method was less time-consuming and the AVE curves can be visualized immediately. The proposed GIS–SRTM method is relatively supportive in analyzing spatial data to select the optimal site for rainwater harvesting and prevent excessive evaporation losses. 相似文献
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Madurya Adikaram Amarasooriya Pitawala Hiroaki Ishiga Daham Jayawardana 《Environmental Earth Sciences》2017,76(24):817
The concentrations of Br and I in marine sediments have been used to categorize the sedimentary environments of different coastal regions of the world with respect to organic matter contents. The present study uses the concentrations of Br, I and P2O5 of different marine settings as a new proxy to interpret the depositional environments. A total of 150 coastal lagoon sediment samples (suspended sediments, surface sediments and sediment cores) were analyzed for Br, I and P2O5 concentrations by X-ray fluorescence spectrometry. They were compared with the Br, I and P2O5 concentrations of the 2004 Indian Ocean tsunami sediments. Sediments from various sources are separately clustered in I–Br plot and a trivial negative correlation is found for the whole plot. A similar correlation pattern exists in the I–P2O5 diagram. This correlation is explained by the distribution of marine plants (higher and lower) in different sedimentary environments of the coastal profile. Therefore, the concentration of I and its relation to P2O5 can be used as a tool to identify sediment depositional environments in marine settings. 相似文献
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Glacier‐fed river thermal regimes vary markedly in space and time; however, knowledge is limited on the fundamental processes controlling alpine stream temperature dynamics. To address the research gap, this study quantified heat exchanges at the water surface and bed of the Taillon glacier‐fed stream, French Pyrénées. Hydro‐meteorological observations were recorded at 15‐min intervals across two summer melt seasons (2010 and 2011), and energy balance components were measured or estimated based on site‐specific data. Averaged over both seasons, net radiation was the largest heat source (~80% of total flux); sensible heat (~13%) and friction (~3%) were also sources, while heat exchange across the channel–streambed interface was negligible (<1%). Latent heat displayed distinct interannual variability and contributed 5% in 2010 compared with 0.03% in 2011. At the sub‐seasonal scale, latent heat shifted from source to sink, possibly linked to the retreating valley snowline that changed temperature and humidity gradients. These findings represent the first, multiyear study of the heat exchange processes operating in a glacier‐fed stream, providing fundamental process understanding; the research highlights the direct control antecedent (winter) conditions that have on energy exchange and stream temperature during summer months. In particular, the timing and volume of snowfall/snowmelt can drive thermal dynamics by the following: (1) altering the length of the stream network exposed to the atmosphere and (2) controlling the volume and timing of cold water advection downstream. Finally, this study highlights the need to develop long‐term hydro‐meteorological monitoring stations to improve the understanding of these highly dynamic, climatically sensitive systems. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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The cumulative impacts of reclamation and dredging on the marine ecology and land-use in the Kingdom of Bahrain 总被引：1，自引：0，他引：1
Zainal K Al-Madany I Al-Sayed H Khamis A Al Shuhaby S Al Hisaby A Elhoussiny W Khalaf E 《Marine pollution bulletin》2012,64(7):1452-1458
This article assesses the ecological and economic impacts of land reclamation and dredging through consulting recent environmental impact assessment reports. Geographic features of Bahrain during 1963-2008 are produced using Geographical Information System. Extensive but inexpensive shallow coastal areas and tidal flats have been reclaimed particularly from 1997 to 2007 at a high rate of 21 km(2)/year. Formal records show the increase in the original land mass by the year 2008 to be 91 km(2). An estimated total cumulative loss of major habitats resulting from 10 reclamation projects was around 153.58 km(2). Also much larger scale impacts should be considered resulting from the borrow areas used for the extraction of sand or infill materials. A number of key habitats and species are affected in the vicinity of these projects. The study attempts to assign a monetary value to the marine ecosystem functions. There is a need for efficient coastal zone management to regulate a sustainable use of the marine resources. 相似文献
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Iraq, the land of two rivers, has a history that extends back millennia and is the subject of much archaeological research. However, little environmental research has been carried out, and as such relatively little is known about the interaction between Iraq’s vegetation and climate. This research serves to fill this knowledge gap by investigating the relationship between the Normalized Difference Vegetation Index (NDVI) and two climatic factors (precipitation and air temperature) over the last decade. The precipitation and air temperature datasets are from the Water and Global Change Forcing Data ERA-Interim (WFDEI), and the NDVI dataset was extracted from the Moderate Resolution Imaging Spectroradiometer (MODIS) at 250 m spatial resolution and 16 day temporal resolution. Three different climatic regions in Iraq, Sulaymaniyah, Wasit, and Basrah, were selected for the period of 2001–2015. This is the first study to compare these regions in Iraq, and one of only a few investigating vegetation’s relationship with multiple climatic factors, including precipitation and air temperature, particularly in a semi-arid region. The interannual, intra-annual and seasonal variability for each region is analysed to compare the different responses of vegetation growth to climatic factors. Correlations between NDVI and climatic factors are also included. Plotting annual cycles of NDVI and precipitation reveals a coherent onset, fluctuation (peak and decline), with a time lag of 4 months for Sulaymaniyah and Wasit (while for the Basrah region, high temperatures and a short rainy season was observed). The correlation coefficients between NDVI and precipitation are relatively high, especially in Sulaymaniyah, and the largest positive correlation was (0.8635) with a time lag of 4 months. The phenological transition points range between 3 and 4 month time lag; this corresponds to the duration of maturity of the vegetation. However, when correlated with air temperature, NDVI experiences an inverse relationship, although not as strong as that of NDVI and precipitation; the highest negative correlation was observed in Wasit with a time lag of 2 months (? 0.7562). The results showed that there is a similarity between temporal patterns of NDVI and precipitation. This similarity is stronger than that of NDVI and air temperature, so it can be concluded that NDVI is a sensitive indicator of the inter-annual variability of precipitation and that precipitation constitutes the primary factor in germination while the air temperature acts with a lesser effect. 相似文献
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Theoretical and Applied Climatology - Mean annual and monthly averages of mean (Tmean), maximum (Tmax) and minimum (Tmin) air temperature from seven stations in Iraq were analysed to detect the... 相似文献
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The stream sediments of Wadi El Reddah(North Eastern Desert,Egypt)are geochemically and mineralogically investigated.Their content of radioactive and other heavy minerals is mainly represented by thorite,uranothorite,zircon,monazite,xenotime,columbite,fergusonite,and unknown rare earth elements(REEs)bearing minerals as well as cassiterite.Special emphasis on REE content of thorite,uranothorite,zircon and xenotime has been done to correlate them with the increase of uranium contents in these sediments.The key evidence for the presence lowtemperature alteration processes includes the presence of some zircon crystals as remnants after complete dissolution of the overgrowth zircon in severe acidic environment,the sulphur content,biogenic minerals,occurrence of unusual minerals as cassiterite pore filling in zircon,variation in the REEs content from the surrounding granites to the stream sediments and the abundance of monazite in the surrounding granites.Most minerals are partially and/or completely altered,which indicated by the pseudomorphism of zircon by xenotime,thorite,and uranothorite. 相似文献